Home Einkernige und oxoverbrückte zweikernige Fe(III)-Komplexe von N-Alkyl-N,N-bis(2-pyridylmethyl)aminen / Mononuclear and Oxo-Bridged Binuclear Fe(III) Complexes of N-Alkyl-N,N-bis(2-pyridylmethyl)amines
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Einkernige und oxoverbrückte zweikernige Fe(III)-Komplexe von N-Alkyl-N,N-bis(2-pyridylmethyl)aminen / Mononuclear and Oxo-Bridged Binuclear Fe(III) Complexes of N-Alkyl-N,N-bis(2-pyridylmethyl)amines

  • Stefan Dick , Armin Weiss , Ursel Wagner , Friedrich Wagner and Gerhard Große
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 52 Issue 3

Abstract

Tridentate amines of the type N-alkyl-N,N -bis(2-pyridylmethyl)amine with alkyl = methyl L1, benzyl L2 and adamantyl L3 form mononuclear Fe(III) complexes LFeCl3. In the presence of various carboxylates binuclear μ-oxo-bis(μ-carboxylato) Fe(III) complexes [L2Fe2O(RCO2)2]2+ are formed. These compounds can be synthesized from mono-, bi-, tri- and tetranuclear iron complexes as starting materials.

The crystal structures of three mononuclear and four binuclear complexes show that the tridentate ligand is always facially coordinated to Fe. While in binuclear complexes of L1 and L2 the Namin-atom is trans to the oxo-bridge, in a complex of L3 a coordination with one Npyridin atom trans to that bridge is found. In all complexes the Fe-Namine distances increase with increasing space requirement of the alkyl substituent. The effects of different ligands trans to Namine and Npyridin are discussed.

57Fe Mößbauer spectra show that the electric field gradient at Fe vanishes in L1FeCl3 and L2FeCl3 despite non-cubic ligand spheres. For both mono- and binuclear complexes a correlation between isomer shift δ and Fe-N distances exists. The strong increase of Lamb-Mößbauer factors on cooling to 4,2 K and the Goldanski-Karyagin effect observed for some complexes can be explained by the displacement parameters of the Fe-atoms obtained by X -ray structure analysis.

