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Wechselwirkungen in Molekülkristallen, 175 [1, 2]. Kristallzüchtung und Strukturbestimmung von {Cäsium-tetraphenylimido- diphosphat}-Aggregaten mit unterschiedlicher lipophiler Umhüllung durch verschiedenartig Methyl-substituierte Phenylringe sowie relativistische DFT-Modellberechnungen zu Cäsium/Cäsium-Wechselwirkungen / Interaction in M olecular Crystals, 175 [1,2]. Crystal Growth and Structure Determination of {Cesium-tetraphenylimidodiphosphate} Aggregates with Differing Lipophilic Wrapping Due to Differently Methyl-Substituted Phenyl Rings, and Relativistic DFT-Model Calculations of Cesium/Cesium Interactions
-
Hans Bock
Published/Copyright:
June 2, 2014
Abstract
In alkali-tetraphenylimidodiphosphate ion aggregates, the size of the cation determines the curvature of the ligand and, therefore, whether hexameric ellipsoidal clusters or polymeric chains are formed. To further characterize the ligand spatial requirements, the phenyl rings have been methylsubstituted in 4-, 3/5-, 3/4- or 2,3-positions, their conformations structurally analyzed and correlated with the van der Waals substituent profiles. In addition, relativistic density functional theory potential curves have been calculated for the Cs⊕ ··· Cs⊕
interactions in simplified model systems.
Keywords : Cesium Tetraphenylimidodiphosphates; Methyl Substitution Effects; Polyion Aggregates; Crystal Structures
Received: 2000-12-21
Published Online: 2014-6-2
Published in Print: 2001-6-1
© 1946 – 2014: Verlag der Zeitschrift für Naturforschung
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Keywords for this article
Cesium Tetraphenylimidodiphosphates;
Methyl Substitution Effects;
Polyion Aggregates;
Crystal Structures
Articles in the same Issue
- A One-Dimensional Polymeric Form of the Polycation Te82+ in the Structure of Te8[Bi4Cl14]
- Preparation and Structure of Cyclic Gallium(III) and Gallium(II) 2-Amino-ethyl-amides
- New Metal-Rich Compounds NblrSi, NblrGe, and TalrSi -Synthesis, Structure, and Magnetic Properties
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- Synthesis and Solid-Phase Application of a 9-Xanthenyl Handle
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