Home Kristallstrukturen, Schwingungsspektren und Normalkoordinatenanalysen von Tetrahalogenooxalatoosmaten (IV), [OsX4(ox)]2-, X = Cl, Br, I / Crystal Structures, Vibrational Spectra and Normal Coordinate Analyses of Tetrahalogenooxalatoosmates (IV), [OsX4(ox)]2-, X = Cl, Br, I
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Kristallstrukturen, Schwingungsspektren und Normalkoordinatenanalysen von Tetrahalogenooxalatoosmaten (IV), [OsX4(ox)]2-, X = Cl, Br, I / Crystal Structures, Vibrational Spectra and Normal Coordinate Analyses of Tetrahalogenooxalatoosmates (IV), [OsX4(ox)]2-, X = Cl, Br, I

  • W. Preetz and A. Krull
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 52 Issue 3

Abstract

The crystal structures of [(C5H5N)2CH2][OsCl4(ox)] (monoclinic, space group I2/m, a = 10.260(5), b = 13.841(5), c = 12.273(5) Å, β = 92.050(5)°, Z = 4), [(C5H5N)2CH2][OsBr4(ox)]·H2O(monoclinic, space group P21/n, a = 11.666(3),b = 11.591(5), c = 14.926(2) Å, β = 102.45(2)°, Z = 4) and [P(C6H5)4]2 [OsI4(ox)]·2CH2Cl2 (triclinic, space group P1̄, a = 14.597(2), b = 11.9185(9), c = 22.5624(14) Å, α = 80.284(8), β = 78.903(8), γ = 69.432(8)°, Z = 2) have been determined by single crystal X-ray diffraction analysis. The IR and Raman spectra of the three complexes were measured at room temperature. Using the molecular parameters of the X-ray determinations normal coordinate analyses based on a modified valence force field have been performed and the normal modes of vibration are assigned. With a set of 25 force constants and taking into account the innerligand vibrations a good agreement between observed and calculated frequencies has been achieved. The valence force constants of the X-Os-X axis are fd(OsCl) = 1.77, fd(OsBr) = 1.48, fd(OsI) = 1.0 mdyn/Å, of the X′-Os-O• axes are fd(OsCl′) = 1.88, fd(OsBr′) = 1.6, fd(OsI′) =1.1 mdyn/Å and fd(OsO•) ranges from 2.7 to 2.8 mdyn/Å.

