Home Physical Sciences Metall(II)-Diazin Komplexe: Kristallstrukturen von Cd(pyrazin)Br2, Cd(pyrazin)I2, Cu(pyrazin)Cl2 und Cd(pyrimidin)(NO3)2·2H2O/ Metal(II) Diazine Complexes: Crystal Structures of Cd(pyrazine)Br2, Cd(pyrazine)I2, Cu(pyrazine)Cl2, and Cd(pyrimidine)(NO3)2·2H2O.
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Metall(II)-Diazin Komplexe: Kristallstrukturen von Cd(pyrazin)Br2, Cd(pyrazin)I2, Cu(pyrazin)Cl2 und Cd(pyrimidin)(NO3)2·2H2O/ Metal(II) Diazine Complexes: Crystal Structures of Cd(pyrazine)Br2, Cd(pyrazine)I2, Cu(pyrazine)Cl2, and Cd(pyrimidine)(NO3)2·2H2O.

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Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 52 Issue 12

Abstract

Single crystals of the compounds Cd(pyrazine)Br2, Cd(pyrazine)I2, Cu(pyrazine)Cl2 and Cd(pyrimidine)(NO3)2·2H2O were obtained by crystallisation from aqueous solutions of the metal salts and solutions of the respective diazine in an organic solvent.

The structures of the pyrazine complexes consist of “supramolecular” networks of -M-pyrazine-M-and -M -(μ2-Hal)2-M-chains. The pyrimidine complex shows a three dimensional network due to -M-pyrimidine-M-chains connected via hydrogen bonds between H(H2O) and O(ONO2).

