Single crystals of the new lead zinc silicon tellurium oxide PbZn4SiTeO10 have been prepared by solid state reaction in air. The compound is colourless and crystallizes in orthorhombic symmetry, space group D162h Pnma, with the cell parameters: a = 6.542 (5), b = 15.624(4), c = 8.280(4) Å, Z = 4. The structure has been determined from a single crystal X-ray study and refined to the conventional values R = 0.032 and wR(F2) = 0.050. Zn2+ and Si4+ show tetrahedral and Te6+ octahedral coordination by O2-.The crystal structure is dominated by a 3∞ [Zn4O10]12- framework with isolated TeO66+ and SiO44+ polyhedra. Pb2+ ions are incorporated in the network. The centres of negative charge of the lone pairs of Pb2+ are estimated by calculations of the Coulomb term of the lattice energy
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Articles in the same Issue
- Synthese und Eigenschaften von 1,3-Diisopropyl-4,5-dimethylimidazolium- 2-carboxylat. Ein stabiles Carben-Addukt des Kohlendioxids [1] / Synthesis and Properties of 1,3-Diisopropyl-4,5-dimethylimidazolium -2-carboxylate. A Stable Carbene Adduct of Carbon Dioxide [1]
- 1,3-Diisopropyl-4,5-dimethylimidazolium-2-N,N’-diisopropylamidinat, ein neuartiges Retain [1] / 1,3-Diisopropyl-4,5-dimethylimidazolium-2-N,N'-diisopropylamidinate, a Novel Betaine [1]
- Komplexe Chalkogenide der IVa Metalle mit niedrigdimensionalen anionischen Partialstrukturen. Darstellung und Kristallstruktur von K2ZrTe3 und Rb2ZrTe3 / Complex Chalcogenides of the IVa Metals with Low Dimensional Anionic Partial Structures. Preparation and Crystal Structures of K2ZrTe3 and Rb2ZrTe3
- The Crystal Structure of Dimethyl (2Z, 6Z)-2,7-bis-(benzyloxycarbonylamino) octa-2,6-diendioate: A Useful Precursor for Optically Pure 2,7-Diaminosuberic Acid
- Structure of Tl(18-crown-6){Cl3CC(O)N P(O)(OCH3)2}: Coordination of the Ionic Multidentate Weakens the Interaction of the Metal Atom with the Crown Ether
- Crystal and Molecular Structure of Two Tetradentate “Oxime-and-Amide” Ligands
- Dimers [Al2N6]12- and Chains 1∞[AlN4/23-] in the Crystal Structures of Ca6[Al2N6] and Ba3[Al2N4]
- Metallation of Calix[4]arene with Thulium Diiodide, TmI2(DME)3: Molecular Structure of [(5,11,17,23-Tetra-tert-butyl-25,27-dioxo-26,28- dimethoxycalix[4]arene)thulium(III)iodide(diethyl etherate)]
- Zur Kristallchemie des ersten Blei-Zink-Silicium-Telluroxids: PbZn4SiTeO10 / On the Crystal Chemistry of the First Lead Zinc Silicon Tellurium Oxyde PbZn4SiTeO10
- Syntheses, Structures, and Spectroscopic Properties of Alkoxide, Hydroxide, and Siloxide Complexes with (η3-Allyl)Mo Moieties
- Dichloro[bis(η5-2,4-cyclopentadien-l-yl)alkylphosphan]zirconium: PR(C5H4)2ZrCl2; R = Me, Et, iPr, tBu / Dichloro[bis(η5-2 ,4 -cyclopentadien-l-yl)alkylphosphine]zirconium: PR(C5H4)2ZrCl2; R = Me, Et, iPr, tBu
- Untersuchungen zum quasibinären System Bi2Te3/BiBr3 / Investigations on the Pseudobinary System Bi2Te3/BiBr3
