Home Physical Sciences Synthesis and Coordination Properties of 6,6'-Dimesityl-2,2'-bipyridine
Article
Licensed
Unlicensed Requires Authentication

Synthesis and Coordination Properties of 6,6'-Dimesityl-2,2'-bipyridine

  • Michael Schmittel , Andrea Ganz , Wolfdieter A. Schenk and Michael Hagel
Published/Copyright: June 2, 2014
Become an author with De Gruyter Brill
Author Information Explore this Subject
Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 54 Issue 4

A synthetic route to 6,6′-dimesityl-2,2′-bipyridine is presented that involves a Suzuki coupling of 6,6′-dibromo-2,2′-bipyridine with mesityl boronic acid. The new sterically crowded ligand is investigated by X-ray analysis and its coordination behavior in the presence of copper(I) is examined.

Keywords : Suzuki Coupling; Copper(I) Complex; X -Ray Data
Received: 1999-1-11
Published Online: 2014-6-2
Published in Print: 1999-4-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Synthese und Eigenschaften von 1,3-Diisopropyl-4,5-dimethylimidazolium- 2-carboxylat. Ein stabiles Carben-Addukt des Kohlendioxids [1] / Synthesis and Properties of 1,3-Diisopropyl-4,5-dimethylimidazolium -2-carboxylate. A Stable Carbene Adduct of Carbon Dioxide [1]
  2. 1,3-Diisopropyl-4,5-dimethylimidazolium-2-N,N’-diisopropylamidinat, ein neuartiges Retain [1] / 1,3-Diisopropyl-4,5-dimethylimidazolium-2-N,N'-diisopropylamidinate, a Novel Betaine [1]
  3. Komplexe Chalkogenide der IVa Metalle mit niedrigdimensionalen anionischen Partialstrukturen. Darstellung und Kristallstruktur von K2ZrTe3 und Rb2ZrTe3 / Complex Chalcogenides of the IVa Metals with Low Dimensional Anionic Partial Structures. Preparation and Crystal Structures of K2ZrTe3 and Rb2ZrTe3
  4. The Crystal Structure of Dimethyl (2Z, 6Z)-2,7-bis-(benzyloxycarbonylamino) octa-2,6-diendioate: A Useful Precursor for Optically Pure 2,7-Diaminosuberic Acid
  5. Structure of Tl(18-crown-6){Cl3CC(O)N P(O)(OCH3)2}: Coordination of the Ionic Multidentate Weakens the Interaction of the Metal Atom with the Crown Ether
  6. Crystal and Molecular Structure of Two Tetradentate “Oxime-and-Amide” Ligands
  7. Dimers [Al2N6]12- and Chains 1∞[AlN4/23-] in the Crystal Structures of Ca6[Al2N6] and Ba3[Al2N4]
  8. Metallation of Calix[4]arene with Thulium Diiodide, TmI2(DME)3: Molecular Structure of [(5,11,17,23-Tetra-tert-butyl-25,27-dioxo-26,28- dimethoxycalix[4]arene)thulium(III)iodide(diethyl etherate)]
  9. Zur Kristallchemie des ersten Blei-Zink-Silicium-Telluroxids: PbZn4SiTeO10 / On the Crystal Chemistry of the First Lead Zinc Silicon Tellurium Oxyde PbZn4SiTeO10
  10. Syntheses, Structures, and Spectroscopic Properties of Alkoxide, Hydroxide, and Siloxide Complexes with (η3-Allyl)Mo Moieties
