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Experimental methods for the determination of stress changes at electrified solid-liquid interfaces

  • Gyözö G. Láng

    Eötvös Loránd University, Institute of Chemistry, Department of Physical Chemistry, H-1117 Budapest, Pázmány P. s. 1/A, Hungary, http://orcid.org/0000-0002-8362-7671

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    , Noémi Kovács

    Eötvös Loránd University, Institute of Chemistry, Department of Physical Chemistry, H-1117 Budapest, Pázmány P. s. 1/A, Hungary

    , Soma Vesztergom

    Eötvös Loránd University, Institute of Chemistry, Department of Physical Chemistry, H-1117 Budapest, Pázmány P. s. 1/A, Hungary, http://orcid.org/0000-0001-7052-4553

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    , Mária Ujvári

    Eötvös Loránd University, Institute of Chemistry, Department of Physical Chemistry, H-1117 Budapest, Pázmány P. s. 1/A, Hungary

    , Dóra Zalka

    Eötvös Loránd University, Institute of Chemistry, Department of Physical Chemistry, H-1117 Budapest, Pázmány P. s. 1/A, Hungary

    and Krisztina Szekeres

    Eötvös Loránd University, Institute of Chemistry, Department of Physical Chemistry, H-1117 Budapest, Pázmány P. s. 1/A, Hungary

Published/Copyright: May 9, 2017

Abstract

In the present study some of the methods developed for the experimental determination of (interfacial or film) stress changes in electrochemical systems containing solid-liquid interfaces are briefly reviewed, as well as the kind and quality of information that can be obtained using these methods are discussed. The “bending beam” (“bending cantilever”, “laser beam deflection”, “wafer curvature”) method and related techniques, the piezoelectric method, the extensometer method, and the method based on the measurement of contact angle are discussed in detail. Special attention has been paid to problems related to the use of optical methods for position sensing.

Zusammenfassung

Die vorgestellte Studie stellt einige der Methoden vor, die in elektrochemischen Systemen zur experimentellen Bestimmung der Grenzflächenspannungen an den Phasengrenzen flüssig/fest von Elektroden oder darauf lokalisierten Filmen genutzt werden können. Darüber hinaus werden die Resultate der Verfahren im Hinblick auf Art und Qualität ihrer Aussage bewertet. Sowohl optische Verfahren zur Messung der Krümmung (,,bending cantilever“, ,,laser beam deflection“, ,,wafer curvature“) und vergleichbare Techniken, als auch das piezoelektrische Verfahren, die Nutzung eines Extensometers und die Messung des Kontaktwinkels werden detailliert diskutiert. Besonderes Augenmerk wurde bei den optischen Verfahren auf die der Darstellung der Notwendigkeit der genauen Kenntnis der Positionierung der einzelnen Komponenten gelegt.

Funding statement: This research has received funding from the Hungarian Scientific Research Fund (OTKA) under Grant Agreement number K 109036.

About the authors

Gyözö G. Láng

Eötvös Loránd University, Institute of Chemistry, Department of Physical Chemistry, H-1117 Budapest, Pázmány P. s. 1/A, Hungary, http://orcid.org/0000-0002-8362-7671

Noémi Kovács

Eötvös Loránd University, Institute of Chemistry, Department of Physical Chemistry, H-1117 Budapest, Pázmány P. s. 1/A, Hungary

Soma Vesztergom

Eötvös Loránd University, Institute of Chemistry, Department of Physical Chemistry, H-1117 Budapest, Pázmány P. s. 1/A, Hungary, http://orcid.org/0000-0001-7052-4553

Mária Ujvári

Eötvös Loránd University, Institute of Chemistry, Department of Physical Chemistry, H-1117 Budapest, Pázmány P. s. 1/A, Hungary

Dóra Zalka

Eötvös Loránd University, Institute of Chemistry, Department of Physical Chemistry, H-1117 Budapest, Pázmány P. s. 1/A, Hungary

Krisztina Szekeres

Eötvös Loránd University, Institute of Chemistry, Department of Physical Chemistry, H-1117 Budapest, Pázmány P. s. 1/A, Hungary

Received: 2016-12-16
Revised: 2017-2-28
Accepted: 2017-4-8
Published Online: 2017-5-9
Published in Print: 2017-10-26

©2017 Walter de Gruyter Berlin/Boston

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