Home Notizen: Synthese und Strukturuntersuchungen von Iodocupraten(I), XVIII. Darstellung und Kristallstruktur von PbCu2I4 ·2CH3CN/Synthesis and Structure Investigations of Iodocuprates(I), XVIII. Preparation and Crystal Structure of PbCu2I4 · 2CH3CN
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Notizen: Synthese und Strukturuntersuchungen von Iodocupraten(I), XVIII. Darstellung und Kristallstruktur von PbCu2I4 ·2CH3CN/Synthesis and Structure Investigations of Iodocuprates(I), XVIII. Preparation and Crystal Structure of PbCu2I4 · 2CH3CN

  • Hans Hartl and Michael Hoyer
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 52 Issue 6

Abstract

Single crystals of PbCu2I4·2(CH3CN) are formed by reaction of Pbl2 with Cul in acetonitril. The compound crystallizes in the mono­clinic space group C2/m; a = 1625.8(3), b = 436.6(1), c = 1025.8(2)pm; β = 94.77(3)°; V = 725.7 pm3 106; Z = 2. The crystal structure is built up by chains of trans-edge sharing 1∞[PbI6/3] octahedra and corner sharing 1∞[CuI3/3CH3CN)] tetra­hedra connected by common I-I edges.

Keywords: Iodometallates; Lead-Copper-Iodide; Synthesis; Crystal Structure
Received: 1997-3-14
Published Online: 2014-6-2
Published in Print: 1997-6-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

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https://doi.org/10.1515/znb-1997-0616
Keywords for this article
Iodometallates; Lead-Copper-Iodide; Synthesis; Crystal Structure

Articles in the same Issue

  1. Introduction of Functional Silyl Groups into Tris(dialkylamino)phosphonium Methylides
  2. Bis(silylation) of Tris(dimethylamino)phosphonium Methylide
  3. Metal-Mediated Assembly of Hexameric Ethylcycloarsoxane (C2H5AsO)6 in Mono-and Dinuclear Complexes with Tetrahedral and Octahedral Coordination Spheres
  4. Quaternary Selenidogermanates(IV) A3[AgGe4Se10]·2H2O and A2[MnGe4Se10]·3H2O (A = Rb, Cs) with Open Framework Structures
  5. Vanadiumkomplexe mit dreizähnigen diaciden Liganden. Bis[2-(2′-hydroxyphenyl)-chinolin-8-olato]dimethoxo-dioxo-divanadium(V) -ein neuer Strukturtyp/Vanadium Complexes with Tridentate Diacidic Ligands. Bis[2-(2′-hydroxyphenyl)-8-quinolinolato)dimethoxo-dioxo-divanadium (V) - a New Structure Type
  6. Untersuchungen zur thermischen Zersetzung von Ammoniumlanthanhalogeniden/Investigation on the Thermal Decomposition of Ammonium Halides
  7. Darstellung und Charakterisierung der Carbosilazane Bis[tris(methylamino)silyl]methan und Bis[tris(phenylamino)silyl]methan/Preparation and Characterization of the Carbosilazanes Bis[tris(methylamino)silyl]methane and B is[tris(phenylamino)silyl]m ethane
  8. Laboratory Stopped-Flow XAFS Apparatus. Structure Determination of the Short-Lived Peroxochromium Intermediate Formed during Reduction Process of Chromate(VI) Ion by Hydrogen Peroxide
  9. Chemical Basis for High Activity in Oxygenation of Cyclohexane Catalyzed by Dinuclear Iron(III) Complexes with Ethereal Oxygen Containing Ligand and Hydrogen Peroxide System
  10. Synthese von Bis[pyridin-phthalocyaninato(1,5-)iridium(II)]iodid und Pyridin-iodo-phthalocyaninato(2-)iridium(III)-Pyridin durch schrittweise Oxydation von Bis[pyridin-phthalocyaninato(2-)iridium(II)]/Synthesis of Bis[pyridine-phthalocyaninato(1,5-)iridium(II)] Iodide and Pyridine-iodo-phthalocyaninato(2-)iridium(III)-Pyridine by Successive Oxidation of Bis[pyridine-phthalocyaninato(2-)iridium(II)]
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  13. Stereospecific Association of C-20 Epimers of 3β-Hydroxy-16-oxo-24-nor-17-azachol-5-eno-23-nitryle
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  15. Notizen: [{Cp*(CI)Re}2(μ-CO)2](Re ≡ Re), ein zweikerniger Rhenium(II)-Komplex mit cis-konfigurierten, terminalen Cl-Atomen/[{Cp*(Cl)Re}2(μ-CO)2](Re ≡ Re), a Dinuclear Rhenium(II) Complex with cis Configuration of the Terminal Cl Atoms
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