The interaction of ester functionalized amide gemini surfactants with polymers
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Yue Lei
Haiyan Gao is an associate professor, she received a doctorate in science from the Institute of Coal Chemistry, Chinese Academy of Sciences in 2003. Research direction is physical chemistry, synthesis and application of chemicals.
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Hujun Xu
Hujun Xu is a professor, he received his Ph.D. degree in 2005 from Nanjing University of Science and Technology, P.R. China. He has been involved in surfactants and detergents for over 30 years. He has published over 100 papers in the field of surfactants and detergents.
Abstract
In this study the interaction between the esterified amide gemini surfactant C12-(BAE)-C12, where BAE stands for the bis(acetoxy)ethane linking group, and the non-ionic polymer polyvinylpyrrolidone (PVP) was investigated by the surface tension method. It was found that there was no apparent interaction between them. The interaction between C12-(BAE)-C12 and sodium polyelectrolyte polyacrylate (NaPAA) was investigated by surface tension, micropolarity and turbidity measurements. The results showed that there was a strong interaction between them. The aggregates were formed by electrostatic attraction between the molecules of C12-(BAE)-C12 and NaPAA in the bulk. This process led to the appearance of two inflection points, the critical aggregation concentration (cac) and the critical micelle concentration (CMC), on the surface tension and micropolarity curves. In addition, the inorganic salt NaBr had two opposite effects, promoting or inhibiting the interaction between C12-(BAE)-C12 and NaPAA. This was related to the concentration of NaBr itself.
About the authors
Haiyan Gao is an associate professor, she received a doctorate in science from the Institute of Coal Chemistry, Chinese Academy of Sciences in 2003. Research direction is physical chemistry, synthesis and application of chemicals.
Hujun Xu is a professor, he received his Ph.D. degree in 2005 from Nanjing University of Science and Technology, P.R. China. He has been involved in surfactants and detergents for over 30 years. He has published over 100 papers in the field of surfactants and detergents.
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Research ethics: Not applicable.
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Author contributions: Yue Lei: Conceptualization, Methodology, Software, Investigation, Formal Analysis, Writing- Original draft preparation; Yue Liu: Data Curation, Writing - Original Draft; Yuheng Li: Visualization, Investigation; Xiaohao Lu: Software, Validation; Haiyan Gao∗: Conceptualization, Supervision, Writing - Review & Editing; Hujun Xu: Visualization, Resources, Supervision.
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Competing interests: The authors declare no conflict of interest.
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Research funding: None declared.
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Data availability: Paper data are available upon request.
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- The interaction of ester functionalized amide gemini surfactants with polymers
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Articles in the same Issue
- Frontmatter
- Physical Chemistry
- Transition from a foam-like to an onion-like nanostructure in water-rich L3 phases
- Simulation of adsorption at rotating disk
- Wetting behaviour of ionic surfactants on the aluminium foil
- The interaction of ester functionalized amide gemini surfactants with polymers
- Biosurfactants
- The use of polyoxyethylene (20) cetyl ether in assessing the hydrophobicity of compounds of biomedical importance and in the process of drug release from microemulsions
- Novel Surfactants
- Synthesis, characterization, and evaluation of ethoxylated lauryl myristyl alcohol as non-ionic surfactants (surfethoxymers)
- Synthesis
- Synthesis and surface properties of branched-chain tertiary fatty alcohol sulfate surfactants
- Application
- Influence of surfactant concentration on selected quality parameters of fruit washing agents
- Preparation, characterization, and stability of lipid nanoparticles including unsaturated lipids
- Drug Delivery System
- Design, characterization, and evaluation of novel mucoadhesive nasal inserts for the treatment of hypertension
- Review
- An overview on eco-friendly polyglycerol esters of fatty acid, synthesis and applications
