Startseite Metallkomplexe von Biologisch Wichtigen Liganden, CXLVIII [1]. Katalytische Peptidsynthese aus Glycinester miit Hilfe von Triflaten Und Cloriden der Seltenen Erden, sowie von Metall(III), (IV), (V) und (VI)-Chloriden / Metal Complexes of Biologically Important Ligands, CXLVIII [1]. Synthesis of Peptides from Glycine Ester Catalysed by Triflates and Chlorides of Metal(III, IV, V And VI) Ions
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

Metallkomplexe von Biologisch Wichtigen Liganden, CXLVIII [1]. Katalytische Peptidsynthese aus Glycinester miit Hilfe von Triflaten Und Cloriden der Seltenen Erden, sowie von Metall(III), (IV), (V) und (VI)-Chloriden / Metal Complexes of Biologically Important Ligands, CXLVIII [1]. Synthesis of Peptides from Glycine Ester Catalysed by Triflates and Chlorides of Metal(III, IV, V And VI) Ions

  • Jan Schapp und Wolfgang Beck EMAIL logo
Veröffentlicht/Copyright: 2. Juni 2014
Veröffentlichen auch Sie bei De Gruyter Brill
Informationen für Autor*innen Erkunden Sie dieses Fachgebiet
Zeitschrift für Naturforschung B
Aus der Zeitschrift Zeitschrift für Naturforschung B Band 58 Heft 1

Abstract

Formation of di- and triglycine ethylester which were determined by HPLC after derivatisation with dansyl chloride was observed in medium to high yields from CH2Cl2 solutions of glycine ethylester in the presence of metal triflates and metal chlorides: FeCl3 (yield 82%), AlCl3 (73%), GdCl3 (56%), La(OTf)3 (59%), Sc(OTf)3 (55%), ZrCl4 (62%), HfCl4 (60%), VOCl3 (43%), TaCl5 (29%). Esters of higher α-amino acid esters (AlaOMe, PheOMe) gave lower yields in peptide formation.

Keywords : Peptides Synthesis; Rare Earth Elements; Transition Metals; Catalysts; α-Amino Acid Esters
Received: 2002-8-23
Published Online: 2014-6-2
Published in Print: 2003-1-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Artikel in diesem Heft

