Home Physical Sciences Aluminiumphosphate mit nichtzentrosymmetrischen Schicht-und Raumnetzstrukturen aus topologisch verwandten Motiven: 1. KAl2(PO4)2(OH)·4H2O/Aluminum Phosphates with Non-Centrosym metric Layer-and Framework-Structures of Topologically Related Motifs 1. KAl2(PO4)2(OH)·4H2O
Article
Licensed
Unlicensed Requires Authentication

Aluminiumphosphate mit nichtzentrosymmetrischen Schicht-und Raumnetzstrukturen aus topologisch verwandten Motiven: 1. KAl2(PO4)2(OH)·4H2O/Aluminum Phosphates with Non-Centrosym metric Layer-and Framework-Structures of Topologically Related Motifs 1. KAl2(PO4)2(OH)·4H2O

  • , , and
Published/Copyright: June 2, 2014
Become an author with De Gruyter Brill
Author Information Explore this Subject
Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 52 Issue 12

Abstract

KAl2(PO4)2(OH)·4H2O could be obtained by the reaction of gibbsite with a potassium-phosphate solution of pH = 5.5 at 333 K. A single crystal X-ray structure analysis showed that KAl2(PO4)2(OH)·4H2O is isotypic with the mineral minyulite. Crystal data: orthorhombic space group Pba2, a = 934.7(1), b = 982, 1 (1), c = 551,0(1) pm, Z = 2. It possesses dimeric units of Al-octahedra which are bridged by an OH-and two bidentate phosphate groups. The dimers are linked by phosphate to plane polar layers. Cavities in the layers are occupied by K ions. One corner of each phosphate tetrahedron is not connected to Al but accepts four hydrogen bonds from water molecules bound to Al of the adjacent layer. A powder neutron scattering experiment with KAl2(PO4)2(OD)·4D2O showed that four D atoms and P coordinate the hydrogen bond accepting O in KAl2(PO4)2(OD)·4D2O like a square pyramid. Analogous dimeric building units are found in the Al phosphate minerals minyulite and morinite; similar dimers of Fe octahedra occur in the mineral copiapite, a number of Fe containing enzymes and numerous synthetic iron complexes.

High-resolution 31P solid-state NMR spectra show only one isotropic line at δiso = -9.6 ppm and confirm the presence of one symmetry independent phosphorus site in the unit cell. In the 1H-MAS-NMR spectra the water molecules and the bridging OH groups show signals at 5.4 and 1.4 ppm, respectively

