Startseite Comparison of some organic and inorganic ion exchangers concerning the sorption of Ce(III), Te(IV), Zr(IV), Hf(IV) and Nb(V)
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Comparison of some organic and inorganic ion exchangers concerning the sorption of Ce(III), Te(IV), Zr(IV), Hf(IV) and Nb(V)

  • Fatma H. El-Sweify EMAIL logo , Ehab A. A. El-Shazly und Shreen M. Salama
Veröffentlicht/Copyright: 14. November 2017

Abstract

The sorption behaviors of Ce(III), as a representative of trivalent lanthanide ions, and Te(IV), Zr(IV) and Nb(V) as fission products representatives, as well as Hf(IV), from various aqueous media on some synthesized inorganic exchangers, as well as commercially available organic ion exchangers were studied and compared. Organic cation exchanger Dowex-50WX8 and organic anion exchangers AG-1X8 and AG-2X8 were utilized. Synthesized inorganic ion exchangers were zirconium titanium phosphate (ZrTiP) of different Zr:Ti mole ratios and ceric tungstate (CeW). The sorption was carried out from mineral acid solutions as well as EDTA and DTPA solutions. The radioactive isotopes, 95Zr, 95Nb, 123mTe, 141Ce and 181Hf were used to trace the sorption behaviors of the corresponding elements, which were studied in mixtures of them. The differences between the sorption behaviors of the studied metal ionic species on both kinds of ion exchangers were interpreted and discussed in this work.

References

1. Greenwood, N. N., Earnshaws, A.: Chemistry of the Elements (1997), 2nd ed., Pergamon Press, Oxford, London.Suche in Google Scholar

2. Martin, F. S., Miles, G. L.: Chemical Processing of Nuclear Fuels (1958), Butterworths Scientific Publications, London.Suche in Google Scholar

3. Hecht, F.: Grundzüge der Radio-und Reaktorchemie (1968), Akademische Verlagsgesellschaft, Frankfurt am Main.Suche in Google Scholar

4. Busev, A. I., Tiptsova, V. G., Ivanov, V. M.: Analytical Chemistry of Rare Elements (1981), Translated from Russian by Alexander Rosinkin, Mir Publishers, Moscow.Suche in Google Scholar

5. Kandil, S. A., Saleh, Z. A., Farag, R. S., Khalifa, Kh. F.: An improvement of radioiodine separation from tellurium oxide target through the bed depth of ion-exchanger. J. Radioanal. Nucl. Chem. 293(1), 75 (2012).10.1007/s10967-012-1769-zSuche in Google Scholar

6. Mostafa, M., Ramadan, H. E., El-Amir, M. A.: Radiochemical precipitation studies for separation of iodine from tellurium and other trace impurities. J. Radioanal. Nucl. Chem. 295(1), 115 (2013).10.1007/s10967-012-1890-zSuche in Google Scholar

7. Hassan, K. F., Spellerberg, S., Scholten, B., Qaim, S. M., Saleh, Z. A.: Development of an ion-exchange method for separation of radioiodine from tellurium and antimony and its application to the production of 124I via the 121Sb (α, n)-process. J. Radioanal. Nucl. Chem. 302(1), 689 (2014).10.1007/s10967-014-3270-3Suche in Google Scholar

8. Schweitzer, G. K., Pesterfield, L. L.: The Aqueous Chemistry of the Elements (2010), Oxford University Press, New York, USA.10.1093/oso/9780195393354.001.0001Suche in Google Scholar

9. Chakraborty, R., Sen, B., Chattopadhyay, P.: Zirconium-titanium-phosphate nanoparticles. Triton X-100 based size modification, characterization and application in radiochem. separation. Radiochim. Acta. 102(4), 363 (2014).10.1515/ract-2014-2115Suche in Google Scholar

10. Chakraborty, R., Bhattacharaya, K., Chattopadhyay, P.: Nanostructured zirconium phosphate as ion exchanger: Synthesis, size dependent property and analytical application in radiochemical separation. Appl. Radiat. Isot. 85, 34 (2014).10.1016/j.apradiso.2013.10.018Suche in Google Scholar PubMed

11. Patil, P., Pathak Sachin, S., Sharath Babu, M., Kumar, N., Mukerjee, S. K., Pius, I. C.: Sorption studies of plutonium and uranium on zirconium phosphosilicate ion exchanger prepared by gelation route. Proc. of the 7th. DAE-BRNS biennial symposium on emerging trends in separation science and technology; Guwahati (India), 17–20 May, 14 (2016).Suche in Google Scholar