  1. Dinuclear Derivatives of Mn2(CO)10 with the Ligand Tri(1-Cyclohepta- 2,4,6-Trienyl)Phosphane, P(C7H7)3, and their Oxidative Cleavage
  2. Synthesis and Reactivity of Bromo-Mer-Tricarbonyl-Trans-Bis[Tri(1-Cyclohepta- 2,4,6-Trienyl)Phosphane]-Manganese, Mnbr(CO)3[P(C7H7)3]2
  3. Transition Metal-Gallium Ordering In HfCoGa2 And HfNiGa2
  4. Metal Directed One-Pot Syntheses: Mono-, Di- and Tetra-Nuclear Clusters [1]
  5. Quadratate Und Hydrogenquadratate Cyclischer Stickstoffbasen Mit Schicht-, Ketten- und Leiterstrukturen / Squarates and Hydrogensquarates of Cyclic Nitrogen Bases with Layer-, Chainand Ladder-Structures
  6. Tungstenmethyl-Dimethylsilanols Cp(Oc)2(R3P)W—CH2—SiMe2OH (R = Me, Ph) – Synthesis Via Oxygenation or Hydrolysis
  7. Reaktionen von Vanadium(V)- und Tantal(V)-Komplexen Mit Kinetisch Stabilisierten Phosphaalkinen. Einfache Synthese von 1,3,4-Thia- und 1,3,4-Selenadiphospholen / Reactions of Vanadium(V) and Tantalum(V)-Complexes with Kinetically Stabilized Phosphaalkynes. A Simple Synthesis of 1,3,4-Thia and 1,3,4-Selenadiphospholes
  8. New Coordination Polymers Based On Transition Metal Squarates And Pyrazine Ligands
  9. Peri-Interactions in Naphthalenes, 9 [1]. On Hypercoordination in Non-Quaternary Phosphonium Salts and a Secondary Phosphine with the (8-Dimethylamino-Naphth-1-Yl) Substituent
  10. The Hexakis(N,N'-Dimethylurea)Cobalt(Ii) Cation: A Flexible Building Block for the Construction of Hydrogen Bonded Networks
  11. Metallkomplexe von Biologisch Wichtigen Liganden, CXLVIII [1]. Katalytische Peptidsynthese aus Glycinester miit Hilfe von Triflaten Und Cloriden der Seltenen Erden, sowie von Metall(III), (IV), (V) und (VI)-Chloriden / Metal Complexes of Biologically Important Ligands, CXLVIII [1]. Synthesis of Peptides from Glycine Ester Catalysed by Triflates and Chlorides of Metal(III, IV, V And VI) Ions
  12. Metallkomplexe mit Biologisch Wichtigen Liganden, CIL [1]. Metallorganische η2-N,O-Lysinato-Komplexe / Metal Complexes Of Biologically Important Ligands, Cil [1]. Organometallic η2-N,O-Lysinato-Complexes
  13. Synthese monofluorierter cyclopropanoider Nucleosidanaloga / Synthesis of Monofluorinated Cyclopropanoic Nucleoside Analogues
  14. Hydroxyurea Analogues of Fosmidomycin
  15. Synthesis of 2-Phenylisothiazol-3(2H)-One 1,1-Dioxides: Inhibitors of Human Leukocyte Elastase
  16. Erratum
  17. The Reduction of Pyridine to 1,4-Dihydropyridine by Lithiumtetrahydroborate in the Presence of Water
  18. Preparation, Crystal and Magnetic Structure of the Double Perovskites Ca2TWO6 (T = Co, Ni)
  19. Hydroboration of Bis(Trimethylsilyl)Ethyne. New Aspects of Hydroboration
  20. Conductivity, Electrodeposition and Magnetic Property of Cobalt(II) and Dysprosium Chloride in Zinc Chloride-1-Ethyl-3-Methylimidazolium Chloride Room Temperature Molten Salt
  21. A Zwitterionic Platinum Complex with a Carbene Ligand
  22. Synthesis and Structural Characterization of the Mixed Ligand Complex [Cu(Hml)2(Phen)] · 2 H2O (H2ml = 2-Methyllactic Acid)
  23. Synthesis, Thermal and X-Ray Investigations of the High-Temperature Phase of Copper(I) Cyanide
  24. Rietveld Refinement of the Crystal Structure of α-Be3N2 and the Experimental Determination of Optical Band Gaps for Mg3N2, Ca3N2 and CaMg2N2
  25. Preparation and Crystal Structure of Hexapotassium-μ-Oxo-Hexathiodititanate(IV), K6Ti2OS6
  26. (Phosphine)Silver(I) Sulfonate Complexes
  27. Beryllium Dichloride Coordination by Nitrogen Donor Molecules
  28. Zur gezielten Synthese funktionell substituierter Oligosilane aus Silyltriflaten und Aminosilyllithiumverbindungen / Tailor-Made Synthesis of Functional Substituted Oligosilanes from Silyl Triflates and (Aminosilyl)Lithium Compounds
  29. Secondary Bonding Interactionsi in Some Di- and Trihaloanilinium Halides
  30. Ba9[NbN4]2O[Cn2] – Synthesis, Crystal Structure and Raman Spectrum
https://doi.org/10.1515/znb-2003-0111
Schlagwörter für diesen Artikel
Peptides Synthesis; Rare Earth Elements; Transition Metals; Catalysts; α-Amino Acid Esters