Keywords: Crystal Structure; Neutron Scattering; MAS NMR; Minyulite; Aluminium Phosphate
Received: 1997-9-9
Published Online: 2014-6-2
Published in Print: 1997-12-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Aluminiumphosphate mit nichtzentrosymmetrischen Schicht-und Raumnetzstrukturen aus topologisch verwandten Motiven: 1. KAl2(PO4)2(OH)·4H2O/Aluminum Phosphates with Non-Centrosym metric Layer-and Framework-Structures of Topologically Related Motifs 1. KAl2(PO4)2(OH)·4H2O
  2. Aluminiumphosphate mit nichtzentrosymmetrischen Schicht- und Raumnetzstrukturen aus topologisch verwandten Motiven: 2. KAl2(PO4)2(OH)·2H2O/Aluminum Phosphates with Non-Centrosymmetric Layer- and Framework-Structures of Topologically Related Motifs: 2. KAl2(PO4)2(OH)·2H2O
  3. Metall(II)-Diazin Komplexe: Kristallstrukturen von Cd(pyrazin)Br2, Cd(pyrazin)I2, Cu(pyrazin)Cl2 und Cd(pyrimidin)(NO3)2·2H2O/ Metal(II) Diazine Complexes: Crystal Structures of Cd(pyrazine)Br2, Cd(pyrazine)I2, Cu(pyrazine)Cl2, and Cd(pyrimidine)(NO3)2·2H2O.
  4. Untersuchungen zum ternären System Bi/Te/O, II. Thermisches Verhalten und Koexistenzbeziehungen von Bi2O2Te/Investigations of the Ternary System Bi/Te/O, II. The Thermal Behaviour and the Relations of Phase Coexistences of Bi2O2Te
  5. Quaternary Equiatomic Compounds LnZnSbO (Ln = La - Nd, Sm) with ZrCuSiAs-Type Structure
  6. Different Connectivities in Supramolecular Aggregates of Trinuclear GoId(I) Complexes with the Sacconi-Ligand N(CH2CH2PPh2)3
  7. Chiral Phosphine Ligands in the Structural Chemistry of Gold
  8. Die Kristallstruckturen der Phosphaniminato-Komplexe.[Ti3IVCl8(NPMe3)3]Cl und [V2III/IVCl4(NPPh3)3]/Crystal Structures of the Phosphoraneiminato Complexes [Ti3IVCl8(NPMe3)3]Cl and [V2III/IVCl4(NPPh3)3]
  9. Synthese und Kristallstrukturbestimmung von Additionsverbindungen aus Alkyldimethylbromsilanen und N-Trimethylsilylimidazol/Syntheses and Crystal Structure Determination of Addition Compounds of Alkyldimethylbromosilanes and N-Trimethylsilylimidazole
  10. Darstellung und Kristallstruktur der oligomeren Iodo-d10-metallate(II) [M(I)(CH3CN)4]4[Cd6I16] · 1,5 CH3CN mit M(I) = Cu, Li/Synthesis and Crystal Structure of the Oligomeric Iodo-d10-metallate(II) [M(I)(CH3CN)4]4[Cd6I16] · 1,5 CH3CN with M(I) = Cu, Li
  11. [Ni3Se(o-C6H4{CH2Se}2)3]2- und [Ni4(SeiC3H7)8], die ersten höherkernigen NickeI(II)-Komplexe mit vollständiger Selen-Ligandensphäre [Ni3Se(o-C6H4{CH2Se}2)3]2- and [Ni4(SeiC3H7)8], the First Polynuclear Nickel(II) Complexes with Complete Selenium Ligand Spheres
  12. Zur Chemie der 1,3,5-Triaza-2-phosphorin-4,6-dione, Teil XIII. Darstellung und Röntgenstrukturanalyse des 1,3,5-Trimethyl-2-trichlormethyl-Derivats. Reaktionen einiger 1,3,5-Trimethyl-1,3,5-triaza-2-(R)-phosphorin-4,6-dione/Chemistry of the l,3,5-Triaza-2-phosphorine-4.6-diones, Part XIII. Synthesis and X -Ray Crystal Structure Determination of the 1,3,5-Trimethyl-2- trichlorom ethyl Derivative. Reactions of Some 1,3,5-Trimethyl-1,3,5-triaza-2-(R )-phosphorine-4,6-diones
  13. Thermische Zersetzung und Lösungskalorimetrie von Ammoniumsamariumchloriden/Thermal Decomposition and Solution Calorimetry of Ammonium Samarium Chlorides
  14. Synthesis of the Caffeine Metabolites 5-Acetylamino-6-formylamino- 3-methyluracil (AFMU) and 5-Acetylamino-6-amino-3-methyluracil (AAMU) on a Preparative Scale
  15. Synthesis and Mesomorphic Properties of Azo Compounds Derived from Phenyl-and Thienyl-1,3,4-Thiadiazole
  16. Chiral Hexa-and Nona-Substituted 1,3,5-Triphenylbenzenes
  17. Synthesis and Crystal Structure Determination of (R,S)-Diphenyl 1-CyclohexyI-1-(4-nitroanilino)methanephosphonate
  18. Notizen: C4S82- and C16S184-: Intermediates in the Synthesis of PoIy(Carbon Sulfide)
  19. Subject Index
  20. Authors Index
https://doi.org/10.1515/znb-1997-1201
Keywords for this article
Crystal Structure; Neutron Scattering; MAS NMR; Minyulite; Aluminium Phosphate

