Home Silyltrielane R' nHal3-n (E = Al, Ga, In; R' = SitBu2Ph): Synthesen, Charakterisierung, Strukturen [1] / Silyltrielanes R'nEHal3-n (E = Al, Ga, In; R' = SitBu2Ph): Syntheses, Characterization, Structures [1]
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Silyltrielane R' nHal3-n (E = Al, Ga, In; R' = SitBu2Ph): Synthesen, Charakterisierung, Strukturen [1] / Silyltrielanes R'nEHal3-n (E = Al, Ga, In; R' = SitBu2Ph): Syntheses, Characterization, Structures [1]

  • Nils Wiberg EMAIL logo , Thomas Blank , Hans-Wolfram Lemer , Heinrich Nöth , Tassilo Habereder and Dieter Fenske
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 56 Issue 7

Water- and oxygen-sensitive compounds of the type R ’nEHal3-n (R' = SitBu2Ph; E = Triel) with or without donors, viz. RAlBr2, R'3Al, R'GaCl2'THF, R'GaCl2, R'3Ga, R'InCl2·THF and R'3In have been synthesized by reaction of EX3 with NaSitBu2Ph (prepared for this purpose) in the absence or presence of donors. The dihalides R'EHal2 have also been obtained by reaction of R'3E with EHal3, whereas monohalides R'2EHal are not accessible via these and other routes up to date. All trielanes have been characterized by NMR and the structures of the R'3E compounds have been determined by X-ray analyses.

Keywords: Silicon; Aluminium; Gallium
Received: 2001-5-2
Published Online: 2014-6-2
Published in Print: 2001-7-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

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  1. Radikal-markierte Metallocene (M = Fe, Co). Metallocenylen verbrückte Bis(3-imidazolin-l-oxyle) / Radical Labeled M etallocenes (M = Fe, Co). M etallocenylene B ridged B is(3-im idazolin-l-oxyls)
  2. Ab initio Calculations and Qualitative Valence Bond Considerations for H2N-NO2 (Nitramide) and H2N-NO (Nitrosamine)
  3. Synthese und Struktur des Kalium-tetrakis(triisopropylsilylphosphanyl)indats / Synthesis and Structure o f Potassium Tetrakis(triisopropylsilylphosphanyl)indate
  4. Transition Metal Complexes with Sulphur Ligands, Part 151 [1]. Ligand Enforced Configurations and Low-Spin States of [FeNS4] Cores in [FeII(L)('pyS4')] Complexes with σ and σ-π Ligands (L = N2H4, pyridine, PMe3, PnPr3; 'pyS4'2- = 2,6-bis(2-mercaptophenylthiomethyl)pyridine (2-))
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  10. Collidinium- und Imidazolium-Salze Fluor-haltiger Anionen. Die Kristallstruktur von [CollH]2 [AsF6][As2 F11] (Coll = 2,4,6-Trimethylpyridin) / Collidinium and Imidazolium Salts of Fluorine-Containing Anions. The Crystal Structure of [CollH]2[AsF6][As2F11] (Coll = 2,4,6-Trimethylpyridine)
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  13. Silyltrielane R' nHal3-n (E = Al, Ga, In; R' = SitBu2Ph): Synthesen, Charakterisierung, Strukturen [1] / Silyltrielanes R'nEHal3-n (E = Al, Ga, In; R' = SitBu2Ph): Syntheses, Characterization, Structures [1]
  14. Reactions of Amino-imino-boranes with Transition Metal Halides and Substituted Transition Metal Halides
  15. Synthesis and Structure of Di- and Triferriostibonium Salts of the Type [Fp2SbPh2]2FeX4 and [Fp3SbR]2FeX4 (Fp = CpFe(CO)2, R = Ph, Cl; X = Cl, Br, I)
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https://doi.org/10.1515/znb-2001-0713
Keywords for this article
Silicon; Aluminium; Gallium

