Home Die Koordination des [Hg2]2+-Kations in der konjugierten Supersäure HF/SbF5 durch CO oder H2O: Kristallstruktur von [Hg2(OH2)2][SbF6]2 · 4HF / The Co-ordination of the [Hg2]2+ Cation with CO or H2O in the Conjugated Super Acid HF/SbF5:Cryst al Structure of [Hg2 (OH2)2][SbF6]2 · 4HF
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Die Koordination des [Hg2]2+-Kations in der konjugierten Supersäure HF/SbF5 durch CO oder H2O: Kristallstruktur von [Hg2(OH2)2][SbF6]2 · 4HF / The Co-ordination of the [Hg2]2+ Cation with CO or H2O in the Conjugated Super Acid HF/SbF5:Cryst al Structure of [Hg2 (OH2)2][SbF6]2 · 4HF

  • Michael Berkei , Markus Schürmanna , Eduard Bernhardt and Helge Willner EMAIL logo
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 57 Issue 6

Abstract

In the superacidic system HF/SbF5, the salt [Hg2(CO)2][Sb2F11]2 reacts with traces of water to give the novel salt bis(aqua)dimercury(I) bis(hexafluoroantimonate)tetra(hydrogenfluoride) solvate [Hg2(OH2)2][SbF6]2 · 4HF. It crystallises in the triclinic system in the space group P1̄ with a = 661.47(6), b = 695.11(7), c = 922.29(9) pm, α = 83.428(5)°, β = 84.186(6)°, γ = 71.696(5)°, and one formula unit per unit cell. The four heavy atoms of the [Hg2(OH2)2]2+ cation are linked symmetrically and almost linear (nearly C2h) with a Hg-Hg bond length of 249.17(11) pm, two terminal Hg-O bonds of 214.8(8) pm, and an O-Hg-Hg bond angle of 177.6(3)°. Final R indices [I > 2σ(I)] are R1 = 0.0405 and wR2 = 0.0714.

Keywords: Carbonyl Cations; Mercury; Super Acids
Received: 2002-2-20
Published Online: 2014-6-2
Published in Print: 2002-6-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Neue Oxopnictate AI3MVO4: Darstellung und Kristallstruktur von A3AsO4 (A = K, Rb, Cs) und K3BiO4 / New Oxopnictates AI3MVO4: Synthesis and Crystal Structure of A3AsO4 (A = K, Rb, Cs) and K3BiO4
  2. Gold(I) Carboxylates and Fluorocarboxylates
  3. Crystal Structure of Tetrabutylammonium Carbonyltribromoplatinate(II) [(C4H9)4N][PtBr3(CO)]
  4. Die Koordination des [Hg2]2+-Kations in der konjugierten Supersäure HF/SbF5 durch CO oder H2O: Kristallstruktur von [Hg2(OH2)2][SbF6]2 · 4HF / The Co-ordination of the [Hg2]2+ Cation with CO or H2O in the Conjugated Super Acid HF/SbF5:Cryst al Structure of [Hg2 (OH2)2][SbF6]2 · 4HF
  5. Synthesis and Characterization of Tetraphenylphosphonium Tetraazidoborate
  6. Two Hydroxo Bridged Dinuclear Lanthanide Phen Complexes: [Ln2(phen)4(H2O)4(OH)2](phen)2(NO3)4 with Ln = Tm, Yb
  7. Zur Alkylierung von 2,3-Dihydro-1,3-diisopropyl-4,5- dimethylimidazol-2-yliden [1] / On the Alkylation of 2,3-Dihydro-1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene [1]
  8. Hetero-Diels-Alder Reactions of Enaminothione with Electrophilic Olefins. Synthesis of 2-Furyl Substituted 2H-Thiopyrans
  9. Preparation, Structure and Optical Properties of [CH3SC(NH2)2]3SnI5, [CH3SC(NH2)2][HSC(NH2)2]SnBr4, (CH3C5H4NCH3)PbBr3, and [C6H5CH2SC(NH2)2]4Pb3I10
  10. Crystal Structure and Conformation of N-(5-Chlorosalicylidene)- 2-hydroxy-5-chloroaniline
  11. Crystal Structure and Vibrational Behaviour of Tetraaqua-di(nicotinamide)M(II)-Saccharinates, with M(II) = Co, Ni, Zn
  12. Thermochemische Untersuchungen zu den Systemen SE2O3-SeO2 IV. Lösungskalorimetrie der SE2SexO3+2x-Phasen (SE = Nd, Sm, Y) / Thermochemical Investigations on the Systems RE2O3-SeO2 IV. Solution Calorimetry of the Phases RE2SexO3+2x(RE =Nd, Sm, Y)
  13. γ-Oxo Carboxylic Acids in Heterocyclic Synthesis, III. Synthesis of Biologically Active 4-Benzylamino-6-(5,5-dioxodibenzothiophen- 2-yl)-2,3,4,5-tetrahydropyridazin-3-ones
  14. Novel Nitronyl Nitroxides: Synthesis and Properties
  15. Synthesis, Spectroscopic Studies, Crystal Structure and Conformation Analysis of N-(2-Fluoro-3-methoxy)-salicylaldimine
  16. Reactivity Trends in the Reaction of Alkynes with 3-Oxo-camphorsulfonylimine
  17. A Facile One-Pot Synthesis of 1,4,7,8,9,10-Hexahydro-6H-[1]- benzothieno[2', 3', :4,5]pyrimido[1,2-b][1,2,4,5]tetrazin-6-ones
  18. An Improved Synthesis of Nickel-bis[5,6-dihydro-1,4-dioxine- 2,3-dithiolate], Ni(edo)2
  19. Synthesis and Electronic Spectra of (N-1-Naphthyl-ethylenediamine)- dichloroplatinum(II). Fluorescence of the Appended Naphthyl Substituent
https://doi.org/10.1515/znb-2002-0604
Keywords for this article
Carbonyl Cations; Mercury; Super Acids