Articles in the same Issue

  1. Aluminiumphosphate mit nichtzentrosymmetrischen Schicht-und Raumnetzstrukturen aus topologisch verwandten Motiven: 1. KAl2(PO4)2(OH)·4H2O/Aluminum Phosphates with Non-Centrosym metric Layer-and Framework-Structures of Topologically Related Motifs 1. KAl2(PO4)2(OH)·4H2O
  2. Aluminiumphosphate mit nichtzentrosymmetrischen Schicht- und Raumnetzstrukturen aus topologisch verwandten Motiven: 2. KAl2(PO4)2(OH)·2H2O/Aluminum Phosphates with Non-Centrosymmetric Layer- and Framework-Structures of Topologically Related Motifs: 2. KAl2(PO4)2(OH)·2H2O
  3. Metall(II)-Diazin Komplexe: Kristallstrukturen von Cd(pyrazin)Br2, Cd(pyrazin)I2, Cu(pyrazin)Cl2 und Cd(pyrimidin)(NO3)2·2H2O/ Metal(II) Diazine Complexes: Crystal Structures of Cd(pyrazine)Br2, Cd(pyrazine)I2, Cu(pyrazine)Cl2, and Cd(pyrimidine)(NO3)2·2H2O.
  4. Untersuchungen zum ternären System Bi/Te/O, II. Thermisches Verhalten und Koexistenzbeziehungen von Bi2O2Te/Investigations of the Ternary System Bi/Te/O, II. The Thermal Behaviour and the Relations of Phase Coexistences of Bi2O2Te
  5. Quaternary Equiatomic Compounds LnZnSbO (Ln = La - Nd, Sm) with ZrCuSiAs-Type Structure
  6. Different Connectivities in Supramolecular Aggregates of Trinuclear GoId(I) Complexes with the Sacconi-Ligand N(CH2CH2PPh2)3
  7. Chiral Phosphine Ligands in the Structural Chemistry of Gold
  8. Die Kristallstruckturen der Phosphaniminato-Komplexe.[Ti3IVCl8(NPMe3)3]Cl und [V2III/IVCl4(NPPh3)3]/Crystal Structures of the Phosphoraneiminato Complexes [Ti3IVCl8(NPMe3)3]Cl and [V2III/IVCl4(NPPh3)3]
  9. Synthese und Kristallstrukturbestimmung von Additionsverbindungen aus Alkyldimethylbromsilanen und N-Trimethylsilylimidazol/Syntheses and Crystal Structure Determination of Addition Compounds of Alkyldimethylbromosilanes and N-Trimethylsilylimidazole
  10. Darstellung und Kristallstruktur der oligomeren Iodo-d10-metallate(II) [M(I)(CH3CN)4]4[Cd6I16] · 1,5 CH3CN mit M(I) = Cu, Li/Synthesis and Crystal Structure of the Oligomeric Iodo-d10-metallate(II) [M(I)(CH3CN)4]4[Cd6I16] · 1,5 CH3CN with M(I) = Cu, Li
  11. [Ni3Se(o-C6H4{CH2Se}2)3]2- und [Ni4(SeiC3H7)8], die ersten höherkernigen NickeI(II)-Komplexe mit vollständiger Selen-Ligandensphäre [Ni3Se(o-C6H4{CH2Se}2)3]2- and [Ni4(SeiC3H7)8], the First Polynuclear Nickel(II) Complexes with Complete Selenium Ligand Spheres
  12. Zur Chemie der 1,3,5-Triaza-2-phosphorin-4,6-dione, Teil XIII. Darstellung und Röntgenstrukturanalyse des 1,3,5-Trimethyl-2-trichlormethyl-Derivats. Reaktionen einiger 1,3,5-Trimethyl-1,3,5-triaza-2-(R)-phosphorin-4,6-dione/Chemistry of the l,3,5-Triaza-2-phosphorine-4.6-diones, Part XIII. Synthesis and X -Ray Crystal Structure Determination of the 1,3,5-Trimethyl-2- trichlorom ethyl Derivative. Reactions of Some 1,3,5-Trimethyl-1,3,5-triaza-2-(R )-phosphorine-4,6-diones
  13. Thermische Zersetzung und Lösungskalorimetrie von Ammoniumsamariumchloriden/Thermal Decomposition and Solution Calorimetry of Ammonium Samarium Chlorides
  14. Synthesis of the Caffeine Metabolites 5-Acetylamino-6-formylamino- 3-methyluracil (AFMU) and 5-Acetylamino-6-amino-3-methyluracil (AAMU) on a Preparative Scale
  15. Synthesis and Mesomorphic Properties of Azo Compounds Derived from Phenyl-and Thienyl-1,3,4-Thiadiazole
  16. Chiral Hexa-and Nona-Substituted 1,3,5-Triphenylbenzenes
  17. Synthesis and Crystal Structure Determination of (R,S)-Diphenyl 1-CyclohexyI-1-(4-nitroanilino)methanephosphonate
  18. Notizen: C4S82- and C16S184-: Intermediates in the Synthesis of PoIy(Carbon Sulfide)
  19. Subject Index
  20. Authors Index
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Winner of the OpenAthens UX Award 2026
Winner of the OpenAthens UX Award 2026
Have an idea on how to improve our website?
Please write us.
© 2026 De Gruyter Brill
Downloaded on 20.3.2026 from https://www.degruyterbrill.com/document/doi/10.1515/znb-1997-1201/html
Scroll to top button