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Crystal Structure of Eu2PdSi3
-
U. Ch. Rodewald
and
E.V. Sampathkumaran
Published/Copyright:
June 2, 2014
Single crystals of Eu2PdSi3 were obtained from an arc-melted sample that was further annealed at 1020 K for seven days in a silica tube. The structure of Eu2PdSi3 was refined from single crystal X-ray diffractometer data: P6/mmm, a = 831.88(12), c = 435.88(9) pm, wR2 = 0.1175, 265 F2 values, and 13 variable parameters. It crystallizes with the U2RuSi3 structure, a superstructure of the AlB2 type. The palladium and silicon atoms form a planar two-dimensional [PdSi3] network. The two crystallographically different europium atoms have hexagonal prismatic coordinations Eu1Si12 and Eu2Pd4Si8. The Pd-Si and Si-Si distances within the [PdSi3] network are 244 and 236 pm, respectively.
Received: 2003-8-19
Published Online: 2014-6-2
Published in Print: 2003-10-1
© 1946 – 2014: Verlag der Zeitschrift für Naturforschung
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