: Mononuclear Iron(III) Complex; Binuclear Iron(III) Complex; Crystal Structure; 57Fe Mößbauer Spectra
Received: 1996-8-1
Published Online: 2014-6-2
Published in Print: 1997-3-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Calorimetrie an Yttriumtrihalogeniden und Yttriumoxidhalogemden / Calorimetry of Yttrium Trihalides and Yttrium Oxyhalides
  2. Calorimetrie an Ammoniumyttriumhalogeniden / Calorimetry of Ammonium Yttrium Halides
  3. Kristallstrukturen, Schwingungsspektren und Normalkoordinatenanalysen von Tetrahalogenooxalatoosmaten (IV), [OsX4(ox)]2-, X = Cl, Br, I / Crystal Structures, Vibrational Spectra and Normal Coordinate Analyses of Tetrahalogenooxalatoosmates (IV), [OsX4(ox)]2-, X = Cl, Br, I
  4. The Phenomenon of Intramolecular Attractive S---O Interactions: Synthesis and Structure of (1,10-Phenanthroline)copper(II) Complexes with Isonitroso-(4-methylthiazol-2-yl)acetamide and Isonitroso-(4-methylthiazol-2-yl)-(benzothiazol-2-yl)methanide
  5. Direct Synthesis of Zinc and Nickel(II) Complexes with 1,4-Diazabicyclo[2.2.2]octane
  6. Crystal Structure of the Di-bromo-bis(2-dimethylaminoethanolato)(dimethylsulfoxide)-copper(II)-lead(II) Dimer Obtained by Direct Synthesis
  7. Unsymmetrische BN23--Ionen in den Strukturen von Ca2ClBN2 und Sr2ClBN2 / Unsymmetric BN23--Ions in the Structures of Ca2ClBN2 and Sr2ClBN2
  8. Bromierung von „Poly(1,4-diselenobenzol)“ / Bromination of “Poly(1,4-diselenobenzene)”
  9. Monoheteroarylborate [1] / Monoheteroarylborates [1]
  10. 1,3-Di-terf-butyl-6H-benzo[b]naphtho[1,2-d]pyran-6-thione, a Severely Helically Distorted Thionolactone-Bridged Biaryl
  11. Synthese und Struktur von Kalium-4,4-difluor-[1,3,2]dithiazetidinid-1,l,3,3-tetraoxid und Rubidium-4,4,5,5-tetrafluor-[1,3,2]dithiazolidinid-1,1,3,3-tetraoxid / Syntheses and Structure of Potassium-4,4-difluoro-[1,3,2]dithiazetidinide-1,1,3,3- tetraoxide and Rubidium-4,4,5,5-tetrafluoro-[ 1,3,2]dithiazolidinide-1,1,3,3-tetraoxide
  12. Synthese und Kristallstruktur eines Barium-Zink-Vanadyl-phosphats BaZn(VO)(PO4)2 mit [(VO)PO4]-Schichten / Synthesis and Crystal Structure of a Barium-Zinc-Vanadyl-Phosphate BaZn(VO)(PO4)2 Containing [(VO)PO4] Layers
  13. Einkernige und oxoverbrückte zweikernige Fe(III)-Komplexe von N-Alkyl-N,N-bis(2-pyridylmethyl)aminen / Mononuclear and Oxo-Bridged Binuclear Fe(III) Complexes of N-Alkyl-N,N-bis(2-pyridylmethyl)amines
  14. Diphenyl(1-pyridyl)phosphine Sulfide as a Ligand in Mono-and Binuclear Coinage Metal Complexes
  15. Röntgenstrukturuntersuchungen an Elpasolith-verwandten Hexacyanokomplexen [N(CH3)4]2A[M(CN)6] (A = Rb, Tl; M = Cr, Fe) / X-Ray Structure Investigations of Elpasolite Related Hexacyano Complexes [N(CH3)4]2A[M(CN)6] (A = Rb, Tl; M = Cr, Fe)
  16. Synthese und Kristallstruktur von Hexa(tert-butyl)bismocenium-tetrachloroaluminat / Synthesis and Crystal Structure of Hexa(tert-butyl)bismocenium Tetrachloroaluminate
  17. Über die Reaktionen von (CH3)4N+I-, (CH3)4N+ICl2-, (CH3)4N+ICl4- und (CH3)4N+Cl- mit Trifluormethylhypochlorit CF3OCl / The Reactions of (CH3)4N+I-, ( CH3)4N+ICl2-, (CH3)4N+ICl4- and (CH3)4N+Cl- with Trifluoromethylhypochlorite CF3OCl
  18. Hydrothermal Synthesis and Crystal Structure of the New Manganese(II) Thioantimonate(III), Mn(en)3Sb4S7
  19. Bondenolide, a New Diterpenoid from the Seeds of Caesalpinia bonduc
  20. Enzymatic Racemic Resolution of a Fluorinated Substrate and Syntheses of E and Z Alkenes as Precursors for Some Biologically Active Fluorohexoses
  21. Synthesis and Chiroptical Properties of Some N-(2-Chloro-7-cyclopropyl-4,7-dihydro-4-oxo-thieno[2,3-b]pyridine-5-carbonyl) L-α-Amino Esters
  22. Notizen: Synthesis of N,C,C-Trilithio-2,5-diallyl-pyrrole and its Solvent-Controlled Reactions with Electrophiles Notizen
  23. Notizen: A New Lithium Amide with Bulky Substituents -Molecular Structure of N-Lithio-N-trimethylsilyl-9-amino- 9-borabicyclo[3.3.1]nonane; Competition between N-Li and BN(pp)π Interactions
https://doi.org/10.1515/znb-1997-0313

