Startseite Rubidium- und Caesium-Oxoantimonate(V) mit Kanalstrukturen. Synthesen, Kristallstrukturen und Schwingungsspektren / Rubidium and Caesium Oxoantim onates(V) with Channel Structures. Syntheses, Crystal Structures and Vibrational Spectra
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Rubidium- und Caesium-Oxoantimonate(V) mit Kanalstrukturen. Synthesen, Kristallstrukturen und Schwingungsspektren / Rubidium and Caesium Oxoantim onates(V) with Channel Structures. Syntheses, Crystal Structures and Vibrational Spectra

  • Christian Hirschle , Jürgen Rosstauscher , Franziska Emmerling und Caroline Röhr EMAIL logo
Veröffentlicht/Copyright: 2. Juni 2014
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The oxoantimonates(V) Cs2Sb4O11 (monoclinic, C2/m, a=1964.5(5), b=762.8(2), c=730.2(2) pm, β=96.276(5)°, Z=4) and A3Sb5014 (A=Rb/Cs; orthorhombic, Pbam, a=718.81 (9)/ 743.37(13), b=2447.8(2)/2625.1(5), c=733.1(2)/739.6(3) pm, Z=4) were synthesized from Sb205 and the peroxides AO2 (A=Rb, Cs). Their crystal structures were determined on the basis of single crystal diffractometer data. The structures are composed of three-dimensional nets of [SbO6 ]octahedra connected via common corners and edges, with the A cations incorporated in the resulting channel systems. The Raman spectra of the compounds are discussed in relation with the different type of oxide connectivites in the oxoantimonate anions.

Received: 2000-10-20
Published Online: 2014-6-2
Published in Print: 2001-2-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Artikel in diesem Heft

  1. Wechselwirkungen in Molekülkristallen, 167 [1, 2]. Kristallzüchtung und Strukturbestimmung von σ-Donator/Akzeptor- Komplexen zwischen 1,4-Dioxan und den Polyiod-Molekülen I2,I2C=CI2, (IC)4S sowie (IC)4NR (R = H, CH3) / Interaction in Molecular Crystals, 167 [1, 2]. C rystallization and Structure Determination of σ -Donor/Acceptor Complexes between 1,4-Dioxane and the Polyiodine Molecules I2,I2C=CI2, (IC)4S and (IC)4NR (R = H, CH3)
  2. Reaction between Yttrium Nitrate and 2,2':6',2"-Terpyridine (terpy) in MeCN: Preparation, Crystal Structures and Spectroscopic Characterization of [Y (NO3)3(terpy)(H2O )] and [Y(NO3)3(terpy)(H2O )] · terpy · 3 MeCN
  3. Zur Acylierung von 2,3-Dihydro-l,3-diisopropyl-4,5- dimethylimidazol-2-yliden [1] / Acylation o f 2,3-Dihydro-l,3-diisopropyl-4,5-dimethylimidazol-2-ylidene [1]
  4. Syntheses and Characterization of 1-Haloazagermatranes
  5. Mono-and Bis(cyclopentadienyl)hafnium(IV) Derivatives with Higher Fatty Acids
  6. Remarkably Large 15N, 13C and 18O Isotope NMR Shifts of the Mono-coordinate Phosphorus Atoms in the Compounds (Me3 Si)iPrNCP, K+[iPrNCP]-and KOCP · 2 DME (DME = 1,2-Dimethoxyethane)
  7. Wechselwirkungen in Molekülkristallen, 168 [1,2]. σ-Donator/Akzeptor-Komplexe {HCl3···Xe }(X = Cl, Br , I ) von Triiodmethan in Tetraphenylphosphoniumhalogeniden / Interaction in Molecular Crystals, 168 [1, 2]. σ-Donor/Acceptor Complexes {HCl3 ···X} (X = Cl , Br , I ) of Triiodomethane in Tetraphenylphosphonium Halides
  8. Darstellung und Charakterisierung von Bis(trichlorsilyl)phenylamin und 2,2,4,4-TetrachIor-1,3-diphenyl-[ 1,3,2,4]diazadisiletidin / Preparation and Characterization of Bis(trichlorosilyl)phenylamine and 2,2,4,4-Tetrachloro-1,3-diphenyl-[ 1,3,2,4]diazadisiletidine
  9. Rubidium- und Caesium-Oxoantimonate(V) mit Kanalstrukturen. Synthesen, Kristallstrukturen und Schwingungsspektren / Rubidium and Caesium Oxoantim onates(V) with Channel Structures. Syntheses, Crystal Structures and Vibrational Spectra
  10. Synthese und Charakterisierung von cis- und trans-Dicyclohexyl-3,3′,4,4′- tetracarbonsäuren und ihren Dianhydriden / Syntheses and Characterization of cis- and trans-Dicyclohexyl-3,3′,4,4′- tetracarboxylic Acids and their Dianhydrides
  11. Darstellung und Strukturelle Charakterisierung von cis-und trans- Dicyclohexyl-3,3′,4,4′-tetracarbonsäure-tetramethylestern / Preparation and Structural Characterization of cis- and trans-Tetramethyl Dicyclohexyl-3,3′,4,4′-tetracarboxylates
  12. Spectro-Electrochemistry of Diethyldithiocarbamate Complexes of Ni(II), Pd(II) and Pt(II)
  13. Darstellung und Kristallstruktur von Cs6Cl4O / Preparation and Crystal Structure of Cs6Cl4O
  14. Preparation and Characterization of 4-[4-(Dimethylamino)styryl]-l-methyl- pyridinium Lead Triiodide and its Tribromide Analog
  15. The Crystal and Molecular Structure of (μ-Oxo)bis{chloro(methyl)thienyl- tellurium(IV)}
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