Startseite Darstellung und Kristallstruktur von (n-Bu4N)[ReBr5Py] / Synthesis and Crystal Structure of (n-Bu4N)[ReBr5Py]
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Darstellung und Kristallstruktur von (n-Bu4N)[ReBr5Py] / Synthesis and Crystal Structure of (n-Bu4N)[ReBr5Py]

  • B. v. Malottki und W. Preetz EMAIL logo
Veröffentlicht/Copyright: 2. Juni 2014
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By reaction of (n-Bu4N)2[ReBr6] with pyridine and (n-Bu4N)BH4 in dichloromethane various bromo-pyridine-rhenium(III) complexes are formed which can be separated by chromatography. Electrochemical oxidation of (n-Bu4N)2[ReBr5Py] leads to (n-Bu4N)[ReBr5Py]. X-ray structure determination on a single crystal has been performed of (n-Bu4N)[ReBr5Py] (monoclinic, space group P21/n a = 11,248(5), b = 17,192(5), c = 15,206(5) Å, β = 97,600(5)°, Z = 4).

Received: 2000-3-24
Published Online: 2014-6-2
Published in Print: 2000-6-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

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