Startseite A “missing” caesium member in the family of A3Al2P3O12 aluminophosphates
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A “missing” caesium member in the family of A3Al2P3O12 aluminophosphates

  • Larisa Shvanskaya EMAIL logo und Olga Yakubovich
Veröffentlicht/Copyright: 7. Februar 2017
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Zeitschrift für Kristallographie - Crystalline Materials
Aus der Zeitschrift Zeitschrift für Kristallographie - Crystalline Materials Band 232 Heft 5

Abstract

A new caesium aluminophosphate, Cs3Al2P3O12, has been synthesized by spontaneous crystallization from the melt and structurally characterized. The compound crystallizes in the orthorhombic space group Pnma, with a=9.7675(2) Å, b=17.7537(3) Å, c=8.1063(2) Å, V=1405.71(2) Å3, and Z=4. Its crystal structure is based on an open interrupted framework built by alternating AlO4 and PO4 tetrahedra with Cs ions occupying the channels. The Cs3Al2P3O12 framework topology resembles the previously known 4.8.12-net, which has been reported in the [C4N3H16][Al2P3O12] phase prepared by solvothermal synthesis in the presence of diethylenetriamine (DETA). The crystal chemical relationships between the K, Rb, Cs, Tl, [NH4] and [C4N3H16]-members of the A3Al2P3O12 family of compounds are discussed.

Keywords: crystal structure; high-temperature crystallization; open interrupted framework; single-crystal X-ray diffraction; topology

Acknowledgments

We thank V.O.Yapaskurt for the X-ray spectral analysis of the sample, N.V. Zubkova for her help in the X-ray experiment and L.V. Melchakova for the DTA and TGA experimental data. This work was supported in part by the Ministry of Education and Science of the Russian Federation in the framework of Increase Competitiveness Program of NUST “MISiS” (project No. K2-2016-066).

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Supplemental Material:

The online version of this article (DOI: 10.1515/zkri-2016-2012) offers supplementary material, available to authorized users.

Received: 2016-10-5
Accepted: 2017-1-10
Published Online: 2017-2-7
Published in Print: 2017-5-1

©2017 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. Graphical Synopsis
  3. Obituary
  4. Howard David Flack (1943–2017)
  5. Inorganic Crystal Structures
  6. Crystal structures of [SbF6]− salts of di- and tetrahydrated Ag +, tetrahydrated Pd2 + and hexahydrated Cd2 + cations
  7. The novel stairs-like layered compound Co5(OH)6(H2O)2[SO3]2
  8. A “missing” caesium member in the family of A3Al2P3O12 aluminophosphates
  9. Ternary gallides RE4Rh9Ga5, RE5Rh12Ga7 and RE7Rh18Ga11 (RE=Y, La–Nd, Sm, Gd, Tb) – intergrowth structures with MgCu2 and CaCu5 related slabs
  10. Organic and Metalorganic Crystal Structures
  11. OD- and non-OD-polytypism of 9-(3-chloropyridin-4-yl)-9H-carbazole
  12. Two mefenamic acid derivatives: structural study using powder X-ray diffraction, Hirshfeld surface and molecular electrostatic potential calculations
  13. Role of halogen substituents in a series of polymorphic 2,5-diamino-3,6-dicyanopyrazine derivatives with highly flexible groups
https://doi.org/10.1515/zkri-2016-2012
Schlagwörter für diesen Artikel
crystal structure; high-temperature crystallization; open interrupted framework; single-crystal X-ray diffraction; topology

Artikel in diesem Heft

  1. Frontmatter
  2. Graphical Synopsis
  3. Obituary
  4. Howard David Flack (1943–2017)
  5. Inorganic Crystal Structures
  6. Crystal structures of [SbF6]− salts of di- and tetrahydrated Ag +, tetrahydrated Pd2 + and hexahydrated Cd2 + cations
  7. The novel stairs-like layered compound Co5(OH)6(H2O)2[SO3]2
  8. A “missing” caesium member in the family of A3Al2P3O12 aluminophosphates
  9. Ternary gallides RE4Rh9Ga5, RE5Rh12Ga7 and RE7Rh18Ga11 (RE=Y, La–Nd, Sm, Gd, Tb) – intergrowth structures with MgCu2 and CaCu5 related slabs
  10. Organic and Metalorganic Crystal Structures
  11. OD- and non-OD-polytypism of 9-(3-chloropyridin-4-yl)-9H-carbazole
  12. Two mefenamic acid derivatives: structural study using powder X-ray diffraction, Hirshfeld surface and molecular electrostatic potential calculations
  13. Role of halogen substituents in a series of polymorphic 2,5-diamino-3,6-dicyanopyrazine derivatives with highly flexible groups
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