Article
Licensed
Unlicensed
Requires Authentication
Die neuen Oxobismutate(III) Cs6Bi4O9, K9Bi5O13 und A2Bi4O7 (A = Rb, Cs) / The New Oxobismutates(III) Cs6Bi4O9, K9Bi5O13 and A2Bi4O7 (A = Rb, Cs)
-
Franziska Emmerling
Published/Copyright:
June 2, 2014
Abstract
The title compounds were synthesized at a temperature of 700 °C via oxidation of elemental Bi with the hyperoxides AO2 or via reaction of the elemental alkali metals A with Bi2O3. Their crystal structures have been determined by single crystal x-ray diffraction. They are dominated by two possible surroundings of Bi by O, the ψ-trigonal-bipyramidal three (B) and the ψ-tetrahedral four (T) coordination. Cs6Bi4O9 (triclinic, spacegroup P1̄, a = 813.82(12), b = 991.60(14), c = 1213.83(18) pm, α = 103.658(2), β = 93.694(3), γ = 91.662(3)°, Z = 2) contains centrosymmetric chain segmentes [Bi8O18]12- with six three- (T) and two four-coordinated (B) Bi(III) centers. K9Bi5O13 (monoclinic, spacegroup P21/c, a = 1510.98(14), b = 567.59(5), c = 2685.6(2) pm, β = 111.190(2)°, Z = 4) is a mixed valence compound with isolated [BivO4]3- tetrahedra and chains [BiIII4O9]6- of two T and two B coordinated Bi. In the compounds A2Bi4O7 (A = Rb/Cs: monoclinic, C2/c, a = 2037.0(3) / 2130.6(12), b = 1285.5(2) / 1301.9(7), c = 1566.6(2) / 1605.6(9) pm, β = 94.783(3) / 95.725(9)°, Z = 8) ribbons [Bi4O6O2/2]2- are formed, which are condensed to form a three-dimensional framework.
Received: 2002-7-31
Published Online: 2014-6-2
Published in Print: 2002-10-1
© 1946 – 2014: Verlag der Zeitschrift für Naturforschung
You are currently not able to access this content.
You are currently not able to access this content.
Articles in the same Issue
- Nitridsulfidhalogenide der leichten Lanthanide vom Typ M6N3S4X (M = La - Nd; X = Cl, Br) mit ausgeordneten Sulfid- und Halogenid-Lagen / Nitride Sulfide Halides of the Light Lanthanides with the Formula Type M6N3S4X (M = La - Nd; X = Cl, Br) with Ordered Sulfide and Halide Positions
- Bis(triphenylphosphoranylidene)ammonium Dicyanoaurate(I)
- Die neuen Oxobismutate(III) Cs6Bi4O9, K9Bi5O13 und A2Bi4O7 (A = Rb, Cs) / The New Oxobismutates(III) Cs6Bi4O9, K9Bi5O13 and A2Bi4O7 (A = Rb, Cs)
- [3+1]-Cyclisierungen zu Tetraboraporphyrinogenen / [3+1]-Cycloadditions with Formation of Tetraboraporphyrinogenes
- Mercury Cyanamide / Carbodiimide Networks: Synthesis and Crystal Structures of Hg2(NCN)Cl2 and Hg3(NCN)2Cl2
- Self-Assembly of Organo-Sulfur, Selenium and Tellurium Compounds via π-π-Stacking and Hydrogen Bonding Interactions
- DFT Calculations of the Structures of Various Isomers (cis/trans) of [(CH3)(PH3)M-NH2-CH2-C(O)-O] and [(Cl)(PH3)M-NH2-CH2-C(O)-O] Complexes with M = Ni, Pd and Pt
- Eine einfache Synthese von 1,3-Dihydro-1,3-diborapentafulven-Derivaten / A Convenient Synthesis of 1,3-Dihydro-1,3-diborapentafulvene Derivatives
- Crystal Structure and Magnetic Properties of (2,2'-Dipyridyl)-(2-acetylphenolato)copper(II) Perchlorate
- Synthesis, Crystal Structures and Investigations on the Thermal Properties of New CuBr(2-Ethylpyrazine) Coordination Polymers
- Novel Non-Symmetric Nickel-Diimine Complexes for the Homopolymerization of Ethene: Control of Branching by Catalyst Design
- The First 6,8-Cycloeudesmane Sesquiterpene from a Marine Organism: The Red Seaweed Laurencia microcladia from the Baia di Calenzana, Elba Island
