Home Synthesis, structure, and luminescence properties of double perovskites Ba2.9Sr0.1WO6: Eu3+ red emitting phosphor
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Synthesis, structure, and luminescence properties of double perovskites Ba2.9Sr0.1WO6: Eu3+ red emitting phosphor

  • Arif Ullah , Jinghao Zhuang , Zheng Liu , Xiaozhan Yang ORCID logo EMAIL logo and Wenlin Feng
Published/Copyright: September 29, 2023

Abstract

In this work, the phosphors of Eu3+ ions doped Ba2.9Sr0.1WO6 were successfully synthesized by the high-temperature solid-state method. The luminescence properties, including the emission and excitation spectra, fluorescent lifetimes, and CIE chromaticity coordinates were characterized. The crystal structure and composite of the samples were investigated by XRD (X-ray diffraction), and HRTEM (high-resolution transmission electron microscope). The emission spectra consist of the characteristic peak of Eu3+ excitation at 393 nm; the leading emission peak at 618 nm can be ascribed to the transition of 7F05L6. The optimal red emission is achieved by 2 % Eu3+ doping. This red Ba2.9Sr0.1WO6: Eu3+ has good luminescent properties and may have potential application in white LEDs.


Corresponding author: Xiaozhan Yang, School of Science, Chongqing University of Technology, Chongqing 400054, China; and Chongqing Key Laboratory of Green Energy Materials Technology and Systems, Chongqing 400054, China, E-mail:

Award Identifier / Grant number: KJZD-K202201107

Award Identifier / Grant number: 51574054

Funding source: Chongqing Science and Technology Bureau

Award Identifier / Grant number: CSTB2022NSCQ-MSX0356

Award Identifier / Grant number: cstc2021jcyj-msxmX0493

Funding source: Joint Fund of Chongqing Municipal Education Commission and Science and Technology Bureau

Award Identifier / Grant number: CSTB2022NSCQ- LZX0032

Award Identifier / Grant number: KJZD-M201901102

Funding source: National Natural Science Foundation of China

Award Identifier / Grant number: Unassigned

Acknowledgments

The authors would like to acknowledge support from the National Natural Science Foundation of China (51574054), Chongqing Municipal Education Commission (KJZD-M201901102, KJZD-K202201107), Joint Fund of Chongqing Municipal Education Commission and Science and Technology Bureau (CSTB2022NSCQ- LZX0032), Chongqing Science and Technology Bureau (cstc2021jcyj-msxmX0493, CSTB2022NSCQ-MSX0356).

  1. Research ethics: Not applicable.

  2. Author contributions: Arif Ullah, Jinghao Zhuang: Conceptualization, Methodology, Writing – original draft, Writing – review & editing, Investigation, Data curation. Zheng Liu: Software, Visualization, Validation, Formal analysis. Xiaozhan Yang: Supervision. Wenlin Feng: Software, Resources.

  3. Competing interests: The authors state no competing interests.

  4. Research funding: National Natural Science Foundation of China (51574054), Chongqing Municipal Education Commission (KJZD-M201901102, KJZD-K202201107), Joint Fund of Chongqing Municipal Education Commission and Science and Technology Bureau (CSTB2022NSCQ- LZX0032), Chongqing Science and Technology Bureau (cstc2021jcyj-msxmX0493, CSTB2022NSCQ-MSX0356).

  5. Data availability: The raw data can be obtained on request from the corresponding author.

References

[1] X. T. Zhang, D. Zhang, B. F. Zheng, et al.., “Luminescence and energy transfer of color-tunable Y2Mg2Al2Si2O12:Eu2+, Ce3+ phosphors,” Inorg. Chem., vol. 60, pp. 5908–5916, 2021. https://doi.org/10.1021/acs.inorgchem.1c00317.Search in Google Scholar PubMed

[2] H. Chen and Y. Wang, “Photoluminescence and cathodoluminescence properties of novel rare-earth free narrow-band bright green-emitting ZnB2O4:Mn2+ phosphor for LEDs and FEDs,” Chem. Eng. J., vol. 361, pp. 314–321, 2019. https://doi.org/10.1016/j.cej.2018.12.039.Search in Google Scholar