  11. Dichloro[bis(η5-2,4-cyclopentadien-l-yl)alkylphosphan]zirconium: PR(C5H4)2ZrCl2; R = Me, Et, iPr, tBu / Dichloro[bis(η5-2 ,4 -cyclopentadien-l-yl)alkylphosphine]zirconium: PR(C5H4)2ZrCl2; R = Me, Et, iPr, tBu
  12. Untersuchungen zum quasibinären System Bi2Te3/BiBr3 / Investigations on the Pseudobinary System Bi2Te3/BiBr3
  13. Wechselwirkungen in Molekülkristallen, 153 [1 - 3]. Wirt/Gast-Einschlußverbindungen von N,N'-Ditosyl-p-phenylendiamin-Derivaten: Die Kristallstrukturen von N,N'-Di(4-ethyl-benzosulfuryl)-p-phenylendiamin und seinen Aggregaten mit Aceton und Cyclopentanon / Interactions in Molecular Crystals, 153 [1 - 3]. Host/Guest-Inclusion Compounds of N,N'-Ditosyl-p-phenylenediamine Derivatives: The Crystal Structures of N,N'-Di(4-ethyl-benzosulfuryl)-p-phenylenediamine and its Aggregates with Acetone and Cyclopentanone
  14. Wechselwirkungen in Molekülkristallen, 154 [1 - 3]. Wirt/Gast-Einschlußverbindungen von N,N'-Ditosyl-p-phenylendiamin- Derivaten: Die Kristallstrukturen von N,N'-Di(4-nitro-benzosulfuryl)-p- phenylendiamin und seinen Wasserstoffbrücken-Addukten mit Cyclopentanon, Cyclohexanon, Tetrahydrofuran, N,N-Dimethylformamidsowie Pyridin / Interactions in Molecular Crystals, 154 [1 - 3]. Host/Guest-Inclusion Compounds of N,N'-Ditosyl-p-phenylenediamine Derivatives: The Crystal Structures of N,N'-Di(4- nitro-benzosulfuryl)-p-phenylenediamine and its Hydrogen-Bonded Adducts with Cyclopentanone, Cyclohexanone, Tetrahydrofurane, N,N-Dimethylformamide as well as Pyridine
  15. Low Temperature Crystal Growth and Structure of Ordered Ba7F12Cl2
  16. Darstellung chiraler heterocyclischer β-Aminosäureester / Preparation of Chiral Heterocyclic Esters of β-Amino Acids
  17. Reaktionen von Isochinolinium-Salzen mit Hydroxylamin-Derivaten, 2. Mitteilung N-(Alkyl)- und N-(Aryl)-substituierte Verbindungen / Reactions of Isoquinolinium Salts with Hydroxylamine Derivatives, 2nd Communication N-(Alkyl) and N-(Aryl) Substituted Compounds
  18. Montmorillonite K-10 Catalyzed Knoevenagel Condensation under Microwave Irradiation in Solventless System
  19. New Monoterpene Glycosides from Paeonia emodi
  20. Synthese neuer Pyridin-, Pyrindin- bzw. Isochinolin-substituierter α- und β-C-Nukleoside der 2-Desoxy-D-ribose / Synthesis of Novel Pyridine-, Pyrindine- and Isoquinoline-Substituted α- and β-C-Nucleosides of 2-Deoxy-D-ribose
  21. Synthesis and Coordination Properties of 6,6'-Dimesityl-2,2'-bipyridine
  22. A Polyhydroxylated Cyclopentene: A Useful Synthon toward the Synthesis of Carbocyclic D-Fructofuranoid
  23. Alquds, a New Flavone Glycoside from Calamintha incana
https://doi.org/10.1515/znb-1999-0421
Keywords for this article
Suzuki Coupling; Copper(I) Complex; X -Ray Data