- Polysulfonylamine, CLIX [1]. Eine Vielfalt supramolekularer Synthone in zwei Molekülkomplexen von Di(4-halogenbenzolsulfonyl)aminen mit Sauerstoffbasen / Polysulfonylamines, CLIX [1]. A Variety of Supramolecular Synthons in Two Molecular Complexes of Di(4-halobenzenesulfonyl)amines with Oxygen Bases
- A Simple Conversion of 2'-Benzyloxyflavanone to Pterocarpan
- Synthesis of Rigid Cyclopropanoid Nucleoside Analogues
- Manganese(II), Iron(II), Cobalt(II) and Nickel(II) Complexes of Methanesulfonic Acid Hydrazide. Crystal Structure of trans-Dichlorotetrakis(methanesulfonic Acid Hydrazide-N2)cobalt(II) and trans-Dichlorotetrakis(methanesulfonic Acid Hydrazide-N2)nickel(II)
- Synthesis of a Dinuclear μ-(η2-Thioaldehyde)zirconocene Cation Complex
- Crystal Structure of trans- [ReCl2(dppp)2]Cl · ½H2O (dppp = 1,3-bis(diphenylphosphino)propane)
Articles in the same Issue
- Nitridsulfidhalogenide der leichten Lanthanide vom Typ M6N3S4X (M = La - Nd; X = Cl, Br) mit ausgeordneten Sulfid- und Halogenid-Lagen / Nitride Sulfide Halides of the Light Lanthanides with the Formula Type M6N3S4X (M = La - Nd; X = Cl, Br) with Ordered Sulfide and Halide Positions
- Bis(triphenylphosphoranylidene)ammonium Dicyanoaurate(I)
- Die neuen Oxobismutate(III) Cs6Bi4O9, K9Bi5O13 und A2Bi4O7 (A = Rb, Cs) / The New Oxobismutates(III) Cs6Bi4O9, K9Bi5O13 and A2Bi4O7 (A = Rb, Cs)
- [3+1]-Cyclisierungen zu Tetraboraporphyrinogenen / [3+1]-Cycloadditions with Formation of Tetraboraporphyrinogenes
- Mercury Cyanamide / Carbodiimide Networks: Synthesis and Crystal Structures of Hg2(NCN)Cl2 and Hg3(NCN)2Cl2
- Self-Assembly of Organo-Sulfur, Selenium and Tellurium Compounds via π-π-Stacking and Hydrogen Bonding Interactions
- DFT Calculations of the Structures of Various Isomers (cis/trans) of [(CH3)(PH3)M-NH2-CH2-C(O)-O] and [(Cl)(PH3)M-NH2-CH2-C(O)-O] Complexes with M = Ni, Pd and Pt
- Eine einfache Synthese von 1,3-Dihydro-1,3-diborapentafulven-Derivaten / A Convenient Synthesis of 1,3-Dihydro-1,3-diborapentafulvene Derivatives
- Crystal Structure and Magnetic Properties of (2,2'-Dipyridyl)-(2-acetylphenolato)copper(II) Perchlorate
- Synthesis, Crystal Structures and Investigations on the Thermal Properties of New CuBr(2-Ethylpyrazine) Coordination Polymers
- Novel Non-Symmetric Nickel-Diimine Complexes for the Homopolymerization of Ethene: Control of Branching by Catalyst Design
- The First 6,8-Cycloeudesmane Sesquiterpene from a Marine Organism: The Red Seaweed Laurencia microcladia from the Baia di Calenzana, Elba Island
- Polysulfonylamine, CLIX [1]. Eine Vielfalt supramolekularer Synthone in zwei Molekülkomplexen von Di(4-halogenbenzolsulfonyl)aminen mit Sauerstoffbasen / Polysulfonylamines, CLIX [1]. A Variety of Supramolecular Synthons in Two Molecular Complexes of Di(4-halobenzenesulfonyl)amines with Oxygen Bases
- A Simple Conversion of 2'-Benzyloxyflavanone to Pterocarpan
- Synthesis of Rigid Cyclopropanoid Nucleoside Analogues
- Manganese(II), Iron(II), Cobalt(II) and Nickel(II) Complexes of Methanesulfonic Acid Hydrazide. Crystal Structure of trans-Dichlorotetrakis(methanesulfonic Acid Hydrazide-N2)cobalt(II) and trans-Dichlorotetrakis(methanesulfonic Acid Hydrazide-N2)nickel(II)
- Synthesis of a Dinuclear μ-(η2-Thioaldehyde)zirconocene Cation Complex
- Crystal Structure of trans- [ReCl2(dppp)2]Cl · ½H2O (dppp = 1,3-bis(diphenylphosphino)propane)
