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peri-Interactions in Naphthalenes, 4 [1]. Hypercoordination in 8-Dimethylamino-naphth-1-yl Phosphorus Compounds

  • Günter Paulus Schiemenz , Simon Pörksen and Christian Näther
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 55 Issue 9

In an 8-dimethylamino-naphth-1-yl-phosphorane a dative N→P bond forms in spite of the spacer properties of the naphthalene skeleton. Its “normal” length, 213.2 pm, much too short to fill the perispace, forces the C10 skeleton into severe distortion. In the light of these properties peri distances d(N-P/Si) ≫250 pm in 8-dimethylamino-naphth-1-yl-phosphines, -silanes etc. are recognized as evidence for steric hindrance

: Hypercoordination; Bond Length Alterations; Sub-van der Waals Interatomic Distances
Received: 2000-5-25
Published Online: 2014-6-2
Published in Print: 2000-9-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Wechselwirkungen in Molekülkristallen, 156 [1, 2]. Kristallzüchtung und Strukturbestimmung von (Imidodiphosphat)-Alkalisalzen mit Kationen niedriger und hoher Koordinationszahlen / Interaction in Molecular Crystals, 156 [1, 2]. Crystal Growth and Structure Determination of Alkali(imidodiphosphate) Salts with Cations of Low and High Coordination Numbers
  2. Wechselwirkungen in Molekülkristallen, 157 [1, 2]. Mischkristallzüchtung und Strukturbestimmungen von Tetra(3,4-dimethylphenyl)-imidodiphosphat-Salzen mit Alkalikation- Verhältnissen K⊕/Rb⊕(1:5) und Rb⊕/Cs⊕(1:1) / Interaction in Molecular Crystals, 157 [1, 2]. Mixed Crystal Growth and Structure Determinations of Tetrakis(3,4-dimethylphenyl)-imidodiphosphate Salts with Alkali Cation Ratios K⊕/Rb⊕ (1:5) and Rb⊕/Cs⊕ (1:1)
  3. Synthesis, Crystal Structure and Magnetic Properties of a (μ-Hydroxo)(μ-Pyrazolato) Dicopper(II) Complex
  4. Polysulfonylamine, CXXVIII [1]. Disulfonylamido-Gold(I)-Komplexe mit Tetrahydrothiophen als Ligand / Polysulfonylamines, CXXVIII. Disulfonylamido-gold(I) Complexes with Tetrahydrothiophene as Ligand
  5. 1,1′-Di(tert-butyl)metallocenium Cations. The X-Ray Crystal Structures of [M(C5H4tBu)2]PF6 (M = Fe, Co) and [Co (C5H4t Bu)2]2CoCl4
  6. Metal Complexes of Biologically Important Ligands, CXXV [1]. Palladium(II) and Platinum(II) Complexes of Quinine Derivatives and in vitro Tests
  7. New Indides EuAuIn2, EuPdIn4, GdRhIn2, YbRhIn4, and YbPdIn4
  8. peri-Interactions in Naphthalenes, 4 [1]. Hypercoordination in 8-Dimethylamino-naphth-1-yl Phosphorus Compounds
  9. Metallkomplexe mit biologisch wichtigen Liganden, CXXVIII [1], Palladium(II)-Komplexe mit deprotonierten Peptidestern als N,N′-Chelatliganden / Metal Complexes with Biologically Important Ligands, CXXVIII [1]. Palladium(II) Complexes with Deprotonated Peptide Esters as N,N′-Chelate Ligands
  10. Structural and Spectral Studies of Palladium (II) Complexes of Pyridil bis{3-Piperidyl-, bis{Hexamethyleneiminyl-, bis{N(4)-Diethyl- and bis{N(4)-Dipropylthiosemicarbazone}
  11. Synthesis, Crystal Structures and Properties of the Polychalcogenides Manganese-tris(1,2-ethanediamine)-triselenide [Mn(en)3]Se3 and Manganese-tris(1,2-ethanediamine)-monotellurodiselenide [Mn(en)3 ]TeSe2
  12. Lewis-Säure/Base Addukte von TiCl4 und Methylpyridinen / Lewis Acid/Base Adducts of TiCl4 and Methylpyridines
  13. Darstellung und Charakterisierung des Silber(I,II,III)-oxidclathrates Ag7O8HCO3 / Synthesis and Characterization of the Silver(I,II,III) Oxide Clathrate Ag7O8HCO3
  14. ERRATUM
https://doi.org/10.1515/znb-2000-0908