12. Gogoi, D., Singh, P. K., Kumar, T., Shanmugamani, A. G., Rao, S. V. S., Chitra, S., Velmurugan, S.: Synthesis, characterization and removal properties of cerium molybdophosphate (CMP) for cesium removal. Proc. of DAE-BRNS biennial symposium on emerging trends in separation science and technology, Mumbai (India), 25–28 Feb, 40 (2014).Suche in Google Scholar

13. El-Sweify, F. H., Abdel Fattah, A. A., El-Sheikh, R., Aly, S. M., Ghamry, M. A.: Studies on 99Mo–99mTc adsorption and elution behaviors using the inorganic sorbent ceric tungstate and conventional organic resins. Radiochim. Acta. 105, 561 (2017).10.1515/ract-2016-2665Suche in Google Scholar

14. El-Sweify, F. H., Abdel Fattah, A. A., El-Sheikh, R., Aly, S. M., Ghamry, M. A.: Batch and column adsorption behaviors of Se(IV) and Te(IV) on organic and inorganic ion exchangers from HCl solutions. Radiochim. Acta. 105(9), 739 (2017).10.1515/ract-2016-2666Suche in Google Scholar

15. Parangi, T., Chudasama, U., Wani, B.: Synthesis, characterization and application of cerium phosphate as an ion exchanger. Proc. of 4th. DAE-BRNS biennial symposium on emerging trends in separation science and technology; Kalpakkam (India), 1–4 Mar, 207 (2010).Suche in Google Scholar

16. Chen, S., Zhu, C.: Dengbolu: titanium dioxide nanotubes as solid-phase extraction adsorbent for on-line pre-concentration and determination of trace rare earth elements by inductively coupled plasma mass spectrometry. Microchem. J. 110, 89 (2013).10.1016/j.microc.2013.02.010Suche in Google Scholar

17. Fu, Q., Yang, L., Wang, Q.: On line preconcentration with a novel alkyl phosphinic acid extraction resin coupled with inductively coupled plasma mass spectrometry for determination of trace rare earth elements in seawater. Talanta 72, 1248 (2007).10.1016/j.talanta.2007.01.015Suche in Google Scholar PubMed

18. Remenec, B., Dulanska, S., Gardonova, V., Metal, L.: Determination of 94Nb in radioactive waste using ion exchange chromatography. J. Radioanal. Nucl. Chem. 295, 907 (2013).10.1007/s10967-012-2235-7Suche in Google Scholar

19. El-Sweify, F. H., Abdel-Fattah, A. A., Elkhouly, S. H., Aly, S. M.: Solvent extraction and ion exchange studies on the separation of Ce, Nd, Gd, Tm and Zr. Arab J. Nucl. Sci. Appl. 46, 43 (2013).Suche in Google Scholar

20. El-Sweify, F. H., El-Shazly, E. A. A., Salama, Sh. M.: Radiochemical studies on the use of modified resins in the isolation and separation of Ce(III), Zr(IV), Hf(IV), Te(IV) and Nb(V). Arab J. Nucl. Sci. Appl. 40, 97 (2007).Suche in Google Scholar

21. Fedyunina, N. N., Ossipov, K. B., Seregina, I. F., Bolshov, M. A., Statkus, M. A., Tsysin, G. I.: Determination of rare earth elements in rock samples by inductively coupled plasma mass-spectrometry after sorption pre-concentration using POL-DETATA sorbent. Talanta 102, 128 (2012).10.1016/j.talanta.2012.07.026Suche in Google Scholar PubMed

22. Ponou, J., Wang, L. P., Katsunori Okaya, G. D., Fujita, T., Mitsuhashi, K., Okaya, K., Fujita, T., Mitsuhashi, K., Atarashi, T., Satoh, G., Neda, M.: Recovery of rare earth elements from aqueous solution obtained from Vietnamese clay minerals using dried and carbonized parachlorella. J. Environ. Chem. Eng. 2, 1070 (2014).10.1016/j.jece.2014.04.002Suche in Google Scholar

23. Zhao, F., Repo, E., Meng, Y., Wang, X., Yin, D., Sillanpää, M.: An EDTA-β-Cyclodextrin material for the adsorption of rare earth elements and its application in preconcentration of rare earth elements in seawater. J. Colloid. Interface Sci. 465, 215 (2016).10.1016/j.jcis.2015.11.069Suche in Google Scholar PubMed

