Abstract
Radiationless resonance electronic excitation energy transfer (ET) is a fundamental physical phenomenon in luminescence spectroscopy playing an important role in natural processes, especially in photosynthesis and biochemistry. Besides, it is widely used in photooptics, optoelectronics, and protein chemistry, coordination chemistry of transition metals and lanthanides as well as in luminescent analysis. ET involves the transfer of electronic energy from a donor (D) (molecules or particles) which is initially excited, to an acceptor (A) at the ground state to emit it later. Fluorescence or phosphorescence of the acceptor that occurs during ET is known as sensitized. There do many kinds of ET exist but in all cases along with other factors the rate and efficiency of ET in common solvents depends to a large extent on the distance between the donor and the acceptor. This dependency greatly limits the efficiency of ET and, correspondingly, does not allow the determination of analytes in highly diluted (10–9–10–15 M) solutions. To solve the problem of distance-effect, the effects of concentrating and bring close together the donor and acceptor in surfactant micelles (liquid nanosystems) or sorption on solid nanoparticles are used. Various approaches to promote the efficiency of ET for improvement determination selectivity and sensitivity using liquid and solid nanoobjects is reviewed and analyzed.
Acknowledgements
The work was supported by Russian Foundation for Basic Research, project No. 18-03-01029a
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Articles in the same Issue
- Characterisation of battery materials by electron and ion microscopy techniques: a review
- Hydrogenation of nitriles and imines for hydrogen storage
- Coupling photoredox and biomimetic catalysis for the visible-light-driven oxygenation of organic compounds
- Energy transfer in liquid and solid nanoobjects: application in luminescent analysis
- An introductory course in green chemistry: Progress and lessons learned
- Molecular structure and vibrational spectra of 2-(4-bromophenyl)-3-(4-hydroxyphenyl) 1,3-thiazolidin-4-one and its selenium analogue: Insights using HF and DFT methods
- Applied battery diagnosis
- Inorganic mass spectrometry
- Safer electrolyte components for rechargeable batteries
Articles in the same Issue
- Characterisation of battery materials by electron and ion microscopy techniques: a review
- Hydrogenation of nitriles and imines for hydrogen storage
- Coupling photoredox and biomimetic catalysis for the visible-light-driven oxygenation of organic compounds
- Energy transfer in liquid and solid nanoobjects: application in luminescent analysis
- An introductory course in green chemistry: Progress and lessons learned
- Molecular structure and vibrational spectra of 2-(4-bromophenyl)-3-(4-hydroxyphenyl) 1,3-thiazolidin-4-one and its selenium analogue: Insights using HF and DFT methods
- Applied battery diagnosis
- Inorganic mass spectrometry
- Safer electrolyte components for rechargeable batteries