Startseite Organomonophosphines in PtP2Cl2 derivatives: structural aspects
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Organomonophosphines in PtP2Cl2 derivatives: structural aspects

  • Milan Melník EMAIL logo und Peter Mikuš
Veröffentlicht/Copyright: 30. Juni 2015

Abstract

In this review, 260 monomeric Pt(II) complexes are summarized and analyzed in which the inner coordination sphere is built up by a pair of organomonophosphines and two chlorine atoms (PtP2Cl2). These complexes are crystallized in four crystal systems: tetragonal (x17)<orthorhombic (x31)<triclinic (x90)<monoclinic (x122). The square-planar environments have cis- and trans-configurations. The former by far prevails. The mean Pt-L bond distances (cis- vs. trans-configurations) are 2.347 Å (Cl, trans to P) and 2.230 Å (P, trans to Cl) vs. 2.307 Å (Cl, trans to Cl) and 2.320 Å (P, trans to P). There are two types of isomerisms: cis-, trans- and distortion. In general, the derivatives with a cis-configuration are somewhat more distorted than that with a trans-configuration.


Corresponding author: Milan Melník, Faculty of Pharmacy, Department of Pharmaceutical Analysis and Nuclear Pharmacy, Comenius University in Bratislava, Odbojárov 10, SK-832 32 Bratislava, Slovak Republic; and Toxicological and Antidoping Center, Faculty of Pharmacy, Comenius University in Bratislava, Odbojárov 10, SK-832 32 Bratislava, Slovak Republic, e-mail:

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Received: 2015-3-20
Accepted: 2015-5-27
Published Online: 2015-6-30
Published in Print: 2015-12-1

©2015 by De Gruyter

Heruntergeladen am 24.10.2025 von https://www.degruyterbrill.com/document/doi/10.1515/revic-2015-0004/pdf
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