Startseite Cyclic polyamines as templates for novel complex topologies in uranyl sulfates and selenates
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Cyclic polyamines as templates for novel complex topologies in uranyl sulfates and selenates

  • Vladislav V. Gurzhiy EMAIL logo , Olga S. Tyumentseva , Sergey V. Krivovichev und Ivan G. Tananaev
Veröffentlicht/Copyright: 2. Februar 2018
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Zeitschrift für Kristallographie - Crystalline Materials
Aus der Zeitschrift Zeitschrift für Kristallographie - Crystalline Materials Band 233 Heft 3-4

Abstract

Single crystals of two novel uranyl sulfates and two novel uranyl selenates with protonated cyclen and 3-aminotropane molecules, ((C8H24N4)[(UO2)3(SO4)5](H2O)3 (I), (C8H24N4)(H5O2)(H3O)[(UO2)4(SeO4)7(H2O)](H2O)6.6 (II), (C8H18N2)(H5O2)(H3O)[(UO2)3(SO4)5(H2O)](H2O)0.5 (III), and (C8H18N2)(H5O2)(H3O)[(UO2)3(SeO4)5 (H2O)](H2O)2 (IV) have been prepared by isothermal evaporation from aqueous solutions and structurally characterized. Uranyl-containing 2D units have been investigated using topological approach and information-based complexity measures demonstrating that complex topologies form more rare than their simplest counterparts, which is a response of the crystal structure to changes of chemical conditions within the system.

Keywords: aminotropane; complexity; cyclen; single crystal X-ray diffraction; topology; uranyl selenates; uranyl sulfates

Acknowledgements

This work was supported by the President of Russian Federation grants for young scientists (to VVG, no. MK-6209.2016.5) and Russian Foundation for Basic Research (to OST, no. 16-33-60142-mol-a-dk). X-ray diffraction studies were carried out in the X-ray Diffraction Centre of St. Petersburg State University.

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Supplemental Material:

The online version of this article offers supplementary material (https://doi.org/10.1515/zkri-2017-2129).

Received: 2017-11-7
Accepted: 2017-12-22
Published Online: 2018-2-2
Published in Print: 2018-3-28

©2018 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. Graphical Synopsis
  3. Special issue “Deciphering the complexity of mineral structures”
  4. Preface
  5. Ladders of information: what contributes to the structural complexity of inorganic crystals
  6. Single-crystal analysis of nanodomains by electron diffraction tomography: mineralogy at the order-disorder borderline
  7. Derivative structures based on the sphere packing
  8. From structure topology to chemical composition. XXV: new insights into the close packing of cations in the structures of the seidozerite-supergroup TS-block minerals
  9. The (3+3) commensurately modulated structure of the uranyl silicate mineral swamboite-(Nd), Nd0.333[(UO2)(SiO3OH)](H2O)2.41
  10. Cyclic polyamines as templates for novel complex topologies in uranyl sulfates and selenates
  11. Old defined minerals with complex, still unresolved structures: the case of stützite, Ag5−x Te3
  12. The incommensurately modulated crystal structure of roshchinite, Cu0.09Ag1.04Pb0.65Sb2.82As0.37S6.08
  13. Another step toward the solution of the real structure of zinkenite
  14. Reexamination of the crystal structure of semseyite, Pb9Sb8S21
https://doi.org/10.1515/zkri-2017-2129
Schlagwörter für diesen Artikel
aminotropane; complexity; cyclen; single crystal X-ray diffraction; topology; uranyl selenates; uranyl sulfates

Artikel in diesem Heft

  1. Frontmatter
  2. Graphical Synopsis
  3. Special issue “Deciphering the complexity of mineral structures”
  4. Preface
  5. Ladders of information: what contributes to the structural complexity of inorganic crystals
  6. Single-crystal analysis of nanodomains by electron diffraction tomography: mineralogy at the order-disorder borderline
  7. Derivative structures based on the sphere packing
  8. From structure topology to chemical composition. XXV: new insights into the close packing of cations in the structures of the seidozerite-supergroup TS-block minerals
  9. The (3+3) commensurately modulated structure of the uranyl silicate mineral swamboite-(Nd), Nd0.333[(UO2)(SiO3OH)](H2O)2.41
  10. Cyclic polyamines as templates for novel complex topologies in uranyl sulfates and selenates
  11. Old defined minerals with complex, still unresolved structures: the case of stützite, Ag5−x Te3
  12. The incommensurately modulated crystal structure of roshchinite, Cu0.09Ag1.04Pb0.65Sb2.82As0.37S6.08
  13. Another step toward the solution of the real structure of zinkenite
  14. Reexamination of the crystal structure of semseyite, Pb9Sb8S21
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