Articles in the same Issue

  1. Neue Oxopnictate AI3MVO4: Darstellung und Kristallstruktur von A3AsO4 (A = K, Rb, Cs) und K3BiO4 / New Oxopnictates AI3MVO4: Synthesis and Crystal Structure of A3AsO4 (A = K, Rb, Cs) and K3BiO4
  2. Gold(I) Carboxylates and Fluorocarboxylates
  3. Crystal Structure of Tetrabutylammonium Carbonyltribromoplatinate(II) [(C4H9)4N][PtBr3(CO)]
  4. Die Koordination des [Hg2]2+-Kations in der konjugierten Supersäure HF/SbF5 durch CO oder H2O: Kristallstruktur von [Hg2(OH2)2][SbF6]2 · 4HF / The Co-ordination of the [Hg2]2+ Cation with CO or H2O in the Conjugated Super Acid HF/SbF5:Cryst al Structure of [Hg2 (OH2)2][SbF6]2 · 4HF
  5. Synthesis and Characterization of Tetraphenylphosphonium Tetraazidoborate
  6. Two Hydroxo Bridged Dinuclear Lanthanide Phen Complexes: [Ln2(phen)4(H2O)4(OH)2](phen)2(NO3)4 with Ln = Tm, Yb
  7. Zur Alkylierung von 2,3-Dihydro-1,3-diisopropyl-4,5- dimethylimidazol-2-yliden [1] / On the Alkylation of 2,3-Dihydro-1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene [1]
  8. Hetero-Diels-Alder Reactions of Enaminothione with Electrophilic Olefins. Synthesis of 2-Furyl Substituted 2H-Thiopyrans
  9. Preparation, Structure and Optical Properties of [CH3SC(NH2)2]3SnI5, [CH3SC(NH2)2][HSC(NH2)2]SnBr4, (CH3C5H4NCH3)PbBr3, and [C6H5CH2SC(NH2)2]4Pb3I10
  10. Crystal Structure and Conformation of N-(5-Chlorosalicylidene)- 2-hydroxy-5-chloroaniline
  11. Crystal Structure and Vibrational Behaviour of Tetraaqua-di(nicotinamide)M(II)-Saccharinates, with M(II) = Co, Ni, Zn
  12. Thermochemische Untersuchungen zu den Systemen SE2O3-SeO2 IV. Lösungskalorimetrie der SE2SexO3+2x-Phasen (SE = Nd, Sm, Y) / Thermochemical Investigations on the Systems RE2O3-SeO2 IV. Solution Calorimetry of the Phases RE2SexO3+2x(RE =Nd, Sm, Y)
  13. γ-Oxo Carboxylic Acids in Heterocyclic Synthesis, III. Synthesis of Biologically Active 4-Benzylamino-6-(5,5-dioxodibenzothiophen- 2-yl)-2,3,4,5-tetrahydropyridazin-3-ones
  14. Novel Nitronyl Nitroxides: Synthesis and Properties
  15. Synthesis, Spectroscopic Studies, Crystal Structure and Conformation Analysis of N-(2-Fluoro-3-methoxy)-salicylaldimine
  16. Reactivity Trends in the Reaction of Alkynes with 3-Oxo-camphorsulfonylimine
  17. A Facile One-Pot Synthesis of 1,4,7,8,9,10-Hexahydro-6H-[1]- benzothieno[2', 3', :4,5]pyrimido[1,2-b][1,2,4,5]tetrazin-6-ones
  18. An Improved Synthesis of Nickel-bis[5,6-dihydro-1,4-dioxine- 2,3-dithiolate], Ni(edo)2
  19. Synthesis and Electronic Spectra of (N-1-Naphthyl-ethylenediamine)- dichloroplatinum(II). Fluorescence of the Appended Naphthyl Substituent
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