RE13Pd25+xZn28–x (RE = Y, Ho–Lu) – A 4 × 4 × 4 tungsten superstructure with short Pd/Zn dumbbells as structural motif
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Birgit Gerke
Abstract
The rare earth-based zinc compounds RE13Pd25+xZn28–x (RE = Y, Ho–Lu) were synthesized from the elements in sealed niobium ampoules with a maximum reaction temperature of 1470 K followed by different annealing sequences. The structures of all compounds were refined from single crystal X-ray diffraction data, indicating substantial Zn/Pd mixing on one 8c and one 24g zinc site. Exemplarily, the homogeneity range of the solid solution Yb13Pd25+xZn28–x was manifested from samples of different starting compositions and five single crystal data sets. The RE13Pd25+xZn28–x structures are cubic, space group I4̅3m with lattice parameters ranging from 1295 to 1307 pm, as a function of the rare earth element and the Zn/Pd mixing. Hierarchically, one can derive the RE13Pd25+xZn28–x structures from the simple bcc packing. A group–subgroup scheme was developed for this new 4 × 4 × 4 tungsten superstructure which shows vacancy ordering and dumbbell formation. Temperature dependent magnetic susceptibility measurements show diamagnetism for a Lu13Pd29Zn24 sample and Curie–Weiss paramagnetism for Tm13Pd29Zn24 down to 3 K.
Acknowledgments:
We thank Dipl.-Ing. Ute Ch. Rodewald and Dr. Timo Bartsch for collecting the single crystal intensity data. B.G. and O.N. are indebted to the Fonds der Chemischen Industrie and the NRW Forschungsschule Molecules and Materials – A Common Design Principle for PhD fellowships.
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©2016 by De Gruyter
Artikel in diesem Heft
- Frontmatter
- Graphical Synopsis
- Inorganic Crystal Structures
- The crystal structure of a fluorine-dominant titanium calcium amphibole from the Eifel paleovolcanic area, Germany
- RE13Pd25+xZn28–x (RE = Y, Ho–Lu) – A 4 × 4 × 4 tungsten superstructure with short Pd/Zn dumbbells as structural motif
- Organic and Metalorganic Crystal Structures
- Bis[bis(N-2-hydroxyethyl,N-isopropyl-dithiocarbamato)mercury(II)]2: crystal structure and Hirshfeld surface analysis
- Structural, Hirshfeld surface and theoretical analysis of two conformational polymorphs of N,N′-bis(pyridin-3-ylmethyl)oxalamide
- Superspace description of trimethyltin hydroxide at T = 100 K
- Halogen and hydrogen bonding in cis-dichlorobis(propionitrile)platinum(II) chloroform monosolvate
- Synthesis and structural phase transitions of [Mg2Sb2(C4H2O6)2(H2O)8](ClO4)2·5H2O with complex homochiral chains
Artikel in diesem Heft
- Frontmatter
- Graphical Synopsis
- Inorganic Crystal Structures
- The crystal structure of a fluorine-dominant titanium calcium amphibole from the Eifel paleovolcanic area, Germany
- RE13Pd25+xZn28–x (RE = Y, Ho–Lu) – A 4 × 4 × 4 tungsten superstructure with short Pd/Zn dumbbells as structural motif
- Organic and Metalorganic Crystal Structures
- Bis[bis(N-2-hydroxyethyl,N-isopropyl-dithiocarbamato)mercury(II)]2: crystal structure and Hirshfeld surface analysis
- Structural, Hirshfeld surface and theoretical analysis of two conformational polymorphs of N,N′-bis(pyridin-3-ylmethyl)oxalamide
- Superspace description of trimethyltin hydroxide at T = 100 K
- Halogen and hydrogen bonding in cis-dichlorobis(propionitrile)platinum(II) chloroform monosolvate
- Synthesis and structural phase transitions of [Mg2Sb2(C4H2O6)2(H2O)8](ClO4)2·5H2O with complex homochiral chains
