Home Synthesis and Structure of Di- and Triferriostibonium Salts of the Type [Fp2SbPh2]2FeX4 and [Fp3SbR]2FeX4 (Fp = CpFe(CO)2, R = Ph, Cl; X = Cl, Br, I)
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Synthesis and Structure of Di- and Triferriostibonium Salts of the Type [Fp2SbPh2]2FeX4 and [Fp3SbR]2FeX4 (Fp = CpFe(CO)2, R = Ph, Cl; X = Cl, Br, I)

  • Ingo-Peter Lorenz EMAIL logo , Rudolf Schneider , Heinrich Nöth , Kurt Polborn and Joachim Breunig
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 56 Issue 7

The reaction of Ph2SbSiMe3 with CpFe(CO)2X (X = Cl, Br) leads to the formation of the diphenyldiferriostibonium salts [{CpFe(CO)2}2SbPh2]2FeX4, whereas PhSb(SiMe3)2 and CpFe(CO)2Cl react to give the phenyltriferriostibonium salt [{CpFe(CO)2}3Sb]2FeCl4. Sb(SiMe3)3 reacts with CpFe(CO)2X (X = Cl, Br) to yield the halogenotriferriostibonium salts [{CpFe(CO)2}3SbX]2FeX4. The chloro derivative can also be obtained: from SbCl3 with {CpFe(CO)2}2 or Na[CpFe(CO)2], and from SbCl5 and Na[CpFe(CO)2], The compounds have been characterized by spectroscopic (IR, NMR, MS), analytical (C, H) and X-ray diffraction investigations ([{CpFe(CO)2}2SbPh2]2FeBr4, [{CpFe(CO)2}3SbPh]2FeCl4, [{CpFe(CO)2}3SbCl]2FeCl4).

Keywords: Ferriostibonium Salts; Organometallated Antimony; Silyl Method
Received: 2001-5-14
Published Online: 2014-6-2
Published in Print: 2001-7-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

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https://doi.org/10.1515/znb-2001-0715
Keywords for this article
Ferriostibonium Salts; Organometallated Antimony; Silyl Method

Articles in the same Issue

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  2. Ab initio Calculations and Qualitative Valence Bond Considerations for H2N-NO2 (Nitramide) and H2N-NO (Nitrosamine)
  3. Synthese und Struktur des Kalium-tetrakis(triisopropylsilylphosphanyl)indats / Synthesis and Structure o f Potassium Tetrakis(triisopropylsilylphosphanyl)indate
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  5. The Stannides RERhSn (RE = Ho - Yb) and ScTSn (T = Pd, Pt) - Structure Refinements and 119Sn Mössbauer Spectroscopy
  6. Synthesis, Structure, and Magnetic Properties of EuAgCd and YbAgCd
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  8. Solvothermal Syntheses, Crystal Structures and Properties of Thiomolybdates with Complex Transition Metal Cations
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