- Wechselwirkungen in Molekülkristallen, 153 [1 - 3]. Wirt/Gast-Einschlußverbindungen von N,N'-Ditosyl-p-phenylendiamin-Derivaten: Die Kristallstrukturen von N,N'-Di(4-ethyl-benzosulfuryl)-p-phenylendiamin und seinen Aggregaten mit Aceton und Cyclopentanon / Interactions in Molecular Crystals, 153 [1 - 3]. Host/Guest-Inclusion Compounds of N,N'-Ditosyl-p-phenylenediamine Derivatives: The Crystal Structures of N,N'-Di(4-ethyl-benzosulfuryl)-p-phenylenediamine and its Aggregates with Acetone and Cyclopentanone
- Wechselwirkungen in Molekülkristallen, 154 [1 - 3]. Wirt/Gast-Einschlußverbindungen von N,N'-Ditosyl-p-phenylendiamin- Derivaten: Die Kristallstrukturen von N,N'-Di(4-nitro-benzosulfuryl)-p- phenylendiamin und seinen Wasserstoffbrücken-Addukten mit Cyclopentanon, Cyclohexanon, Tetrahydrofuran, N,N-Dimethylformamidsowie Pyridin / Interactions in Molecular Crystals, 154 [1 - 3]. Host/Guest-Inclusion Compounds of N,N'-Ditosyl-p-phenylenediamine Derivatives: The Crystal Structures of N,N'-Di(4- nitro-benzosulfuryl)-p-phenylenediamine and its Hydrogen-Bonded Adducts with Cyclopentanone, Cyclohexanone, Tetrahydrofurane, N,N-Dimethylformamide as well as Pyridine
- Low Temperature Crystal Growth and Structure of Ordered Ba7F12Cl2
- Darstellung chiraler heterocyclischer β-Aminosäureester / Preparation of Chiral Heterocyclic Esters of β-Amino Acids
- Reaktionen von Isochinolinium-Salzen mit Hydroxylamin-Derivaten, 2. Mitteilung N-(Alkyl)- und N-(Aryl)-substituierte Verbindungen / Reactions of Isoquinolinium Salts with Hydroxylamine Derivatives, 2nd Communication N-(Alkyl) and N-(Aryl) Substituted Compounds
- Montmorillonite K-10 Catalyzed Knoevenagel Condensation under Microwave Irradiation in Solventless System
- New Monoterpene Glycosides from Paeonia emodi
- Synthese neuer Pyridin-, Pyrindin- bzw. Isochinolin-substituierter α- und β-C-Nukleoside der 2-Desoxy-D-ribose / Synthesis of Novel Pyridine-, Pyrindine- and Isoquinoline-Substituted α- and β-C-Nucleosides of 2-Deoxy-D-ribose
- Synthesis and Coordination Properties of 6,6'-Dimesityl-2,2'-bipyridine
- A Polyhydroxylated Cyclopentene: A Useful Synthon toward the Synthesis of Carbocyclic D-Fructofuranoid
- Alquds, a New Flavone Glycoside from Calamintha incana
Articles in the same Issue
- Synthese und Eigenschaften von 1,3-Diisopropyl-4,5-dimethylimidazolium- 2-carboxylat. Ein stabiles Carben-Addukt des Kohlendioxids [1] / Synthesis and Properties of 1,3-Diisopropyl-4,5-dimethylimidazolium -2-carboxylate. A Stable Carbene Adduct of Carbon Dioxide [1]
- 1,3-Diisopropyl-4,5-dimethylimidazolium-2-N,N’-diisopropylamidinat, ein neuartiges Retain [1] / 1,3-Diisopropyl-4,5-dimethylimidazolium-2-N,N'-diisopropylamidinate, a Novel Betaine [1]
- Komplexe Chalkogenide der IVa Metalle mit niedrigdimensionalen anionischen Partialstrukturen. Darstellung und Kristallstruktur von K2ZrTe3 und Rb2ZrTe3 / Complex Chalcogenides of the IVa Metals with Low Dimensional Anionic Partial Structures. Preparation and Crystal Structures of K2ZrTe3 and Rb2ZrTe3
- The Crystal Structure of Dimethyl (2Z, 6Z)-2,7-bis-(benzyloxycarbonylamino) octa-2,6-diendioate: A Useful Precursor for Optically Pure 2,7-Diaminosuberic Acid
- Structure of Tl(18-crown-6){Cl3CC(O)N P(O)(OCH3)2}: Coordination of the Ionic Multidentate Weakens the Interaction of the Metal Atom with the Crown Ether
- Crystal and Molecular Structure of Two Tetradentate “Oxime-and-Amide” Ligands