Articles in the same Issue

  1. Synthese und Eigenschaften von 1,3-Diisopropyl-4,5-dimethylimidazolium- 2-carboxylat. Ein stabiles Carben-Addukt des Kohlendioxids [1] / Synthesis and Properties of 1,3-Diisopropyl-4,5-dimethylimidazolium -2-carboxylate. A Stable Carbene Adduct of Carbon Dioxide [1]
  2. 1,3-Diisopropyl-4,5-dimethylimidazolium-2-N,N’-diisopropylamidinat, ein neuartiges Retain [1] / 1,3-Diisopropyl-4,5-dimethylimidazolium-2-N,N'-diisopropylamidinate, a Novel Betaine [1]
  3. Komplexe Chalkogenide der IVa Metalle mit niedrigdimensionalen anionischen Partialstrukturen. Darstellung und Kristallstruktur von K2ZrTe3 und Rb2ZrTe3 / Complex Chalcogenides of the IVa Metals with Low Dimensional Anionic Partial Structures. Preparation and Crystal Structures of K2ZrTe3 and Rb2ZrTe3
  4. The Crystal Structure of Dimethyl (2Z, 6Z)-2,7-bis-(benzyloxycarbonylamino) octa-2,6-diendioate: A Useful Precursor for Optically Pure 2,7-Diaminosuberic Acid
  5. Structure of Tl(18-crown-6){Cl3CC(O)N P(O)(OCH3)2}: Coordination of the Ionic Multidentate Weakens the Interaction of the Metal Atom with the Crown Ether
  6. Crystal and Molecular Structure of Two Tetradentate “Oxime-and-Amide” Ligands
  7. Dimers [Al2N6]12- and Chains 1∞[AlN4/23-] in the Crystal Structures of Ca6[Al2N6] and Ba3[Al2N4]
  8. Metallation of Calix[4]arene with Thulium Diiodide, TmI2(DME)3: Molecular Structure of [(5,11,17,23-Tetra-tert-butyl-25,27-dioxo-26,28- dimethoxycalix[4]arene)thulium(III)iodide(diethyl etherate)]
  9. Zur Kristallchemie des ersten Blei-Zink-Silicium-Telluroxids: PbZn4SiTeO10 / On the Crystal Chemistry of the First Lead Zinc Silicon Tellurium Oxyde PbZn4SiTeO10
  10. Syntheses, Structures, and Spectroscopic Properties of Alkoxide, Hydroxide, and Siloxide Complexes with (η3-Allyl)Mo Moieties
  11. Dichloro[bis(η5-2,4-cyclopentadien-l-yl)alkylphosphan]zirconium: PR(C5H4)2ZrCl2; R = Me, Et, iPr, tBu / Dichloro[bis(η5-2 ,4 -cyclopentadien-l-yl)alkylphosphine]zirconium: PR(C5H4)2ZrCl2; R = Me, Et, iPr, tBu
  12. Untersuchungen zum quasibinären System Bi2Te3/BiBr3 / Investigations on the Pseudobinary System Bi2Te3/BiBr3
  13. Wechselwirkungen in Molekülkristallen, 153 [1 - 3]. Wirt/Gast-Einschlußverbindungen von N,N'-Ditosyl-p-phenylendiamin-Derivaten: Die Kristallstrukturen von N,N'-Di(4-ethyl-benzosulfuryl)-p-phenylendiamin und seinen Aggregaten mit Aceton und Cyclopentanon / Interactions in Molecular Crystals, 153 [1 - 3]. Host/Guest-Inclusion Compounds of N,N'-Ditosyl-p-phenylenediamine Derivatives: The Crystal Structures of N,N'-Di(4-ethyl-benzosulfuryl)-p-phenylenediamine and its Aggregates with Acetone and Cyclopentanone
  14. Wechselwirkungen in Molekülkristallen, 154 [1 - 3]. Wirt/Gast-Einschlußverbindungen von N,N'-Ditosyl-p-phenylendiamin- Derivaten: Die Kristallstrukturen von N,N'-Di(4-nitro-benzosulfuryl)-p- phenylendiamin und seinen Wasserstoffbrücken-Addukten mit Cyclopentanon, Cyclohexanon, Tetrahydrofuran, N,N-Dimethylformamidsowie Pyridin / Interactions in Molecular Crystals, 154 [1 - 3]. Host/Guest-Inclusion Compounds of N,N'-Ditosyl-p-phenylenediamine Derivatives: The Crystal Structures of N,N'-Di(4- nitro-benzosulfuryl)-p-phenylenediamine and its Hydrogen-Bonded Adducts with Cyclopentanone, Cyclohexanone, Tetrahydrofurane, N,N-Dimethylformamide as well as Pyridine
  15. Low Temperature Crystal Growth and Structure of Ordered Ba7F12Cl2
  16. Darstellung chiraler heterocyclischer β-Aminosäureester / Preparation of Chiral Heterocyclic Esters of β-Amino Acids
  17. Reaktionen von Isochinolinium-Salzen mit Hydroxylamin-Derivaten, 2. Mitteilung N-(Alkyl)- und N-(Aryl)-substituierte Verbindungen / Reactions of Isoquinolinium Salts with Hydroxylamine Derivatives, 2nd Communication N-(Alkyl) and N-(Aryl) Substituted Compounds
  18. Montmorillonite K-10 Catalyzed Knoevenagel Condensation under Microwave Irradiation in Solventless System
  19. New Monoterpene Glycosides from Paeonia emodi
  20. Synthese neuer Pyridin-, Pyrindin- bzw. Isochinolin-substituierter α- und β-C-Nukleoside der 2-Desoxy-D-ribose / Synthesis of Novel Pyridine-, Pyrindine- and Isoquinoline-Substituted α- and β-C-Nucleosides of 2-Deoxy-D-ribose
  21. Synthesis and Coordination Properties of 6,6'-Dimesityl-2,2'-bipyridine
  22. A Polyhydroxylated Cyclopentene: A Useful Synthon toward the Synthesis of Carbocyclic D-Fructofuranoid
  23. Alquds, a New Flavone Glycoside from Calamintha incana
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2025 De Gruyter Brill
Downloaded on 19.12.2025 from https://www.degruyterbrill.com/document/doi/10.1515/znb-1999-0421/html?srsltid=AfmBOopakolGGy-hvU2IxTsfqNs1-algXed5eqEWZcQuCmYakjZJ7g_6
Scroll to top button