Articles in the same Issue

  1. Radikal-markierte Metallocene (M = Fe, Co). Metallocenylen verbrückte Bis(3-imidazolin-l-oxyle) / Radical Labeled M etallocenes (M = Fe, Co). M etallocenylene B ridged B is(3-im idazolin-l-oxyls)
  2. Ab initio Calculations and Qualitative Valence Bond Considerations for H2N-NO2 (Nitramide) and H2N-NO (Nitrosamine)
  3. Synthese und Struktur des Kalium-tetrakis(triisopropylsilylphosphanyl)indats / Synthesis and Structure o f Potassium Tetrakis(triisopropylsilylphosphanyl)indate
  4. Transition Metal Complexes with Sulphur Ligands, Part 151 [1]. Ligand Enforced Configurations and Low-Spin States of [FeNS4] Cores in [FeII(L)('pyS4')] Complexes with σ and σ-π Ligands (L = N2H4, pyridine, PMe3, PnPr3; 'pyS4'2- = 2,6-bis(2-mercaptophenylthiomethyl)pyridine (2-))
  5. The Stannides RERhSn (RE = Ho - Yb) and ScTSn (T = Pd, Pt) - Structure Refinements and 119Sn Mössbauer Spectroscopy
  6. Synthesis, Structure, and Magnetic Properties of EuAgCd and YbAgCd
  7. Ba16Nb5N19 - A Nitridoniobate(V) Containing Isolated [NbN4]7- and [Nb2N7]11- Units
  8. Solvothermal Syntheses, Crystal Structures and Properties of Thiomolybdates with Complex Transition Metal Cations
  9. Kristall- und elektronische Struktur von LaAlSi2 / Crystal and Electronic Structure of LaAlSi2
  10. Collidinium- und Imidazolium-Salze Fluor-haltiger Anionen. Die Kristallstruktur von [CollH]2 [AsF6][As2 F11] (Coll = 2,4,6-Trimethylpyridin) / Collidinium and Imidazolium Salts of Fluorine-Containing Anions. The Crystal Structure of [CollH]2[AsF6][As2F11] (Coll = 2,4,6-Trimethylpyridine)
  11. Hexakis(dimethylaminoxy)disiloxane: Insertion of an Oxygen Atom into the Si-Si Bond of a Disilane by Dimethylaminoxy Lithium
  12. Supersilyltrielane R nEHal3-n (E = Triel, R = SitBu3): Synthesen, Charakterisierung, Reaktionen, Strukturen [1] / Supersilyltrielanes R nEHal3-n (E = Triel, R = SitBu3): Syntheses, Characterization, Reactions, Structures [1]
  13. Silyltrielane R' nHal3-n (E = Al, Ga, In; R' = SitBu2Ph): Synthesen, Charakterisierung, Strukturen [1] / Silyltrielanes R'nEHal3-n (E = Al, Ga, In; R' = SitBu2Ph): Syntheses, Characterization, Structures [1]
  14. Reactions of Amino-imino-boranes with Transition Metal Halides and Substituted Transition Metal Halides
  15. Synthesis and Structure of Di- and Triferriostibonium Salts of the Type [Fp2SbPh2]2FeX4 and [Fp3SbR]2FeX4 (Fp = CpFe(CO)2, R = Ph, Cl; X = Cl, Br, I)
  16. Polysulfonylamine Polysulfonylamine, CXXXVIII [1], 1.1-Di(organosu!fonyl)-3,3-diorganylharnstoffe: Synthese von acht Vertretern und Kristallstruktur des Prototyps (MeSO2)2N-C(O)-NMe2 / Polysulfonylamines, CXXXVIII [1]. 1.1-Di(organosulfonyl)-3,3-diorganylureas: Synthesis of Eight Representatives and Crystal Structure of the Prototype (MeSO2)2N-C(O)-NMe2
  17. Synthesis and Bioactivities of Naturally Occurring Anthraquinones: Isochrysophanol, Isozyganein, ω-Hydroxyisochrysophanol and Morindaparvin
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