Startseite Studies on the effects of 4,4′-dihydroxyphenyl on crystallization and melting behavior of poly (butylene terephthalate)
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Studies on the effects of 4,4′-dihydroxyphenyl on crystallization and melting behavior of poly (butylene terephthalate)

  • Zhiyuan Shen , Faliang Luo EMAIL logo , Jianghua Du , Xiaomei Lei und Lijie Ji
Veröffentlicht/Copyright: 20. Januar 2017
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Abstract

The blends of poly (butylene terephthalate) (PBT) and 4,4′-dihydroxyphenyl (DHP) were prepared by melt blending, and the effects of DHP on the crystallization and melting behaviors of PBT were investigated by differential scanning calorimetry (DSC), wide-angle X-ray diffraction (WAXD), and polarized optical microscopy (POM). The results showed that crystallization temperature and crystallinity of PBT apparently decreased with the addition of DHP. A remarkably decline in crystallization rate of PBT was achieved, and the blends had higher σe and q values than that of pure PBT as analyzed based on the Avrami equation and Lauritzen-Hoffman equation. The crystal structure of PBT did not change by the addition of DHP, while the spherulite size of PBT decreased.

Award Identifier / Grant number: 21264012

Funding statement: We gratefully acknowledge the financial support from the National Natural Science Foundation of China (no. 21264012).

Acknowledgments

We gratefully acknowledge the financial support from the National Natural Science Foundation of China (no. 21264012).

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Received: 2016-6-11
Accepted: 2016-12-5
Published Online: 2017-1-20
Published in Print: 2017-10-26

©2017 Walter de Gruyter GmbH, Berlin/Boston

Heruntergeladen am 3.12.2025 von https://www.degruyterbrill.com/document/doi/10.1515/polyeng-2016-0206/pdf?lang=de
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