Articles in the same Issue

  1. Wechselwirkungen in Molekülkristallen, 156 [1, 2]. Kristallzüchtung und Strukturbestimmung von (Imidodiphosphat)-Alkalisalzen mit Kationen niedriger und hoher Koordinationszahlen / Interaction in Molecular Crystals, 156 [1, 2]. Crystal Growth and Structure Determination of Alkali(imidodiphosphate) Salts with Cations of Low and High Coordination Numbers
  2. Wechselwirkungen in Molekülkristallen, 157 [1, 2]. Mischkristallzüchtung und Strukturbestimmungen von Tetra(3,4-dimethylphenyl)-imidodiphosphat-Salzen mit Alkalikation- Verhältnissen K⊕/Rb⊕(1:5) und Rb⊕/Cs⊕(1:1) / Interaction in Molecular Crystals, 157 [1, 2]. Mixed Crystal Growth and Structure Determinations of Tetrakis(3,4-dimethylphenyl)-imidodiphosphate Salts with Alkali Cation Ratios K⊕/Rb⊕ (1:5) and Rb⊕/Cs⊕ (1:1)
  3. Synthesis, Crystal Structure and Magnetic Properties of a (μ-Hydroxo)(μ-Pyrazolato) Dicopper(II) Complex
  4. Polysulfonylamine, CXXVIII [1]. Disulfonylamido-Gold(I)-Komplexe mit Tetrahydrothiophen als Ligand / Polysulfonylamines, CXXVIII. Disulfonylamido-gold(I) Complexes with Tetrahydrothiophene as Ligand
  5. 1,1′-Di(tert-butyl)metallocenium Cations. The X-Ray Crystal Structures of [M(C5H4tBu)2]PF6 (M = Fe, Co) and [Co (C5H4t Bu)2]2CoCl4
  6. Metal Complexes of Biologically Important Ligands, CXXV [1]. Palladium(II) and Platinum(II) Complexes of Quinine Derivatives and in vitro Tests
  7. New Indides EuAuIn2, EuPdIn4, GdRhIn2, YbRhIn4, and YbPdIn4
  8. peri-Interactions in Naphthalenes, 4 [1]. Hypercoordination in 8-Dimethylamino-naphth-1-yl Phosphorus Compounds
  9. Metallkomplexe mit biologisch wichtigen Liganden, CXXVIII [1], Palladium(II)-Komplexe mit deprotonierten Peptidestern als N,N′-Chelatliganden / Metal Complexes with Biologically Important Ligands, CXXVIII [1]. Palladium(II) Complexes with Deprotonated Peptide Esters as N,N′-Chelate Ligands
  10. Structural and Spectral Studies of Palladium (II) Complexes of Pyridil bis{3-Piperidyl-, bis{Hexamethyleneiminyl-, bis{N(4)-Diethyl- and bis{N(4)-Dipropylthiosemicarbazone}
  11. Synthesis, Crystal Structures and Properties of the Polychalcogenides Manganese-tris(1,2-ethanediamine)-triselenide [Mn(en)3]Se3 and Manganese-tris(1,2-ethanediamine)-monotellurodiselenide [Mn(en)3 ]TeSe2
  12. Lewis-Säure/Base Addukte von TiCl4 und Methylpyridinen / Lewis Acid/Base Adducts of TiCl4 and Methylpyridines
  13. Darstellung und Charakterisierung des Silber(I,II,III)-oxidclathrates Ag7O8HCO3 / Synthesis and Characterization of the Silver(I,II,III) Oxide Clathrate Ag7O8HCO3
  14. ERRATUM
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