Preparation and application of fluorinated-siloxane protective surface coating material for stone inscriptions
-
Pengling Li
,
Xiaoying Zhang
Abstract
A series of fluorinated-siloxane protective surface coating materials (FPA/SiO2) were prepared with different contents of dodecafluoroheptyl methacrylate (DFMA) and fixed content of siloxane. The properties of FPA/SiO2 protective materials were investigated by the methods of Fourier transform infrared spectroscopy (FT-IR) spectra, UV-Vis spectrum, transmission electron microscopy (TEM) and thermogravimetric analysis (TGA). The surface morphology and mineralogical analysis of the fresh and weathered stone samples were characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD), respectively. The artificial ageing test, which was commonly used as a criterion for the evaluation of the protective ability of FPA/SiO2 coating material, was performed. The results indicate that when the content of DFMA is 30 wt.% and the content of SiO2 is 10 wt.%, the prepared coating material has good comprehensive performances. The artificial ageing test shows that the protective surface coating material has good compatibility with and similar appearance to stone relics. The effect of FPA/SiO2 protective coating material for protection of Jiaoshan Steles Grove (China) is noticeable and it can be widely applied to the protection of stone relics.
Acknowledgments
This project was supported by the Society Development Fund of Zhenjiang (SH2013020), Project of Science and Technology of Suzhou (SG201338) and the Innovation Program for Graduate Education of Jiangsu Province (SJLX_0477).
References
[1] Liu Q, Liu YJ, Zeng KW, Yang FL, Zhu H, Liu QJ. J. Archaeol. Sci. 2011, 38, 1896–1900.10.1016/j.jas.2011.03.036Search in Google Scholar
[2] Liu RZ, Zhang BJ, Zhang H, Shi MF. J. Cult. Herit. 2011, 12, 494–499.10.1016/j.culher.2011.03.008Search in Google Scholar
[3] Zhao J, Li WD, Luo HJ, Miao JM. J. Cult. Herit. 2010, 11, 279–287.10.1016/j.culher.2009.05.004Search in Google Scholar
[4] Zhang H, Shi MF, Shen W, Li ZG, Zhang BJ, Liu RZ, Zhang RP. J. Archaeol. Sci. 2013, 40, 935–942.10.1016/j.jas.2012.09.031Search in Google Scholar
[5] Kim EK, Won J, Do JY, Kim SD, Kang YS. J. Cult. Herit. 2009, 10, 214–221.10.1016/j.culher.2008.07.008Search in Google Scholar
[6] Zhao FC, Zeng XR, Li HQ, Zhang J. Colloid. Surf. A 2012, 396, 328–335.10.1016/j.colsurfa.2012.01.017Search in Google Scholar
[7] Zhang YF, Zhang R, Yang CL, Ju X, Zheng J, Lu MG. Colloid. Surf. A 2013, 436, 549–556.10.1016/j.colsurfa.2013.07.028Search in Google Scholar
[8] Tsakalof A, Manoudis P, Karapanagiotis I, Chryssoulakis I, Panayiotou C. J. Cult. Herit. 2007, 8, 69–72.10.1016/j.culher.2006.06.007Search in Google Scholar
[9] Huang YW, Liu WQ, Zhou XS. J. Appl. Polym. Sci. 2012, 125, E282–E291.10.1002/app.36917Search in Google Scholar
[10] Maravelaki-Kalaitzaki P, Kallithrakas-Kontos N, Korakaki D, Agioutantis Z, Maurigiannakis S. Prog. Org. Coat. 2006, 57, 140–148.10.1016/j.porgcoat.2006.08.007Search in Google Scholar
[11] Zhang H, Liu Q, Liu T, Zhang BJ. Prog. Org. Coat. 2013, 76, 1127–1134.10.1016/j.porgcoat.2013.03.018Search in Google Scholar
[12] Maravelaki-Kalaitzaki P, Kallithrakas-Kontos N, Agioutantis Z, Maurigiannakis S, Korakaki D. Prog. Org. Coat. 2008, 62, 49–60.10.1016/j.porgcoat.2007.09.020Search in Google Scholar
[13] Licchelli M, Malagodi M, Weththimuni ML, Zanchi C. Prog. Org. Coat. 2013, 76, 495–503.10.1016/j.porgcoat.2012.11.005Search in Google Scholar
[14] Wang YY, Qiu FX, Xu BB, Xu JC, Jiang Y, Yang DY, Li PL. Prog. Org. Coat. 2013, 6, 876–883.10.1016/j.porgcoat.2013.02.003Search in Google Scholar
[15] Qian SW, Wu WI, Wang HF, Liu CL, Zhang XE. Rare Metal Mater. Eng. 2008, 37, 24–27.10.1016/S1001-0521(08)60123-0Search in Google Scholar
