A waterborne uniform graphene oxide-epoxy complex with enhanced anticorrosive properties enabled by intercalation polymerization
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Jingyi Li
,
Ke Zhu
Abstract
Dispersion of graphene in water-based epoxy resins has always been a challenge. In this work, the stable and uniform graphene oxide modified emulsifying epoxy resin curing agents (WPA@GOs) were firstly prepared by intercalation polymerization. Subsequently, WPA@GO was used to emulsify E44 to obtain WPA@GO/E44 nano-emulsions. Compared to WPA/E44 and WPA-GO/E44, the water resistance, tensile strength, and anticorrosive properties of WPA@GO/E44 were significantly increased. The corrosion density of WPA@GO2/E44 coating decreased by 5 times and polarization impedance increased by 10 times in comparison to WPA/E44 coating.
Funding source: National Natural Science Foundation of China
Award Identifier / Grant number: 5160030644
Funding source: Natural Science Foundation of Shaanxi Province
Award Identifier / Grant number: No. 2020JQ-899
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Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
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Research funding: The authors express sincere thanks to the Natural Science Basic Research Plan Project Specification of Shaanxi Province (no. 2020JQ-899), Natural Science Foundation of China (5160030644), Natural Science Talent Program of Weinan Normal University (18ZRRC02), and support by Education Department of Shaanxi Province Special Science Research Program (grant no. 21JK0626).
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Conflict of interest statement: The authors declare that they have no conflicts of interest regarding this article.
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Data availability: All data generated or analysed during this study are included in this published article (and its Supplementary Material).
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Supplementary Material
This article contains supplementary material (https://doi.org/10.1515/polyeng-2022-0295).
© 2023 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Frontmatter
- Material Properties
- Modification of natural pigskin collagen via cryogrinding: a focused study on its physiochemical properties
- Effects of nano-silica on the crystallization, structure, and mechanical properties of crosslinked ethylene-octene copolymer/nano-silica composites
- Preparation and Assembly
- Microencapsulation of polymeric phase change materials (MPCM) for thermal energy storage in industrial coating applications
- A waterborne uniform graphene oxide-epoxy complex with enhanced anticorrosive properties enabled by intercalation polymerization
- Engineering and Processing
- Development of a methodical approach to set-up the injection velocity profile dependent on the part geometry
- Development of variotherm extrusion blow molding technology to produce high-gloss automotive spoilers
- Fabrication, property characterization, and benefit analysis of mixing mechanism of nitrogen and melt, and its comparison of the porous-foam polypropylene injection molding parts
Artikel in diesem Heft
- Frontmatter
- Material Properties
- Modification of natural pigskin collagen via cryogrinding: a focused study on its physiochemical properties
- Effects of nano-silica on the crystallization, structure, and mechanical properties of crosslinked ethylene-octene copolymer/nano-silica composites
- Preparation and Assembly
- Microencapsulation of polymeric phase change materials (MPCM) for thermal energy storage in industrial coating applications
- A waterborne uniform graphene oxide-epoxy complex with enhanced anticorrosive properties enabled by intercalation polymerization
- Engineering and Processing
- Development of a methodical approach to set-up the injection velocity profile dependent on the part geometry
- Development of variotherm extrusion blow molding technology to produce high-gloss automotive spoilers
- Fabrication, property characterization, and benefit analysis of mixing mechanism of nitrogen and melt, and its comparison of the porous-foam polypropylene injection molding parts