- Dimers [Al2N6]12- and Chains 1∞[AlN4/23-] in the Crystal Structures of Ca6[Al2N6] and Ba3[Al2N4]
- Metallation of Calix[4]arene with Thulium Diiodide, TmI2(DME)3: Molecular Structure of [(5,11,17,23-Tetra-tert-butyl-25,27-dioxo-26,28- dimethoxycalix[4]arene)thulium(III)iodide(diethyl etherate)]
- Zur Kristallchemie des ersten Blei-Zink-Silicium-Telluroxids: PbZn4SiTeO10 / On the Crystal Chemistry of the First Lead Zinc Silicon Tellurium Oxyde PbZn4SiTeO10
- Syntheses, Structures, and Spectroscopic Properties of Alkoxide, Hydroxide, and Siloxide Complexes with (η3-Allyl)Mo Moieties
- Dichloro[bis(η5-2,4-cyclopentadien-l-yl)alkylphosphan]zirconium: PR(C5H4)2ZrCl2; R = Me, Et, iPr, tBu / Dichloro[bis(η5-2 ,4 -cyclopentadien-l-yl)alkylphosphine]zirconium: PR(C5H4)2ZrCl2; R = Me, Et, iPr, tBu
- Untersuchungen zum quasibinären System Bi2Te3/BiBr3 / Investigations on the Pseudobinary System Bi2Te3/BiBr3
- Wechselwirkungen in Molekülkristallen, 153 [1 - 3]. Wirt/Gast-Einschlußverbindungen von N,N'-Ditosyl-p-phenylendiamin-Derivaten: Die Kristallstrukturen von N,N'-Di(4-ethyl-benzosulfuryl)-p-phenylendiamin und seinen Aggregaten mit Aceton und Cyclopentanon / Interactions in Molecular Crystals, 153 [1 - 3]. Host/Guest-Inclusion Compounds of N,N'-Ditosyl-p-phenylenediamine Derivatives: The Crystal Structures of N,N'-Di(4-ethyl-benzosulfuryl)-p-phenylenediamine and its Aggregates with Acetone and Cyclopentanone
- Wechselwirkungen in Molekülkristallen, 154 [1 - 3]. Wirt/Gast-Einschlußverbindungen von N,N'-Ditosyl-p-phenylendiamin- Derivaten: Die Kristallstrukturen von N,N'-Di(4-nitro-benzosulfuryl)-p- phenylendiamin und seinen Wasserstoffbrücken-Addukten mit Cyclopentanon, Cyclohexanon, Tetrahydrofuran, N,N-Dimethylformamidsowie Pyridin / Interactions in Molecular Crystals, 154 [1 - 3]. Host/Guest-Inclusion Compounds of N,N'-Ditosyl-p-phenylenediamine Derivatives: The Crystal Structures of N,N'-Di(4- nitro-benzosulfuryl)-p-phenylenediamine and its Hydrogen-Bonded Adducts with Cyclopentanone, Cyclohexanone, Tetrahydrofurane, N,N-Dimethylformamide as well as Pyridine
- Low Temperature Crystal Growth and Structure of Ordered Ba7F12Cl2
- Darstellung chiraler heterocyclischer β-Aminosäureester / Preparation of Chiral Heterocyclic Esters of β-Amino Acids
- Reaktionen von Isochinolinium-Salzen mit Hydroxylamin-Derivaten, 2. Mitteilung N-(Alkyl)- und N-(Aryl)-substituierte Verbindungen / Reactions of Isoquinolinium Salts with Hydroxylamine Derivatives, 2nd Communication N-(Alkyl) and N-(Aryl) Substituted Compounds
- Montmorillonite K-10 Catalyzed Knoevenagel Condensation under Microwave Irradiation in Solventless System
- New Monoterpene Glycosides from Paeonia emodi
- Synthese neuer Pyridin-, Pyrindin- bzw. Isochinolin-substituierter α- und β-C-Nukleoside der 2-Desoxy-D-ribose / Synthesis of Novel Pyridine-, Pyrindine- and Isoquinoline-Substituted α- and β-C-Nucleosides of 2-Deoxy-D-ribose
- Synthesis and Coordination Properties of 6,6'-Dimesityl-2,2'-bipyridine
- A Polyhydroxylated Cyclopentene: A Useful Synthon toward the Synthesis of Carbocyclic D-Fructofuranoid
- Alquds, a New Flavone Glycoside from Calamintha incana