24. Radchenko, V., Roesch, F., Filosofov, D. V., Bochko, O. K., Lebedev, N. A., Rakhimov, A. V., Aksenov, N. V., Bozhikov, G. A., Ponsard, B.: Separation of 90Nb from zirconium target for application in immuno-PET. Radiochim. Acta. 102(5), 433 (2014).10.1515/ract-2013-2156Suche in Google Scholar

25. Taghizadeh, M., Ghanadi, M., Zolfonoun, E.: Separation of zirconium and hafnium by solvent extraction using mixture of TBP and Cyanex 923. J. Nucl. Materials, 412(3), 334 (2011).10.1016/j.jnucmat.2011.03.033Suche in Google Scholar

26. Das, N. R., Lahiri, S.: Reversed phase chromatographic separation of zirconium, niobium and hafnium tracers with HDEHP. J. Radioanal. Nucl. Chem. 163(2), 213 (1992).10.1007/BF02034795Suche in Google Scholar

27. Maji, S., Lahiri, S., Wierczinski, B., Korschinek, B.: Separation of trace level hafnium from tungsten: a step toward solving an astronomical puzzle. Anal. Chem. 78(7), 2302 (2006).10.1021/ac051120ySuche in Google Scholar PubMed

28. Zhang, L., Chen, E., Yu, X.: Preparation of sol-gel materials doped with ionic liquid and extractant for cerium (III) extraction. J. Radioanal. Nucl. Chem. 298(2), 1055 (2013).10.1007/s10967-013-2560-5Suche in Google Scholar

29. Murakami, M., Tsuto, S., Ooe, K., Goto, S., Kudo, H., Haba, H., Kanaya, J.: Extraction of Nb and Ta in HF solutions with tributyl phosphate. Proc. of 5th. Asia-Pacific symposium on radiochemistry; Kanazawa, Ishikawa (Japan), 22–27 Sep. 231 (2013).Suche in Google Scholar

30. Jiang, T., He, Y.-H., Yang, J., Du, W.-X., Yang, T. L.: A study of separation method of 178m2Hf from irradiated ytterbium targets. J. Radioanal. Nucl. Chem. 296(2), 1105 (2013).10.1007/s10967-012-2155-6Suche in Google Scholar

31. Tabdon, S. M., Gill, G. S.: Synthesis and ion-exchange properties of ceric-tungstate. Talanta 20, 585 (1973).10.1016/0039-9140(73)80138-9Suche in Google Scholar PubMed

32. Marei, S. A., Shakshooki, S. K.: Preparation of a new inorganic ion exchanger: zirconium-titanium phosphate/ZTP/. Radiochim. Radioanal. Lett. 4, 187 (1972).Suche in Google Scholar

33. Colthup, N. B., Daly, L. H., Stephen, E. W.: Introduction to Infrared and Raman Spectroscopy. Academic Press International Edition, London (1965).Suche in Google Scholar

34. Gladsden, J. A.: Infrared Spectra of Minerals and Related Inorganic Compounds (1965), Butterworths, London.Suche in Google Scholar

35. Qureshi, M., Varshney, K. G.: Inorganic Ion Exchangers in Chemical Analysis (1991), CRC Press, Boca Raton, USA.Suche in Google Scholar

36. Reichenberg, D.: Selectivity of ion exchange. In: J. A. Marinsky, Y. Marcus (Eds.), Ion exchange, a series of advances, vol. I (1965), Dekker, M. Inc., New York, p. 227.Suche in Google Scholar

37. Korkish, J.: Modern Methods of the Separation of Rarer Metal Ions (1969), Pergamon Press, Oxford, London, New York.Suche in Google Scholar

38. El-Sweify, F. H.: Sorption and separation of some elements of nuclear importance using Chelex-100. J. Radioanal. Nucl. Chem. 222, 65 (1997).10.1007/BF02034247Suche in Google Scholar

39. Cotton, F. A., Geoffery, W. F. R. S.: Advanced Inorganic Chemistry (1999), 6th ed., John Wiley & Sons, Inc., New York, London, p. 441.Suche in Google Scholar

40. Kotrly, S., Šucha, L.: Handbook of Chemical Equilibria in Analytical Chemistry (1985), 1st ed., John Wiley & Sons, New York, USA.Suche in Google Scholar

Received: 2017-3-12
Accepted: 2017-9-13
Published Online: 2017-11-14
Published in Print: 2018-3-28

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