Home Physical Sciences Structural characters of biaxially stretched polypropylene films and the relevant electrical insulating properties
Article
Licensed
Unlicensed Requires Authentication

Structural characters of biaxially stretched polypropylene films and the relevant electrical insulating properties

  • Sixue Zeng , Quan Li , Huixuan Liu , Jinqing Wang and Ke Wang EMAIL logo
Published/Copyright: May 19, 2023
Become an author with De Gruyter Brill

Abstract

Capacitor films from biaxially oriented polypropylene (BOPP) involve intensive external stress field, resulting in special crystallization and orientation characters. However, it still remains ambiguous on the relationship between crystallized morphology in BOPP bulk film and electric properties. In this work, two stretching modes, simultaneously biaxial stretching and sequentially biaxial stretching, were chosen to adjust film thickness, extended chain crystal content, fibrillar morphology, and orientation texture. Meanwhile, the working rules of these structural issues on electrical insulating properties were inspected. It reveals that extended chain crystals with thermal stability and isotropous fibrillated network favor to improved breakdown strength and lowered dielectric loss. These results offer good understanding on the processing-structure-property relation of polymer film dielectrics.


Corresponding author: Ke Wang, College of Polymer Science and Engineering, Sichuan University, Chengdu 610065, P.R. China, E-mail:

Funding source: Ke Wang

Award Identifier / Grant number: No. 51973139

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: Financial support from the National Natural Science Foundation of China (NSFC) by grant no. 51973139 is gratefully appreciated.

  3. Conflict of interest statement: The authors declare that they have no conflicts of interest regarding this article.

References

1. Chen, Q., Shen, Y., Zhang, S., Zhang, Q. M. Polymer-based dielectrics with high energy storage density. Ann. Rev. Mater. Res. 2015, 45, 433–458; https://doi.org/10.1146/annurev-matsci-070214-021017.Search in Google Scholar

2. Prateek, Thakur, V. K., Gupta, R. K. Recent progress on ferroelectric polymer-based nanocomposites for high energy density capacitors: synthesis, dielectric properties, and future aspects. Chem. Rev. 2016, 116, 4260–4317; https://doi.org/10.1021/acs.chemrev.5b00495.Search in Google Scholar PubMed

3. Ritamaki, M., Rytoluoto, I., Lahti, K. Performance metrics for a modern BOPP capacitor film. IEEE Trans. Dielectr. Electr. Insul. 2019, 26, 1229–1237; https://doi.org/10.1109/tdei.2019.007970.Search in Google Scholar

4. Huan, T. D., Boggs, S., Teyssedre, G., Laurent, C., Cakmak, M., Kumar, S., Ramprasad, R. Advanced polymeric dielectrics for high energy density applications. Prog. Mater. Sci. 2016, 83, 236–269; https://doi.org/10.1016/j.pmatsci.2016.05.001.Search in Google Scholar

5. Ritamaki, M., Rytoluoto, I., Lahti, K., Vestberg, T., Pasanen, S., Flyktman, T. Large-area approach to evaluate DC electro-thermal ageing behavior of BOPP thin films for capacitor insulation systems. IEEE Trans. Dielectr. Electr. Insul. 2017, 24, 826–836; https://doi.org/10.1109/tdei.2017.006405.Search in Google Scholar

6. Li, H., Li, H., Li, Z., Lin, F., Wang, W., Wang, B., Huang, X., Guo, X. Temperature dependence of self-healing characteristics of metallized polypropylene film. Microelectron. Reliab. 2015, 55, 2721–2726; https://doi.org/10.1016/j.microrel.2015.09.007.Search in Google Scholar

7. Zhang, M., Li, B., Wang, J. J., Huang, H. B., Zhang, L., Chen, L. Q. Polymer dielectrics with simultaneous ultrahigh energy density and low loss. Adv. Mater. 2021, 33, 2008198; https://doi.org/10.1002/adma.202008198.Search in Google Scholar PubMed

8. Umemura, T., Suzuki, T., Kashiwazaki, T. Impurity effect of the dielectric properties of isotactic polypropylene. IEEE Trans. Electr. Insul. 1982, 17, 300–305; https://doi.org/10.1109/tei.1982.298498.Search in Google Scholar

9. Ho, J., Ramprasad, R., Boggs, S. Effect of alteration of antioxidant by UV treatment on the dielectric strength of BOPP capacitor film. IEEE Trans. Dielectr. Electr. Insul. 2007, 14, 1295–1301; https://doi.org/10.1109/tdei.2007.4339492.Search in Google Scholar

10. Lin, Y. J., Dias, P., Chum, S., Hiltner, A., Baer, E. Surface roughness and light transmission of biaxially oriented polypropylene films. Polym. Eng. Sci. 2007, 47, 1658–1665; https://doi.org/10.1002/pen.20850.Search in Google Scholar

11. Kahouli, A., Gallot-Lavallée, O., Rain, P., Lesaint, O., Heux, L., Guillermin, C., Lupin, J. M. Structure effect of thin film polypropylene view by dielectric spectroscopy and X-ray diffraction: application to dry type power capacitors. J. Appl. Polym. Sci. 2015, 132, 42602; https://doi.org/10.1002/app.42602.Search in Google Scholar

