Abstract
The reactivity of the chalcogen–nitrogen bond toward main-group element or transition-metal halides, as well as electrophilic and nucleophilic reagents, is the source of a variety of applications of Se–N and Te–N compounds in both inorganic or organic chemistry. The thermal lability of Se–N compounds also engenders useful transformations including the formation of radicals via homolytic Se–N bond cleavage. These aspects of Se–N and Te–N chemistry will be illustrated with examples from the reactions of the binary selenium nitride Se4N4, selenium–nitrogen halides [N(SeCln)2]+ (n = 1, 2), the synthons E(NSO)2 (E = Se, Te), chalcogen–nitrogen–silicon reagents, chalcogen(IV) diimides RN=E=NR, the triimidotellurite dianion [Te(NtBu)3]2−, chalcogen(II) amides and diamides E(NR2)2 (E = Se, Te; R = alkyl, SiMe3), and heterocyclic systems.
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Articles in the same Issue
- Multi technique and multiscale approaches to the study of ancient and modern art objects on wooden and canvas support
- Characterization of proteins in cultural heritage using MALDI–TOF and LC–MS/MS mass spectrometric techniques
- Organophosphorus-selenium/tellurium reagents: from synthesis to applications
- Selenium– and tellurium–nitrogen reagents
- Applications of metal selenium/tellurium compounds in materials science
- Organoselenium and organotellurium compounds containing chalcogen-oxygen bonds in organic synthesis or related processes
- Templated enantioselective photocatalysis
- Liquid chromatography: Current applications in Heritage Science and recent developments
- Chemical space of naturally occurring compounds
Articles in the same Issue
- Multi technique and multiscale approaches to the study of ancient and modern art objects on wooden and canvas support
- Characterization of proteins in cultural heritage using MALDI–TOF and LC–MS/MS mass spectrometric techniques
- Organophosphorus-selenium/tellurium reagents: from synthesis to applications
- Selenium– and tellurium–nitrogen reagents
- Applications of metal selenium/tellurium compounds in materials science
- Organoselenium and organotellurium compounds containing chalcogen-oxygen bonds in organic synthesis or related processes
- Templated enantioselective photocatalysis
- Liquid chromatography: Current applications in Heritage Science and recent developments
- Chemical space of naturally occurring compounds