[3] K. Indumathi, S. Tamilselvan, L. Rajasekaran, et al.., “Structural and optical properties of Eu3+ doped Sr3Gd[PO4]3 phosphor white-LED application,” Mater. Lett., vol. 309, p. 131371, 2022. https://doi.org/10.1016/j.matlet.2021.131371.Search in Google Scholar

[4] S.-M. Chen, Q. Zeng, C.-F. Yao, Y.-Y. Liu, Y. Qin, and Z.-Y Min, “Synthesis and luminescent properties of novel Li1.0Nb0.6Ti0.5O3: Dy3+ phosphors for white light-emitting diodes,” J. Lumin., vol. 244, p. 118697, 2022. https://doi.org/10.1016/j.jlumin.2021.118697.Search in Google Scholar

[5] P. Rohilla and A. S. Rao, “Synthesis optimisation and efficiency enhancement in Eu3+ doped barium molybdenum titanate phosphors for w-LED applications,” Mater. Res. Bull., vol. 150, p. 111753, 2022. https://doi.org/10.1016/j.materresbull.2022.111753.Search in Google Scholar

[6] X. Geng, Y. Xie, Y. Y. Ma, et al.., “Abnormal thermal quenching and application for w-LEDs: double perovskite Ca2InSbO6: Eu3+ red-emitting phosphor,” J. Alloys Compd., vol. 847, p. 156249, 2020. https://doi.org/10.1016/j.jallcom.2020.156249.Search in Google Scholar

[7] M. Zhao, B. Li, P. Wang, et al.., “Supramolecularly engineered NIR‐II and upconversion nanoparticles in vivo assembly and disassembly to improve bioimaging,” Adv. Mater., vol. 30, p. 1804982, 2018. https://doi.org/10.1002/adma.201804982.Search in Google Scholar PubMed

[8] S. Gu, M. Xia, C. Zhou, et al.., “Red shift properties, crystal field theory and nephelauxetic effect on Mn4+-doped SrMgAl10-yGayO17 red phosphor for plant growth LED light,” Chem. Eng. J., vol. 396, p. 125208, 2020. https://doi.org/10.1016/j.cej.2020.125208.Search in Google Scholar

[9] Y. Qin, P. Tao, L. Gao, et al.., “Designing highly efficient phosphorescent neutral tetrahedral manganese (II) complexes for organic light‐emitting diodes,” Adv. Opt. Mater., vol. 7, p. 1801160, 2019. https://doi.org/10.1002/adom.201801160.Search in Google Scholar

[10] Y.-Y. Zhou, E.-H. Song, T.-T. Deng, and Q. Y. Zhang, “Waterproof narrow-band fluoride red phosphor K2TiF6: Mn4+ via facile superhydrophobic surface modification,” ACS Appl. Mater. Interfaces, vol. 10, no. 1, pp. 880–889, 2018. https://doi.org/10.1021/acsami.7b15503.Search in Google Scholar PubMed

[11] P. Strobel, V. Weiler, C. Hecht, P. J. Schmidt, and W. Schnick, “Luminescence of the narrow-band red emitting nitridomagnesosilicate Li2(Ca1-xSrx)2[Mg2Si2N6]: Eu2+ (x=0-0.06),” Chem. Mater., vol. 29, pp. 1377–1383, 2017. https://doi.org/10.1021/acs.chemmater.6b05196.Search in Google Scholar

[12] M. Cui, J. Wang, M. Shang, et al.., “Full visible light emission in Eu2+, Mn2+-doped Ca9LiY0.667(PO4)7 phosphors based on multiple crystal lattice substitution and energy transfer for warm white LEDs with high colour-rendering,” J. Mater. Chem. C, vol. 7, pp. 3644–3655, 2019. https://doi.org/10.1039/c9tc00109c.Search in Google Scholar

[13] S. Wu, P. Xiong, Q. Liu, et al.., “Self‐activated tungstate phosphor for near‐infrared light‐emitting diodes,” Adv. Opt. Mater., vol. 10, p. 2201718, 2022. https://doi.org/10.1002/adom.202201718.Search in Google Scholar