12. Zhang, M., Li, D., Xu, W., Chang, H., Liu, Q., Fu, Y., Liao, R., Shi, J., Wang, Y., He, X. Crystalline structure and morphology of biaxially oriented polypropylene film under the coexistence of organic silica particles and its influence on the adsorption diffusion of polar solvent molecules. Packag. Technol. Sci. 2019, 32, 75–84; https://doi.org/10.1002/pts.2417.Search in Google Scholar

13. Nie, H. -Y., Walzak, M., McIntyre, N. Draw-ratio-dependent morphology of biaxially oriented polypropylene films as determined by atomic force microscopy. Polymer 2000, 41, 2213–2218; https://doi.org/10.1016/s0032-3861(99)00397-3.Search in Google Scholar

14. Tabatabaei, S. H., Carreau, P. J., Ajji, A. Effect of processing on the crystalline orientation, morphology, and mechanical properties of polypropylene cast films and microporous membrane formation. Polymer 2009, 50, 4228–4240; https://doi.org/10.1016/j.polymer.2009.06.071.Search in Google Scholar

15. Yoshida, S., Sawada, T., Kawamura, T., Nitta, K. Molecular orientation behavior of isotactic polypropylene films under uniaxial and biaxial deformation at elevated temperatures. Int. Polym. Process. 2012, 27, 237–244; https://doi.org/10.3139/217.2527.Search in Google Scholar

16. Rytöluoto, I., Gitsas, A., Pasanen, S., Lahti, K. Effect of film structure and morphology on the dielectric breakdown characteristics of cast and biaxially oriented polypropylene films. Eur. Polym. J. 2017, 95, 606–624; https://doi.org/10.1016/j.eurpolymj.2017.08.051.Search in Google Scholar

17. Jones, J., Llewellyn, J., Lewis, T. The contribution of field-induced morphological change to the electrical aging and breakdown of polyethylene. IEEE Trans. Dielectr. Electr. Insul. 2005, 12, 951–966; https://doi.org/10.1109/tdei.2005.1522189.Search in Google Scholar

18. Chen, X., Lv, F., Su, F., Ji, Y., Meng, L., Wan, C., Lin, Y., Li, X., Li, L. Deformation mechanism of iPP under uniaxial stretching over a wide temperature range: an in-situ synchrotron radiation SAXS/WAXS study. Polymer 2017, 118, 12–21; https://doi.org/10.1016/j.polymer.2017.04.054.Search in Google Scholar

19. Nitta, K. H., Sawada, T., Yoshida, S., Kawamura, T. Three dimensional molecular orientation of isotactic polypropylene films under biaxial deformation at higher temperatures. Polymer 2015, 74, 30–37; https://doi.org/10.1016/j.polymer.2015.07.049.Search in Google Scholar

20. Kahouli, A., Gallot-Lavallée, O., Rain, P., Lesaint, O., Guillermin, C., Lupin, J. M. Dielectric features of two grades of bi-oriented isotactic polypropylene. J. Appl. Polym. Sci. 2015, 132, 42224; https://doi.org/10.1002/app.42224.Search in Google Scholar

21. Gao, L., Tu, D., Zhou, S., Zhang, Z. The influence of morphology on the electrical breakdown strength of polypropylene film. IEEE Trans. Electr. Insul. 1990, 25, 535–540; https://doi.org/10.1109/14.55728.Search in Google Scholar

22. Xiong, J., Wang, X., Zhang, X., Xie, Y., Lu, J., Zhang, Z. How the biaxially stretching mode influence dielectric and energy storage properties of polypropylene films. J. Appl. Polym. Sci. 2020, 138, 50029; https://doi.org/10.1002/app.50029.Search in Google Scholar

23. Capt, L., Rettenberger, S., Münstedt, H., Kamal, M. R. Simultaneous biaxial deformation behavior of isotactic polypropylene films. Polym. Eng. Sci. 2003, 43, 1428–1441; https://doi.org/10.1002/pen.10121.Search in Google Scholar

24. Lüpke, T., Dunger, S., Sänze, J., Radusch, H. J. Sequential biaxial drawing of polypropylene films. Polymer 2004, 45, 6861–6872; https://doi.org/10.1016/j.polymer.2004.07.075.Search in Google Scholar

25. Chen, Q., Wang, Z., Zhang, S., Cao, Y., Chen, J. Structure evolution and deformation behavior of polyethylene film during biaxial stretching. ACS Omega 2020, 5, 655–666; https://doi.org/10.1021/acsomega.9b03250.Search in Google Scholar PubMed PubMed Central

26. Parthasarthy, G., Sevegney, M., Kannan, R. M. Rheooptical Fourier transform infrared spectroscopy of the deformation behavior in quenched and slow-cooled isotactic polypropylene films. J. Polym. Sci. Part B: Polym. Phys. 2002, 40, 2539–2551; https://doi.org/10.1002/polb.10304.Search in Google Scholar

Received: 2023-03-08
Accepted: 2023-05-04
Published Online: 2023-05-19
Published in Print: 2023-07-26

© 2023 Walter de Gruyter GmbH, Berlin/Boston

Downloaded on 7.3.2026 from https://www.degruyterbrill.com/document/doi/10.1515/polyeng-2023-0058/html
Scroll to top button