[16] Liu BL, Zhang BT, Cao SS, Deng XB, Hou XH, Chen HL. Prog. Org. Coat. 2008, 61, 21–27.10.1016/j.porgcoat.2007.08.008Search in Google Scholar
[17] Guo TY, Xi C, Hao GJ, Song MD, Zhang BH. Adv. Polym. Technol. 2005, 24, 288–295.10.1002/adv.20051Search in Google Scholar
[18] Su T, Wang GY, Wang SL, Hu CP. Eur. Polym. J. 2010, 46, 472–483.10.1016/j.eurpolymj.2009.12.009Search in Google Scholar
[19] Hashemi-Nasab R, Mirabedini SM. Prog. Org. Coat. 2013, 76, 1016–1023.10.1016/j.porgcoat.2013.02.016Search in Google Scholar
[20] Xu W, An QF, Hao LF, Zhang D, Zhang M. Appl. Surf. Sci. 2013, 268, 373–380.10.1016/j.apsusc.2012.12.104Search in Google Scholar
[21] Allahverdi A, Ehsani M, Janpour H, Ahmadi S. Prog. Org. Coat. 2012, 75, 543–548.10.1016/j.porgcoat.2012.05.013Search in Google Scholar
[22] Isin D, Kayaman-Apohan N, Gungor A. Prog. Org. Coat. 2009, 65, 477–483.10.1016/j.porgcoat.2009.04.007Search in Google Scholar
[23] Giavarini C, Santarelli ML, Natalini R, Freddi F. J. Cult. Herit. 2008, 9, 14–22.10.1016/j.culher.2007.12.001Search in Google Scholar
©2015 by De Gruyter
Articles in the same Issue
- Frontmatter
- Original articles
- Preparation and application of fluorinated-siloxane protective surface coating material for stone inscriptions
- The effect of the preparation process on the swelling behavior of silk fibroin-polyurethane composite hydrogels using a full factorial experimental design
- Synthesis of cashew Mannich polyol via a three step continuous route and development of PU rigid foams with mechanical, thermal and fire studies
- Effect of chemical treatment on the mechanical and water absorption properties of bagasse fiber-reinforced epoxy composites
- Environmentally degradable sago starch filled low-density polyethylene
- The effect of hybrid nanoparticle with silica sol as the supporter on the crystallization behavior and mechanical properties of isotactic polypropylene
- Towards novel wound dressings: antibacterial properties of zinc oxide nanoparticles and electrospun fiber mats of zinc oxide nanoparticle/poly(vinyl alcohol) hybrids
- Nanofiber formation in the presence of an external magnetic field in electrospinning
- Preparation and characterization emulsion of PANI-TiO2 nanocomposite and its application as anticorrosive coating
- The effect of the geometry of extrusion head flow channels on the adiabatic extrusion of low density polyethylene
Articles in the same Issue
- Frontmatter
- Original articles
- Preparation and application of fluorinated-siloxane protective surface coating material for stone inscriptions
- The effect of the preparation process on the swelling behavior of silk fibroin-polyurethane composite hydrogels using a full factorial experimental design
- Synthesis of cashew Mannich polyol via a three step continuous route and development of PU rigid foams with mechanical, thermal and fire studies
- Effect of chemical treatment on the mechanical and water absorption properties of bagasse fiber-reinforced epoxy composites
- Environmentally degradable sago starch filled low-density polyethylene
- The effect of hybrid nanoparticle with silica sol as the supporter on the crystallization behavior and mechanical properties of isotactic polypropylene
- Towards novel wound dressings: antibacterial properties of zinc oxide nanoparticles and electrospun fiber mats of zinc oxide nanoparticle/poly(vinyl alcohol) hybrids
- Nanofiber formation in the presence of an external magnetic field in electrospinning
- Preparation and characterization emulsion of PANI-TiO2 nanocomposite and its application as anticorrosive coating
- The effect of the geometry of extrusion head flow channels on the adiabatic extrusion of low density polyethylene