Keywords: Metal Halide Pyrazine Adducts; Cadmium Pyrimidine Complex; Crystal Structure
Received: 1997-8-27
Published Online: 2014-6-2
Published in Print: 1997-12-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Aluminiumphosphate mit nichtzentrosymmetrischen Schicht-und Raumnetzstrukturen aus topologisch verwandten Motiven: 1. KAl2(PO4)2(OH)·4H2O/Aluminum Phosphates with Non-Centrosym metric Layer-and Framework-Structures of Topologically Related Motifs 1. KAl2(PO4)2(OH)·4H2O
  2. Aluminiumphosphate mit nichtzentrosymmetrischen Schicht- und Raumnetzstrukturen aus topologisch verwandten Motiven: 2. KAl2(PO4)2(OH)·2H2O/Aluminum Phosphates with Non-Centrosymmetric Layer- and Framework-Structures of Topologically Related Motifs: 2. KAl2(PO4)2(OH)·2H2O
  3. Metall(II)-Diazin Komplexe: Kristallstrukturen von Cd(pyrazin)Br2, Cd(pyrazin)I2, Cu(pyrazin)Cl2 und Cd(pyrimidin)(NO3)2·2H2O/ Metal(II) Diazine Complexes: Crystal Structures of Cd(pyrazine)Br2, Cd(pyrazine)I2, Cu(pyrazine)Cl2, and Cd(pyrimidine)(NO3)2·2H2O.
  4. Untersuchungen zum ternären System Bi/Te/O, II. Thermisches Verhalten und Koexistenzbeziehungen von Bi2O2Te/Investigations of the Ternary System Bi/Te/O, II. The Thermal Behaviour and the Relations of Phase Coexistences of Bi2O2Te
  5. Quaternary Equiatomic Compounds LnZnSbO (Ln = La - Nd, Sm) with ZrCuSiAs-Type Structure
  6. Different Connectivities in Supramolecular Aggregates of Trinuclear GoId(I) Complexes with the Sacconi-Ligand N(CH2CH2PPh2)3
  7. Chiral Phosphine Ligands in the Structural Chemistry of Gold
  8. Die Kristallstruckturen der Phosphaniminato-Komplexe.[Ti3IVCl8(NPMe3)3]Cl und [V2III/IVCl4(NPPh3)3]/Crystal Structures of the Phosphoraneiminato Complexes [Ti3IVCl8(NPMe3)3]Cl and [V2III/IVCl4(NPPh3)3]
  9. Synthese und Kristallstrukturbestimmung von Additionsverbindungen aus Alkyldimethylbromsilanen und N-Trimethylsilylimidazol/Syntheses and Crystal Structure Determination of Addition Compounds of Alkyldimethylbromosilanes and N-Trimethylsilylimidazole
  10. Darstellung und Kristallstruktur der oligomeren Iodo-d10-metallate(II) [M(I)(CH3CN)4]4[Cd6I16] · 1,5 CH3CN mit M(I) = Cu, Li/Synthesis and Crystal Structure of the Oligomeric Iodo-d10-metallate(II) [M(I)(CH3CN)4]4[Cd6I16] · 1,5 CH3CN with M(I) = Cu, Li
  11. [Ni3Se(o-C6H4{CH2Se}2)3]2- und [Ni4(SeiC3H7)8], die ersten höherkernigen NickeI(II)-Komplexe mit vollständiger Selen-Ligandensphäre [Ni3Se(o-C6H4{CH2Se}2)3]2- and [Ni4(SeiC3H7)8], the First Polynuclear Nickel(II) Complexes with Complete Selenium Ligand Spheres
  12. Zur Chemie der 1,3,5-Triaza-2-phosphorin-4,6-dione, Teil XIII. Darstellung und Röntgenstrukturanalyse des 1,3,5-Trimethyl-2-trichlormethyl-Derivats. Reaktionen einiger 1,3,5-Trimethyl-1,3,5-triaza-2-(R)-phosphorin-4,6-dione/Chemistry of the l,3,5-Triaza-2-phosphorine-4.6-diones, Part XIII. Synthesis and X -Ray Crystal Structure Determination of the 1,3,5-Trimethyl-2- trichlorom ethyl Derivative. Reactions of Some 1,3,5-Trimethyl-1,3,5-triaza-2-(R )-phosphorine-4,6-diones
  13. Thermische Zersetzung und Lösungskalorimetrie von Ammoniumsamariumchloriden/Thermal Decomposition and Solution Calorimetry of Ammonium Samarium Chlorides
  14. Synthesis of the Caffeine Metabolites 5-Acetylamino-6-formylamino- 3-methyluracil (AFMU) and 5-Acetylamino-6-amino-3-methyluracil (AAMU) on a Preparative Scale
  15. Synthesis and Mesomorphic Properties of Azo Compounds Derived from Phenyl-and Thienyl-1,3,4-Thiadiazole
  16. Chiral Hexa-and Nona-Substituted 1,3,5-Triphenylbenzenes
  17. Synthesis and Crystal Structure Determination of (R,S)-Diphenyl 1-CyclohexyI-1-(4-nitroanilino)methanephosphonate
  18. Notizen: C4S82- and C16S184-: Intermediates in the Synthesis of PoIy(Carbon Sulfide)
  19. Subject Index
  20. Authors Index
https://doi.org/10.1515/znb-1997-1203
Keywords for this article
Metal Halide Pyrazine Adducts; Cadmium Pyrimidine Complex; Crystal Structure

