1-aza-18-crown-6 ether tailored graphene oxide for Cs(I) removal from wastewater
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Peng Liu
and
Fuqiu Ma
Abstract
Due to the relative abundance, long half-life and high mobility of radioactive cesium (Cs), new adsorbents are urgently needed to treat Cs to ensure public health. In this study, a graphene oxide (GO) based adsorbent for Cs(I) adsorption was prepared by 1-aza-18-crown-6 ether modification. XRD, FT-IR, XPS and SEM results showed that the properties of 1-aza-18-crown 6 ether modified GO (18C6-GO) changed dramatically compared with that of raw graphite. The adsorption properties of 18C6-GO for Cs(I) were studied by batch static adsorption experiments. The results showed that the adsorption equilibrium time of 18C6-GO was 20 h. Kinetic study revealed that the adsorption rate of Cs(I) conformed to pseudo-second-order kinetic model. Langmuir adsorption isotherm simulation indicated that the adsorption arises at homogeneous adsorption sites on 18C6-GO. Therefore, crown ether modified GO may have implications for the treatment of wastewater.
Funding source: Yantai Science and technology planning project
Award Identifier / Grant number: 2021MSGY029
Funding source: University and Local Integration Development Project of Yantai
Award Identifier / Grant number: 2020XDRHXMPT36
Funding source: Academic-Industry Partnership Fund
Award Identifier / Grant number: 210F0401006
Funding source: Yantai New Growth Drivers Fund
Award Identifier / Grant number: (YTDNY20220425-02)
Acknowledgments
The authors are grateful for all your support.
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Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
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Research funding: This work was financially supported by the Yantai Science and technology planning project (2021MSGY029), the University and Local Integration Development Project of Yantai (2020XDRHXMPT36), and the Academic-Industry Partnership Fund (210F0401006), the Yantai New Growth Drivers Fund (YTDNY20220425-02).
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Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
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© 2022 Walter de Gruyter GmbH, Berlin/Boston
Articles in the same Issue
- Frontmatter
- Review
- Progress in solid state and coordination chemistry of actinides in China
- Original Papers
- Np(V) dicyanamide complexes with electroneutral N-donor ligands
- Comparison of the performance of solvent wash reagents used for the primary cleanup of degraded PUREX solvent
- 1-aza-18-crown-6 ether tailored graphene oxide for Cs(I) removal from wastewater
- Evaluation of nuclear data analysis techniques for volume fraction prediction in the flow meter
Articles in the same Issue
- Frontmatter
- Review
- Progress in solid state and coordination chemistry of actinides in China
- Original Papers
- Np(V) dicyanamide complexes with electroneutral N-donor ligands
- Comparison of the performance of solvent wash reagents used for the primary cleanup of degraded PUREX solvent
- 1-aza-18-crown-6 ether tailored graphene oxide for Cs(I) removal from wastewater
- Evaluation of nuclear data analysis techniques for volume fraction prediction in the flow meter