[14] X. Jin, Y. Xie, R. Tang, et al.., “Novel double perovskite Sr3WO6: Sm3+, Na+ orange-red emitting phosphors with high thermal stability for white LEDs,” J. Alloys Compd., vol. 899, p. 162739, 2022. https://doi.org/10.1016/j.jallcom.2021.162739.Search in Google Scholar

[15] X. Li, H. Xu, X. Xia, F. Xie, S. Zhong, and D. Xu, “One-step synthesis of Sc2W3O12: Eu3+ phosphors with tunable luminescence for WLED,” Ceram. Int., vol. 45, pp. 10461–10467, 2019. https://doi.org/10.1016/j.ceramint.2019.02.107.Search in Google Scholar

[16] X. Shi, J. Li, Q. Zhu, X. Li, and X. Sun, “Hydrothermal assisted synthesis and photoluminescence of (Y1-xEux)2WO6 red phosphors,” J. Alloys Compd., vol. 695, pp. 1984–1992, 2017. https://doi.org/10.1016/j.jallcom.2016.11.033.Search in Google Scholar

[17] M. Sletnes, J. C. Valmalette, T. Grande, and M. A. Einarsrud, “Compositional dependence of the crystal symmetry of Eu3+-doped(SrxBa1−x)2CaWyMo1−yO6 phosphors,” J. Solid State Chem., vol. 233, pp. 30–36, 2016. https://doi.org/10.1016/j.jssc.2015.10.014.Search in Google Scholar

[18] B. Ding, C. Yu, J. Xin, et al.., “Effect of Dy3+ and Eu3+ 4f band gap states on luminescence and energy transfer in monoclinic lutetium tungstate,” ACS Appl. Electron. Mater., vol. 1, pp. 772–782, 2019. https://doi.org/10.1021/acsaelm.9b00115.Search in Google Scholar

[19] C. Cao, Z. Zhang, S. Wei, A. Xie, H. M. Noh, and J. H. Jeong, “Synthesis, optical properties, energy transfer, thermal behavior, and LED package of Eu3+ doped lutetium tungsten oxide phosphors,” Opt. Mater., vol. 101, p. 109753, 2020. https://doi.org/10.1016/j.optmat.2020.109753.Search in Google Scholar

[20] N. Xiao, J. Shen, T. J. Xiao, et al.., “Sr2CaWxMo1−xO6: Eu3+, Li+: an emission tunable phosphor through site symmetry and excitation wavelength,” Mater. Res. Bull., vol. 70, pp. 684–690, 2015. https://doi.org/10.1016/j.materresbull.2015.06.001.Search in Google Scholar

[21] L. Li, W. Chang, W. Chen, et al.., “Double perovskite LiLaMgWO6: Eu3+ novel red-emitting phosphors for solid sate lighting: synthesis, structure and photoluminescent properties,” Ceram. Int., vol. 43, pp. 2720–2729, 2017. https://doi.org/10.1016/j.ceramint.2016.11.093.Search in Google Scholar

[22] R. Cao, C. Chen, F. Cheng, et al.., “Synthesis and luminescence properties of Eu3+, Dy3+ co-doped Ca3Bi(PO4)3 single-phase phosphor,” J. Lumin., vol. 257, p. 119731, 2023. https://doi.org/10.1016/j.jlumin.2023.119731.Search in Google Scholar

[23] Y. Hua, T. Wang, H. Li, J. S. Yu, and L. Li, “Charge transfer band excited (Sr, Ba)2YTaO6: Eu3+ reddish-orange-emitting phosphors for luminescence lifetime thermometry and flexible anti-counterfeiting labels,” J. Alloys Compd., vol. 930, p. 167454, 2023. https://doi.org/10.1016/j.jallcom.2022.167454.Search in Google Scholar

[24] R. Cao, Z. Lai, Y. Cao, et al.., “CaAl2Si2O8: Dy3+, Eu3+: synthesis, luminescence properties, energy transfer, and tunable emission,” New J. Chem., vol. 47, pp. 10025–10035, 2023. https://doi.org/10.1039/d3nj00917c.Search in Google Scholar

Received: 2023-08-01
Accepted: 2023-09-04
Published Online: 2023-09-29
Published in Print: 2023-11-27

© 2023 Walter de Gruyter GmbH, Berlin/Boston

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