Articles in the same Issue

  1. Aluminiumphosphate mit nichtzentrosymmetrischen Schicht-und Raumnetzstrukturen aus topologisch verwandten Motiven: 1. KAl2(PO4)2(OH)·4H2O/Aluminum Phosphates with Non-Centrosym metric Layer-and Framework-Structures of Topologically Related Motifs 1. KAl2(PO4)2(OH)·4H2O
  2. Aluminiumphosphate mit nichtzentrosymmetrischen Schicht- und Raumnetzstrukturen aus topologisch verwandten Motiven: 2. KAl2(PO4)2(OH)·2H2O/Aluminum Phosphates with Non-Centrosymmetric Layer- and Framework-Structures of Topologically Related Motifs: 2. KAl2(PO4)2(OH)·2H2O
  3. Metall(II)-Diazin Komplexe: Kristallstrukturen von Cd(pyrazin)Br2, Cd(pyrazin)I2, Cu(pyrazin)Cl2 und Cd(pyrimidin)(NO3)2·2H2O/ Metal(II) Diazine Complexes: Crystal Structures of Cd(pyrazine)Br2, Cd(pyrazine)I2, Cu(pyrazine)Cl2, and Cd(pyrimidine)(NO3)2·2H2O.
  4. Untersuchungen zum ternären System Bi/Te/O, II. Thermisches Verhalten und Koexistenzbeziehungen von Bi2O2Te/Investigations of the Ternary System Bi/Te/O, II. The Thermal Behaviour and the Relations of Phase Coexistences of Bi2O2Te
  5. Quaternary Equiatomic Compounds LnZnSbO (Ln = La - Nd, Sm) with ZrCuSiAs-Type Structure
  6. Different Connectivities in Supramolecular Aggregates of Trinuclear GoId(I) Complexes with the Sacconi-Ligand N(CH2CH2PPh2)3
  7. Chiral Phosphine Ligands in the Structural Chemistry of Gold
  8. Die Kristallstruckturen der Phosphaniminato-Komplexe.[Ti3IVCl8(NPMe3)3]Cl und [V2III/IVCl4(NPPh3)3]/Crystal Structures of the Phosphoraneiminato Complexes [Ti3IVCl8(NPMe3)3]Cl and [V2III/IVCl4(NPPh3)3]
  9. Synthese und Kristallstrukturbestimmung von Additionsverbindungen aus Alkyldimethylbromsilanen und N-Trimethylsilylimidazol/Syntheses and Crystal Structure Determination of Addition Compounds of Alkyldimethylbromosilanes and N-Trimethylsilylimidazole
  10. Darstellung und Kristallstruktur der oligomeren Iodo-d10-metallate(II) [M(I)(CH3CN)4]4[Cd6I16] · 1,5 CH3CN mit M(I) = Cu, Li/Synthesis and Crystal Structure of the Oligomeric Iodo-d10-metallate(II) [M(I)(CH3CN)4]4[Cd6I16] · 1,5 CH3CN with M(I) = Cu, Li
  11. [Ni3Se(o-C6H4{CH2Se}2)3]2- und [Ni4(SeiC3H7)8], die ersten höherkernigen NickeI(II)-Komplexe mit vollständiger Selen-Ligandensphäre [Ni3Se(o-C6H4{CH2Se}2)3]2- and [Ni4(SeiC3H7)8], the First Polynuclear Nickel(II) Complexes with Complete Selenium Ligand Spheres
  12. Zur Chemie der 1,3,5-Triaza-2-phosphorin-4,6-dione, Teil XIII. Darstellung und Röntgenstrukturanalyse des 1,3,5-Trimethyl-2-trichlormethyl-Derivats. Reaktionen einiger 1,3,5-Trimethyl-1,3,5-triaza-2-(R)-phosphorin-4,6-dione/Chemistry of the l,3,5-Triaza-2-phosphorine-4.6-diones, Part XIII. Synthesis and X -Ray Crystal Structure Determination of the 1,3,5-Trimethyl-2- trichlorom ethyl Derivative. Reactions of Some 1,3,5-Trimethyl-1,3,5-triaza-2-(R )-phosphorine-4,6-diones
  13. Thermische Zersetzung und Lösungskalorimetrie von Ammoniumsamariumchloriden/Thermal Decomposition and Solution Calorimetry of Ammonium Samarium Chlorides
  14. Synthesis of the Caffeine Metabolites 5-Acetylamino-6-formylamino- 3-methyluracil (AFMU) and 5-Acetylamino-6-amino-3-methyluracil (AAMU) on a Preparative Scale
  15. Synthesis and Mesomorphic Properties of Azo Compounds Derived from Phenyl-and Thienyl-1,3,4-Thiadiazole
  16. Chiral Hexa-and Nona-Substituted 1,3,5-Triphenylbenzenes
  17. Synthesis and Crystal Structure Determination of (R,S)-Diphenyl 1-CyclohexyI-1-(4-nitroanilino)methanephosphonate
  18. Notizen: C4S82- and C16S184-: Intermediates in the Synthesis of PoIy(Carbon Sulfide)
  19. Subject Index
  20. Authors Index
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