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Crystal Structure of Tetrabutylammonium Carbonyltribromoplatinate(II) [(C4H9)4N][PtBr3(CO)]

  • Michael Berkei , Jamie F. Bickley and Brian T. Heaton EMAIL logo
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 57 Issue 6

Abstract

Tetrabutylammonium carbonyltribromoplatinate(II) [(C4H9)4N][PtBr3(CO)] crystallises in the monoclinic system in the space group P21/n with a = 1487.84(13), b = 897.41(8), c = 1849.6(2) pm, β = 106.558(2)° and four formula units per unit cell. The [PtBr3 (CO)]- anion is symmetrical (C2v) and almost planar with Pt-Br bond lengths of 242.40(12) pm (trans to CO), 243.25(10) pm and 242.99(9) pm (trans to Br), and a Pt-C bond length of 185.6(11) pm.

Keywords : Carbonyl Compounds
Received: 2002-2-20
Published Online: 2014-6-2
Published in Print: 2002-6-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

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https://doi.org/10.1515/znb-2002-0603
Keywords for this article
Carbonyl Compounds

Articles in the same Issue

  1. Neue Oxopnictate AI3MVO4: Darstellung und Kristallstruktur von A3AsO4 (A = K, Rb, Cs) und K3BiO4 / New Oxopnictates AI3MVO4: Synthesis and Crystal Structure of A3AsO4 (A = K, Rb, Cs) and K3BiO4
  2. Gold(I) Carboxylates and Fluorocarboxylates
  3. Crystal Structure of Tetrabutylammonium Carbonyltribromoplatinate(II) [(C4H9)4N][PtBr3(CO)]
  4. Die Koordination des [Hg2]2+-Kations in der konjugierten Supersäure HF/SbF5 durch CO oder H2O: Kristallstruktur von [Hg2(OH2)2][SbF6]2 · 4HF / The Co-ordination of the [Hg2]2+ Cation with CO or H2O in the Conjugated Super Acid HF/SbF5:Cryst al Structure of [Hg2 (OH2)2][SbF6]2 · 4HF
  5. Synthesis and Characterization of Tetraphenylphosphonium Tetraazidoborate
  6. Two Hydroxo Bridged Dinuclear Lanthanide Phen Complexes: [Ln2(phen)4(H2O)4(OH)2](phen)2(NO3)4 with Ln = Tm, Yb
  7. Zur Alkylierung von 2,3-Dihydro-1,3-diisopropyl-4,5- dimethylimidazol-2-yliden [1] / On the Alkylation of 2,3-Dihydro-1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene [1]
  8. Hetero-Diels-Alder Reactions of Enaminothione with Electrophilic Olefins. Synthesis of 2-Furyl Substituted 2H-Thiopyrans
  9. Preparation, Structure and Optical Properties of [CH3SC(NH2)2]3SnI5, [CH3SC(NH2)2][HSC(NH2)2]SnBr4, (CH3C5H4NCH3)PbBr3, and [C6H5CH2SC(NH2)2]4Pb3I10
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