Home Physical Sciences Novel Electrochemically Derived Dimers of Methylated Uracils
Article
Licensed
Unlicensed Requires Authentication

Novel Electrochemically Derived Dimers of Methylated Uracils

  • , , and
Published/Copyright: June 2, 2014
Become an author with De Gruyter Brill
Author Information Explore this Subject
Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 52 Issue 6

Abstract

Electrolysis of acetic acid/sodium acetate solutions of N-methylated uracils results in the formation of 5-substituted methyl and acethoxy derivatives. Electrolysis of trifluoroacetic acid/potassium trifluoroacetate solutions of N-1-and N-3-methylated uracils provided, be­ sides 5-trifluoromethyl derivatives, novel N-C uracil dimers. In the case of 1,3-dimethyluracil in trifluoroacetic acid. N-l demethylathion was also observed.

Keywords: Electrolysis; Radical Substitution; Uracil Dimers of N-C; Electrochemical Oxidation Electrochemical Trifluoromethylation
Received: 1997-3-6
Published Online: 2014-6-2
Published in Print: 1997-6-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Introduction of Functional Silyl Groups into Tris(dialkylamino)phosphonium Methylides
  2. Bis(silylation) of Tris(dimethylamino)phosphonium Methylide
  3. Metal-Mediated Assembly of Hexameric Ethylcycloarsoxane (C2H5AsO)6 in Mono-and Dinuclear Complexes with Tetrahedral and Octahedral Coordination Spheres
  4. Quaternary Selenidogermanates(IV) A3[AgGe4Se10]·2H2O and A2[MnGe4Se10]·3H2O (A = Rb, Cs) with Open Framework Structures
  5. Vanadiumkomplexe mit dreizähnigen diaciden Liganden. Bis[2-(2′-hydroxyphenyl)-chinolin-8-olato]dimethoxo-dioxo-divanadium(V) -ein neuer Strukturtyp/Vanadium Complexes with Tridentate Diacidic Ligands. Bis[2-(2′-hydroxyphenyl)-8-quinolinolato)dimethoxo-dioxo-divanadium (V) - a New Structure Type
  6. Untersuchungen zur thermischen Zersetzung von Ammoniumlanthanhalogeniden/Investigation on the Thermal Decomposition of Ammonium Halides
  7. Darstellung und Charakterisierung der Carbosilazane Bis[tris(methylamino)silyl]methan und Bis[tris(phenylamino)silyl]methan/Preparation and Characterization of the Carbosilazanes Bis[tris(methylamino)silyl]methane and B is[tris(phenylamino)silyl]m ethane
  8. Laboratory Stopped-Flow XAFS Apparatus. Structure Determination of the Short-Lived Peroxochromium Intermediate Formed during Reduction Process of Chromate(VI) Ion by Hydrogen Peroxide
  9. Chemical Basis for High Activity in Oxygenation of Cyclohexane Catalyzed by Dinuclear Iron(III) Complexes with Ethereal Oxygen Containing Ligand and Hydrogen Peroxide System
  10. Synthese von Bis[pyridin-phthalocyaninato(1,5-)iridium(II)]iodid und Pyridin-iodo-phthalocyaninato(2-)iridium(III)-Pyridin durch schrittweise Oxydation von Bis[pyridin-phthalocyaninato(2-)iridium(II)]/Synthesis of Bis[pyridine-phthalocyaninato(1,5-)iridium(II)] Iodide and Pyridine-iodo-phthalocyaninato(2-)iridium(III)-Pyridine by Successive Oxidation of Bis[pyridine-phthalocyaninato(2-)iridium(II)]
  11. Zur Reaktion von N-Sulfonyliminodithiocarbonaten mit den Dibromiden des Cyclooctatetraens Reaction of Sulfonylcarboniminodithioates with the Dibromides of Cyclooctatetraene
  12. Novel Electrochemically Derived Dimers of Methylated Uracils
  13. Stereospecific Association of C-20 Epimers of 3β-Hydroxy-16-oxo-24-nor-17-azachol-5-eno-23-nitryle
  14. 1.3-Dithienium-and 1.3-Dithiolenium Salts, VI ,13C NMR Spectroscopic Investigations on 2-Substituted 1,3-Dithian-2-ylium Cations. Unusual γ-Effects
  15. Notizen: [{Cp*(CI)Re}2(μ-CO)2](Re ≡ Re), ein zweikerniger Rhenium(II)-Komplex mit cis-konfigurierten, terminalen Cl-Atomen/[{Cp*(Cl)Re}2(μ-CO)2](Re ≡ Re), a Dinuclear Rhenium(II) Complex with cis Configuration of the Terminal Cl Atoms
  16. Notizen: Synthese und Strukturuntersuchungen von Iodocupraten(I), XVIII. Darstellung und Kristallstruktur von PbCu2I4 ·2CH3CN/Synthesis and Structure Investigations of Iodocuprates(I), XVIII. Preparation and Crystal Structure of PbCu2I4 · 2CH3CN
  17. Notizen: Facile Preparation and Crystal Structure of [Bis(diphenylphosphino)amine]digold Dichloride
  18. Kristallstruktur von [PMePh3] [Cl - 1 - C≡C - Ph]/Crystal Structure of [PMePh3] [Cl - I - C≡C - Ph]
https://doi.org/10.1515/znb-1997-0612
Keywords for this article
Electrolysis; Radical Substitution; Uracil Dimers of N-C; Electrochemical Oxidation Electrochemical Trifluoromethylation

