Startseite Sintering Bi2O3–B2O3–ZnO ternary low temperature glass by hydration device to solidify iodine containing silver-coated silica gel
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Sintering Bi2O3–B2O3–ZnO ternary low temperature glass by hydration device to solidify iodine containing silver-coated silica gel

  • Wenhong Han , Guilin Wei , Yi Liu , Xirui Lu EMAIL logo , Shunzhang Chen , Zhentao Zhang , Yi Xie und Xiaoyan Shu EMAIL logo
Veröffentlicht/Copyright: 31. Dezember 2021
Radiochimica Acta
Aus der Zeitschrift Radiochimica Acta Band 110 Heft 3

Abstract

A new glass solidification process aims at radioactive iodine waste was explored in order to reduce the possible harm to environment. Samples with different iodine content in silver-coated silica gel were pretreated by hydration device at 300 °C and then sintered at relatively low temperatures (500, 550 and 600 °C). XRD results show that AgI is mainly chemically fixed in the glass network with some AgI particles being physically wrapped by the glass. Moreover, as the sintering temperature reached to 550 °C, B element crystallized. SEM-EDS results show that Ag and I elements are enriched, while the other elements are evenly distributed. AFM results showed that the sample surface becomes rougher as the iodine content increases in the silver coated silica gel. The FT-IR results show that the structure of the sintered sample is mainly composed of [BiO3], [BiO6] and [BO3]. This study provides a new sintering method by hydration device for the treatment of radioactive iodine waste.

Keywords: hydration device; immobilization; iodine waste; low-temperature sintering
Corresponding author: Xirui Lu, State Key Laboratory of Environmental-friendly Energy Materials, Southwest University of Science and Technology, Mianyang Sichuan 621010, P. R. China; Fundamental Science on Nuclear Wastes and Environmental Safety Laboratory, Southwest University of Science and Technology, Mianyang Sichuan 621010, P. R. China; and National Co-innovation Center for Nuclear Waste Disposal and Environmental Safety, Southwest University of Science and Technology, Mianyang Sichuan 621010, P. R. China, E-mail: ; and Xiaoyan Shu, Fundamental Science on Nuclear Wastes and Environmental Safety Laboratory, Southwest University of Science and Technology, Mianyang Sichuan 621010, P. R. China; and National Co-innovation Center for Nuclear Waste Disposal and Environmental Safety, Southwest University of Science and Technology, Mianyang Sichuan 621010, P. R. China, E-mail:

Funding source: Southwest University of Science and Technology

Award Identifier / Grant number: 20fksy10

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: The authors appreciate the support from the Project of State Key Laboratory of Environment-friendly Energy Materials, Southwest University of Science and Technology (No. 20fksy10).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2021-03-19
Accepted: 2021-12-18
Published Online: 2021-12-31
Published in Print: 2022-03-28

© 2021 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. Original Papers
  3. Sorption behavior of natural uranium from aqueous solutions using modified activated carbon with quinoline
  4. Adsorption of UO2 2+ by AlBaNi-layered double hydroxide nano-particles: kinetic, isothermal, and thermodynamic studies
  5. Behaviour of DGA and Ln resin with alpha radiation dose
  6. Sintering Bi2O3–B2O3–ZnO ternary low temperature glass by hydration device to solidify iodine containing silver-coated silica gel
  7. Enhancement of the thermal and physicochemical properties of styrene butadiene rubber composite foam using nanoparticle fillers and electron beam radiation
  8. Co-transport of bentonite colloid and U(VI) in particulate granite column: role of colloid concentration, ionic strength, pH and flow rate
https://doi.org/10.1515/ract-2021-1032
Schlagwörter für diesen Artikel
hydration device; immobilization; iodine waste; low-temperature sintering

Artikel in diesem Heft

  1. Frontmatter
  2. Original Papers
  3. Sorption behavior of natural uranium from aqueous solutions using modified activated carbon with quinoline
  4. Adsorption of UO2 2+ by AlBaNi-layered double hydroxide nano-particles: kinetic, isothermal, and thermodynamic studies
  5. Behaviour of DGA and Ln resin with alpha radiation dose
  6. Sintering Bi2O3–B2O3–ZnO ternary low temperature glass by hydration device to solidify iodine containing silver-coated silica gel
  7. Enhancement of the thermal and physicochemical properties of styrene butadiene rubber composite foam using nanoparticle fillers and electron beam radiation
  8. Co-transport of bentonite colloid and U(VI) in particulate granite column: role of colloid concentration, ionic strength, pH and flow rate
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