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Structural influences of the substituents of tridentate triazole-based ligands – more than just a minor role in the solid-state structure

  • Simon Kroos and Marian Hebenbrock EMAIL logo
Published/Copyright: July 5, 2024
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Zeitschrift für Kristallographie - Crystalline Materials
From the journal Zeitschrift für Kristallographie - Crystalline Materials Volume 239 Issue 7-8

Abstract

New triazole-based tridentate ligands were synthesized, and their crystal structures determined. Through comparison with the crystal structures of the starting materials and related published ligands, dependencies of intermolecular interactions based on the substitution patterns of the triazole motif were identified. In addition to π-stacking interactions, hydrogen bonding, and C–H···π interactions emerged as key players in intermolecular interactions. The observed variations in these interactions will aid in the design of platinum(II) complexes with specific properties.

Keywords: tridentate ligands; intermolecular interactions; triazole; morpholine; Hirshfeld surface analysis
Corresponding author: Marian Hebenbrock, Universität Münster, Institut für Anorganische und Analytische Chemie, Corrensstr. 28/30, 48149 Münster, Germany, E-mail:

Acknowledgments

The authors thankfully acknowledge the financial and non-material support by Prof. Jens Müller and access to the laboratories and chemicals.

  1. Research ethics: Not applicable.

  2. Author contributions: All authors have accepted responsibility for the entire content of this submitted manuscript and approved the submission.

  3. Competing interests: The authors declare no conflicts of interest regarding this article.

  4. Research funding: This research was funded by Universität Münster.

  5. Data availability: Data is available from the corresponding author on well-founded request.

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Supplementary Material

This article contains supplementary material (https://doi.org/10.1515/zkri-2024-0069).

Received: 2024-02-20
Accepted: 2024-04-17
Published Online: 2024-07-05
Published in Print: 2024-08-27

© 2024 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. In this issue
  3. Organic and Metalorganic Crystal Structures (Original Paper)
  4. Structural influences of the substituents of tridentate triazole-based ligands – more than just a minor role in the solid-state structure
  5. Inorganic Crystal Structures (Original Paper)
  6. Multinuclear solid state NMR spectroscopy of ternary rare-earth silicides RET 2Si2 and germanides LaT 2Ge2 (RE = Sc, Y, La, Lu; T = Fe, Co, Ni, Cu, Ru, Rh, Pd, Ag, Os, Ir, Pt, Au)
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https://doi.org/10.1515/zkri-2024-0069
Keywords for this article
tridentate ligands; intermolecular interactions; triazole; morpholine; Hirshfeld surface analysis

Articles in the same Issue

  1. Frontmatter
  2. In this issue
  3. Organic and Metalorganic Crystal Structures (Original Paper)
  4. Structural influences of the substituents of tridentate triazole-based ligands – more than just a minor role in the solid-state structure
  5. Inorganic Crystal Structures (Original Paper)
  6. Multinuclear solid state NMR spectroscopy of ternary rare-earth silicides RET 2Si2 and germanides LaT 2Ge2 (RE = Sc, Y, La, Lu; T = Fe, Co, Ni, Cu, Ru, Rh, Pd, Ag, Os, Ir, Pt, Au)
  7. [Cd7(SeO3)8]{Cu2Br2}, a host-guest structure derived from β-CdSeO3
  8. Mechanochemical synthesis of (Mg1−xFe x )2SiO4 olivine phases relevant to Martian regolith: structural and spectroscopic characterizations
  9. CaRu2Zn10, SrRu2Zn10 and EuRu2Zn10 – new superstructure variants of ThMn12
  10. Organic and Metalorganic Crystal Structures (Original Paper)
  11. Crystal structure and tautomeric state of Pigment Red 48:2 from X-ray powder diffraction and solid-state NMR
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