Articles in the same Issue

  1. Introduction of Functional Silyl Groups into Tris(dialkylamino)phosphonium Methylides
  2. Bis(silylation) of Tris(dimethylamino)phosphonium Methylide
  3. Metal-Mediated Assembly of Hexameric Ethylcycloarsoxane (C2H5AsO)6 in Mono-and Dinuclear Complexes with Tetrahedral and Octahedral Coordination Spheres
  4. Quaternary Selenidogermanates(IV) A3[AgGe4Se10]·2H2O and A2[MnGe4Se10]·3H2O (A = Rb, Cs) with Open Framework Structures
  5. Vanadiumkomplexe mit dreizähnigen diaciden Liganden. Bis[2-(2′-hydroxyphenyl)-chinolin-8-olato]dimethoxo-dioxo-divanadium(V) -ein neuer Strukturtyp/Vanadium Complexes with Tridentate Diacidic Ligands. Bis[2-(2′-hydroxyphenyl)-8-quinolinolato)dimethoxo-dioxo-divanadium (V) - a New Structure Type
  6. Untersuchungen zur thermischen Zersetzung von Ammoniumlanthanhalogeniden/Investigation on the Thermal Decomposition of Ammonium Halides
  7. Darstellung und Charakterisierung der Carbosilazane Bis[tris(methylamino)silyl]methan und Bis[tris(phenylamino)silyl]methan/Preparation and Characterization of the Carbosilazanes Bis[tris(methylamino)silyl]methane and B is[tris(phenylamino)silyl]m ethane
  8. Laboratory Stopped-Flow XAFS Apparatus. Structure Determination of the Short-Lived Peroxochromium Intermediate Formed during Reduction Process of Chromate(VI) Ion by Hydrogen Peroxide
  9. Chemical Basis for High Activity in Oxygenation of Cyclohexane Catalyzed by Dinuclear Iron(III) Complexes with Ethereal Oxygen Containing Ligand and Hydrogen Peroxide System
  10. Synthese von Bis[pyridin-phthalocyaninato(1,5-)iridium(II)]iodid und Pyridin-iodo-phthalocyaninato(2-)iridium(III)-Pyridin durch schrittweise Oxydation von Bis[pyridin-phthalocyaninato(2-)iridium(II)]/Synthesis of Bis[pyridine-phthalocyaninato(1,5-)iridium(II)] Iodide and Pyridine-iodo-phthalocyaninato(2-)iridium(III)-Pyridine by Successive Oxidation of Bis[pyridine-phthalocyaninato(2-)iridium(II)]
  11. Zur Reaktion von N-Sulfonyliminodithiocarbonaten mit den Dibromiden des Cyclooctatetraens Reaction of Sulfonylcarboniminodithioates with the Dibromides of Cyclooctatetraene
  12. Novel Electrochemically Derived Dimers of Methylated Uracils
  13. Stereospecific Association of C-20 Epimers of 3β-Hydroxy-16-oxo-24-nor-17-azachol-5-eno-23-nitryle
  14. 1.3-Dithienium-and 1.3-Dithiolenium Salts, VI ,13C NMR Spectroscopic Investigations on 2-Substituted 1,3-Dithian-2-ylium Cations. Unusual γ-Effects
  15. Notizen: [{Cp*(CI)Re}2(μ-CO)2](Re ≡ Re), ein zweikerniger Rhenium(II)-Komplex mit cis-konfigurierten, terminalen Cl-Atomen/[{Cp*(Cl)Re}2(μ-CO)2](Re ≡ Re), a Dinuclear Rhenium(II) Complex with cis Configuration of the Terminal Cl Atoms
  16. Notizen: Synthese und Strukturuntersuchungen von Iodocupraten(I), XVIII. Darstellung und Kristallstruktur von PbCu2I4 ·2CH3CN/Synthesis and Structure Investigations of Iodocuprates(I), XVIII. Preparation and Crystal Structure of PbCu2I4 · 2CH3CN
  17. Notizen: Facile Preparation and Crystal Structure of [Bis(diphenylphosphino)amine]digold Dichloride
  18. Kristallstruktur von [PMePh3] [Cl - 1 - C≡C - Ph]/Crystal Structure of [PMePh3] [Cl - I - C≡C - Ph]
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Winner of the OpenAthens UX Award 2026
Winner of the OpenAthens UX Award 2026
Have an idea on how to improve our website?
Please write us.
© 2026 De Gruyter Brill
Downloaded on 24.3.2026 from https://www.degruyterbrill.com/document/doi/10.1515/znb-1997-0612/html
Scroll to top button