Articles in the same Issue

  1. Calorimetrie an Yttriumtrihalogeniden und Yttriumoxidhalogemden / Calorimetry of Yttrium Trihalides and Yttrium Oxyhalides
  2. Calorimetrie an Ammoniumyttriumhalogeniden / Calorimetry of Ammonium Yttrium Halides
  3. Kristallstrukturen, Schwingungsspektren und Normalkoordinatenanalysen von Tetrahalogenooxalatoosmaten (IV), [OsX4(ox)]2-, X = Cl, Br, I / Crystal Structures, Vibrational Spectra and Normal Coordinate Analyses of Tetrahalogenooxalatoosmates (IV), [OsX4(ox)]2-, X = Cl, Br, I
  4. The Phenomenon of Intramolecular Attractive S---O Interactions: Synthesis and Structure of (1,10-Phenanthroline)copper(II) Complexes with Isonitroso-(4-methylthiazol-2-yl)acetamide and Isonitroso-(4-methylthiazol-2-yl)-(benzothiazol-2-yl)methanide
  5. Direct Synthesis of Zinc and Nickel(II) Complexes with 1,4-Diazabicyclo[2.2.2]octane
  6. Crystal Structure of the Di-bromo-bis(2-dimethylaminoethanolato)(dimethylsulfoxide)-copper(II)-lead(II) Dimer Obtained by Direct Synthesis
  7. Unsymmetrische BN23--Ionen in den Strukturen von Ca2ClBN2 und Sr2ClBN2 / Unsymmetric BN23--Ions in the Structures of Ca2ClBN2 and Sr2ClBN2
  8. Bromierung von „Poly(1,4-diselenobenzol)“ / Bromination of “Poly(1,4-diselenobenzene)”
  9. Monoheteroarylborate [1] / Monoheteroarylborates [1]
  10. 1,3-Di-terf-butyl-6H-benzo[b]naphtho[1,2-d]pyran-6-thione, a Severely Helically Distorted Thionolactone-Bridged Biaryl
  11. Synthese und Struktur von Kalium-4,4-difluor-[1,3,2]dithiazetidinid-1,l,3,3-tetraoxid und Rubidium-4,4,5,5-tetrafluor-[1,3,2]dithiazolidinid-1,1,3,3-tetraoxid / Syntheses and Structure of Potassium-4,4-difluoro-[1,3,2]dithiazetidinide-1,1,3,3- tetraoxide and Rubidium-4,4,5,5-tetrafluoro-[ 1,3,2]dithiazolidinide-1,1,3,3-tetraoxide
  12. Synthese und Kristallstruktur eines Barium-Zink-Vanadyl-phosphats BaZn(VO)(PO4)2 mit [(VO)PO4]-Schichten / Synthesis and Crystal Structure of a Barium-Zinc-Vanadyl-Phosphate BaZn(VO)(PO4)2 Containing [(VO)PO4] Layers
  13. Einkernige und oxoverbrückte zweikernige Fe(III)-Komplexe von N-Alkyl-N,N-bis(2-pyridylmethyl)aminen / Mononuclear and Oxo-Bridged Binuclear Fe(III) Complexes of N-Alkyl-N,N-bis(2-pyridylmethyl)amines
  14. Diphenyl(1-pyridyl)phosphine Sulfide as a Ligand in Mono-and Binuclear Coinage Metal Complexes
  15. Röntgenstrukturuntersuchungen an Elpasolith-verwandten Hexacyanokomplexen [N(CH3)4]2A[M(CN)6] (A = Rb, Tl; M = Cr, Fe) / X-Ray Structure Investigations of Elpasolite Related Hexacyano Complexes [N(CH3)4]2A[M(CN)6] (A = Rb, Tl; M = Cr, Fe)
  16. Synthese und Kristallstruktur von Hexa(tert-butyl)bismocenium-tetrachloroaluminat / Synthesis and Crystal Structure of Hexa(tert-butyl)bismocenium Tetrachloroaluminate
  17. Über die Reaktionen von (CH3)4N+I-, (CH3)4N+ICl2-, (CH3)4N+ICl4- und (CH3)4N+Cl- mit Trifluormethylhypochlorit CF3OCl / The Reactions of (CH3)4N+I-, ( CH3)4N+ICl2-, (CH3)4N+ICl4- and (CH3)4N+Cl- with Trifluoromethylhypochlorite CF3OCl
  18. Hydrothermal Synthesis and Crystal Structure of the New Manganese(II) Thioantimonate(III), Mn(en)3Sb4S7
  19. Bondenolide, a New Diterpenoid from the Seeds of Caesalpinia bonduc
  20. Enzymatic Racemic Resolution of a Fluorinated Substrate and Syntheses of E and Z Alkenes as Precursors for Some Biologically Active Fluorohexoses
  21. Synthesis and Chiroptical Properties of Some N-(2-Chloro-7-cyclopropyl-4,7-dihydro-4-oxo-thieno[2,3-b]pyridine-5-carbonyl) L-α-Amino Esters
  22. Notizen: Synthesis of N,C,C-Trilithio-2,5-diallyl-pyrrole and its Solvent-Controlled Reactions with Electrophiles Notizen
  23. Notizen: A New Lithium Amide with Bulky Substituents -Molecular Structure of N-Lithio-N-trimethylsilyl-9-amino- 9-borabicyclo[3.3.1]nonane; Competition between N-Li and BN(pp)π Interactions
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