Artikel in diesem Heft

  1. Dinuclear Derivatives of Mn2(CO)10 with the Ligand Tri(1-Cyclohepta- 2,4,6-Trienyl)Phosphane, P(C7H7)3, and their Oxidative Cleavage
  2. Synthesis and Reactivity of Bromo-Mer-Tricarbonyl-Trans-Bis[Tri(1-Cyclohepta- 2,4,6-Trienyl)Phosphane]-Manganese, Mnbr(CO)3[P(C7H7)3]2
  3. Transition Metal-Gallium Ordering In HfCoGa2 And HfNiGa2
  4. Metal Directed One-Pot Syntheses: Mono-, Di- and Tetra-Nuclear Clusters [1]
  5. Quadratate Und Hydrogenquadratate Cyclischer Stickstoffbasen Mit Schicht-, Ketten- und Leiterstrukturen / Squarates and Hydrogensquarates of Cyclic Nitrogen Bases with Layer-, Chainand Ladder-Structures
  6. Tungstenmethyl-Dimethylsilanols Cp(Oc)2(R3P)W—CH2—SiMe2OH (R = Me, Ph) – Synthesis Via Oxygenation or Hydrolysis
  7. Reaktionen von Vanadium(V)- und Tantal(V)-Komplexen Mit Kinetisch Stabilisierten Phosphaalkinen. Einfache Synthese von 1,3,4-Thia- und 1,3,4-Selenadiphospholen / Reactions of Vanadium(V) and Tantalum(V)-Complexes with Kinetically Stabilized Phosphaalkynes. A Simple Synthesis of 1,3,4-Thia and 1,3,4-Selenadiphospholes
  8. New Coordination Polymers Based On Transition Metal Squarates And Pyrazine Ligands
  9. Peri-Interactions in Naphthalenes, 9 [1]. On Hypercoordination in Non-Quaternary Phosphonium Salts and a Secondary Phosphine with the (8-Dimethylamino-Naphth-1-Yl) Substituent
  10. The Hexakis(N,N'-Dimethylurea)Cobalt(Ii) Cation: A Flexible Building Block for the Construction of Hydrogen Bonded Networks
  11. Metallkomplexe von Biologisch Wichtigen Liganden, CXLVIII [1]. Katalytische Peptidsynthese aus Glycinester miit Hilfe von Triflaten Und Cloriden der Seltenen Erden, sowie von Metall(III), (IV), (V) und (VI)-Chloriden / Metal Complexes of Biologically Important Ligands, CXLVIII [1]. Synthesis of Peptides from Glycine Ester Catalysed by Triflates and Chlorides of Metal(III, IV, V And VI) Ions
  12. Metallkomplexe mit Biologisch Wichtigen Liganden, CIL [1]. Metallorganische η2-N,O-Lysinato-Komplexe / Metal Complexes Of Biologically Important Ligands, Cil [1]. Organometallic η2-N,O-Lysinato-Complexes
  13. Synthese monofluorierter cyclopropanoider Nucleosidanaloga / Synthesis of Monofluorinated Cyclopropanoic Nucleoside Analogues
  14. Hydroxyurea Analogues of Fosmidomycin
  15. Synthesis of 2-Phenylisothiazol-3(2H)-One 1,1-Dioxides: Inhibitors of Human Leukocyte Elastase
  16. Erratum
  17. The Reduction of Pyridine to 1,4-Dihydropyridine by Lithiumtetrahydroborate in the Presence of Water
  18. Preparation, Crystal and Magnetic Structure of the Double Perovskites Ca2TWO6 (T = Co, Ni)
  19. Hydroboration of Bis(Trimethylsilyl)Ethyne. New Aspects of Hydroboration
  20. Conductivity, Electrodeposition and Magnetic Property of Cobalt(II) and Dysprosium Chloride in Zinc Chloride-1-Ethyl-3-Methylimidazolium Chloride Room Temperature Molten Salt
  21. A Zwitterionic Platinum Complex with a Carbene Ligand
  22. Synthesis and Structural Characterization of the Mixed Ligand Complex [Cu(Hml)2(Phen)] · 2 H2O (H2ml = 2-Methyllactic Acid)
  23. Synthesis, Thermal and X-Ray Investigations of the High-Temperature Phase of Copper(I) Cyanide
  24. Rietveld Refinement of the Crystal Structure of α-Be3N2 and the Experimental Determination of Optical Band Gaps for Mg3N2, Ca3N2 and CaMg2N2
  25. Preparation and Crystal Structure of Hexapotassium-μ-Oxo-Hexathiodititanate(IV), K6Ti2OS6
  26. (Phosphine)Silver(I) Sulfonate Complexes
  27. Beryllium Dichloride Coordination by Nitrogen Donor Molecules
  28. Zur gezielten Synthese funktionell substituierter Oligosilane aus Silyltriflaten und Aminosilyllithiumverbindungen / Tailor-Made Synthesis of Functional Substituted Oligosilanes from Silyl Triflates and (Aminosilyl)Lithium Compounds
  29. Secondary Bonding Interactionsi in Some Di- and Trihaloanilinium Halides
  30. Ba9[NbN4]2O[Cn2] – Synthesis, Crystal Structure and Raman Spectrum
Jetzt anmelden und 20% sparen
Institutioneller Zugang
Wie funktioniert Authentifizierung?
Haben Sie eine Idee, wie wir unsere Website verbessern können?
Bitte schreiben Sie uns.
© 2025 De Gruyter Brill
Heruntergeladen am 11.9.2025 von https://www.degruyterbrill.com/document/doi/10.1515/znb-2003-0111/html
Button zum nach oben scrollen