: Tetrachlorooxalatoosmate(IV); Tetrabromooxalatoosmate(IV); Tetraiodooxalatoosmate(IV); Crystal Structure; Vibrational Spectra
Received: 1996-11-27
Published Online: 2014-6-2
Published in Print: 1997-3-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Calorimetrie an Yttriumtrihalogeniden und Yttriumoxidhalogemden / Calorimetry of Yttrium Trihalides and Yttrium Oxyhalides
  2. Calorimetrie an Ammoniumyttriumhalogeniden / Calorimetry of Ammonium Yttrium Halides
  3. Kristallstrukturen, Schwingungsspektren und Normalkoordinatenanalysen von Tetrahalogenooxalatoosmaten (IV), [OsX4(ox)]2-, X = Cl, Br, I / Crystal Structures, Vibrational Spectra and Normal Coordinate Analyses of Tetrahalogenooxalatoosmates (IV), [OsX4(ox)]2-, X = Cl, Br, I
  4. The Phenomenon of Intramolecular Attractive S---O Interactions: Synthesis and Structure of (1,10-Phenanthroline)copper(II) Complexes with Isonitroso-(4-methylthiazol-2-yl)acetamide and Isonitroso-(4-methylthiazol-2-yl)-(benzothiazol-2-yl)methanide
  5. Direct Synthesis of Zinc and Nickel(II) Complexes with 1,4-Diazabicyclo[2.2.2]octane
  6. Crystal Structure of the Di-bromo-bis(2-dimethylaminoethanolato)(dimethylsulfoxide)-copper(II)-lead(II) Dimer Obtained by Direct Synthesis
  7. Unsymmetrische BN23--Ionen in den Strukturen von Ca2ClBN2 und Sr2ClBN2 / Unsymmetric BN23--Ions in the Structures of Ca2ClBN2 and Sr2ClBN2
  8. Bromierung von „Poly(1,4-diselenobenzol)“ / Bromination of “Poly(1,4-diselenobenzene)”
  9. Monoheteroarylborate [1] / Monoheteroarylborates [1]
  10. 1,3-Di-terf-butyl-6H-benzo[b]naphtho[1,2-d]pyran-6-thione, a Severely Helically Distorted Thionolactone-Bridged Biaryl
  11. Synthese und Struktur von Kalium-4,4-difluor-[1,3,2]dithiazetidinid-1,l,3,3-tetraoxid und Rubidium-4,4,5,5-tetrafluor-[1,3,2]dithiazolidinid-1,1,3,3-tetraoxid / Syntheses and Structure of Potassium-4,4-difluoro-[1,3,2]dithiazetidinide-1,1,3,3- tetraoxide and Rubidium-4,4,5,5-tetrafluoro-[ 1,3,2]dithiazolidinide-1,1,3,3-tetraoxide
  12. Synthese und Kristallstruktur eines Barium-Zink-Vanadyl-phosphats BaZn(VO)(PO4)2 mit [(VO)PO4]-Schichten / Synthesis and Crystal Structure of a Barium-Zinc-Vanadyl-Phosphate BaZn(VO)(PO4)2 Containing [(VO)PO4] Layers
  13. Einkernige und oxoverbrückte zweikernige Fe(III)-Komplexe von N-Alkyl-N,N-bis(2-pyridylmethyl)aminen / Mononuclear and Oxo-Bridged Binuclear Fe(III) Complexes of N-Alkyl-N,N-bis(2-pyridylmethyl)amines
  14. Diphenyl(1-pyridyl)phosphine Sulfide as a Ligand in Mono-and Binuclear Coinage Metal Complexes
  15. Röntgenstrukturuntersuchungen an Elpasolith-verwandten Hexacyanokomplexen [N(CH3)4]2A[M(CN)6] (A = Rb, Tl; M = Cr, Fe) / X-Ray Structure Investigations of Elpasolite Related Hexacyano Complexes [N(CH3)4]2A[M(CN)6] (A = Rb, Tl; M = Cr, Fe)
  16. Synthese und Kristallstruktur von Hexa(tert-butyl)bismocenium-tetrachloroaluminat / Synthesis and Crystal Structure of Hexa(tert-butyl)bismocenium Tetrachloroaluminate
  17. Über die Reaktionen von (CH3)4N+I-, (CH3)4N+ICl2-, (CH3)4N+ICl4- und (CH3)4N+Cl- mit Trifluormethylhypochlorit CF3OCl / The Reactions of (CH3)4N+I-, ( CH3)4N+ICl2-, (CH3)4N+ICl4- and (CH3)4N+Cl- with Trifluoromethylhypochlorite CF3OCl
  18. Hydrothermal Synthesis and Crystal Structure of the New Manganese(II) Thioantimonate(III), Mn(en)3Sb4S7
  19. Bondenolide, a New Diterpenoid from the Seeds of Caesalpinia bonduc
  20. Enzymatic Racemic Resolution of a Fluorinated Substrate and Syntheses of E and Z Alkenes as Precursors for Some Biologically Active Fluorohexoses
  21. Synthesis and Chiroptical Properties of Some N-(2-Chloro-7-cyclopropyl-4,7-dihydro-4-oxo-thieno[2,3-b]pyridine-5-carbonyl) L-α-Amino Esters
  22. Notizen: Synthesis of N,C,C-Trilithio-2,5-diallyl-pyrrole and its Solvent-Controlled Reactions with Electrophiles Notizen
  23. Notizen: A New Lithium Amide with Bulky Substituents -Molecular Structure of N-Lithio-N-trimethylsilyl-9-amino- 9-borabicyclo[3.3.1]nonane; Competition between N-Li and BN(pp)π Interactions
https://doi.org/10.1515/znb-1997-0303

Articles in the same Issue

  1. Calorimetrie an Yttriumtrihalogeniden und Yttriumoxidhalogemden / Calorimetry of Yttrium Trihalides and Yttrium Oxyhalides
  2. Calorimetrie an Ammoniumyttriumhalogeniden / Calorimetry of Ammonium Yttrium Halides
  3. Kristallstrukturen, Schwingungsspektren und Normalkoordinatenanalysen von Tetrahalogenooxalatoosmaten (IV), [OsX4(ox)]2-, X = Cl, Br, I / Crystal Structures, Vibrational Spectra and Normal Coordinate Analyses of Tetrahalogenooxalatoosmates (IV), [OsX4(ox)]2-, X = Cl, Br, I
  4. The Phenomenon of Intramolecular Attractive S---O Interactions: Synthesis and Structure of (1,10-Phenanthroline)copper(II) Complexes with Isonitroso-(4-methylthiazol-2-yl)acetamide and Isonitroso-(4-methylthiazol-2-yl)-(benzothiazol-2-yl)methanide
  5. Direct Synthesis of Zinc and Nickel(II) Complexes with 1,4-Diazabicyclo[2.2.2]octane
  6. Crystal Structure of the Di-bromo-bis(2-dimethylaminoethanolato)(dimethylsulfoxide)-copper(II)-lead(II) Dimer Obtained by Direct Synthesis
  7. Unsymmetrische BN23--Ionen in den Strukturen von Ca2ClBN2 und Sr2ClBN2 / Unsymmetric BN23--Ions in the Structures of Ca2ClBN2 and Sr2ClBN2
  8. Bromierung von „Poly(1,4-diselenobenzol)“ / Bromination of “Poly(1,4-diselenobenzene)”
  9. Monoheteroarylborate [1] / Monoheteroarylborates [1]
  10. 1,3-Di-terf-butyl-6H-benzo[b]naphtho[1,2-d]pyran-6-thione, a Severely Helically Distorted Thionolactone-Bridged Biaryl
  11. Synthese und Struktur von Kalium-4,4-difluor-[1,3,2]dithiazetidinid-1,l,3,3-tetraoxid und Rubidium-4,4,5,5-tetrafluor-[1,3,2]dithiazolidinid-1,1,3,3-tetraoxid / Syntheses and Structure of Potassium-4,4-difluoro-[1,3,2]dithiazetidinide-1,1,3,3- tetraoxide and Rubidium-4,4,5,5-tetrafluoro-[ 1,3,2]dithiazolidinide-1,1,3,3-tetraoxide
  12. Synthese und Kristallstruktur eines Barium-Zink-Vanadyl-phosphats BaZn(VO)(PO4)2 mit [(VO)PO4]-Schichten / Synthesis and Crystal Structure of a Barium-Zinc-Vanadyl-Phosphate BaZn(VO)(PO4)2 Containing [(VO)PO4] Layers
  13. Einkernige und oxoverbrückte zweikernige Fe(III)-Komplexe von N-Alkyl-N,N-bis(2-pyridylmethyl)aminen / Mononuclear and Oxo-Bridged Binuclear Fe(III) Complexes of N-Alkyl-N,N-bis(2-pyridylmethyl)amines
  14. Diphenyl(1-pyridyl)phosphine Sulfide as a Ligand in Mono-and Binuclear Coinage Metal Complexes
  15. Röntgenstrukturuntersuchungen an Elpasolith-verwandten Hexacyanokomplexen [N(CH3)4]2A[M(CN)6] (A = Rb, Tl; M = Cr, Fe) / X-Ray Structure Investigations of Elpasolite Related Hexacyano Complexes [N(CH3)4]2A[M(CN)6] (A = Rb, Tl; M = Cr, Fe)
  16. Synthese und Kristallstruktur von Hexa(tert-butyl)bismocenium-tetrachloroaluminat / Synthesis and Crystal Structure of Hexa(tert-butyl)bismocenium Tetrachloroaluminate
  17. Über die Reaktionen von (CH3)4N+I-, (CH3)4N+ICl2-, (CH3)4N+ICl4- und (CH3)4N+Cl- mit Trifluormethylhypochlorit CF3OCl / The Reactions of (CH3)4N+I-, ( CH3)4N+ICl2-, (CH3)4N+ICl4- and (CH3)4N+Cl- with Trifluoromethylhypochlorite CF3OCl
  18. Hydrothermal Synthesis and Crystal Structure of the New Manganese(II) Thioantimonate(III), Mn(en)3Sb4S7
  19. Bondenolide, a New Diterpenoid from the Seeds of Caesalpinia bonduc
  20. Enzymatic Racemic Resolution of a Fluorinated Substrate and Syntheses of E and Z Alkenes as Precursors for Some Biologically Active Fluorohexoses
  21. Synthesis and Chiroptical Properties of Some N-(2-Chloro-7-cyclopropyl-4,7-dihydro-4-oxo-thieno[2,3-b]pyridine-5-carbonyl) L-α-Amino Esters
  22. Notizen: Synthesis of N,C,C-Trilithio-2,5-diallyl-pyrrole and its Solvent-Controlled Reactions with Electrophiles Notizen
  23. Notizen: A New Lithium Amide with Bulky Substituents -Molecular Structure of N-Lithio-N-trimethylsilyl-9-amino- 9-borabicyclo[3.3.1]nonane; Competition between N-Li and BN(pp)π Interactions
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