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Facile synthesis of new thermally stable and organo-soluble polyamide-imides from phosphorus-containing aromatic amines and various dianhydrides

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Published/Copyright: August 3, 2013
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Journal of Polymer Engineering
From the journal Journal of Polymer Engineering Volume 33 Issue 6

Abstract

Imide ring containing novel polyamide-imides (PAIs) were prepared by triphenyl phosphite-activated polycondensation of phosphorus-containing aromatic amines, bis(3-aminophenyl) isopropyl phosphine (BAP) and bis(3-aminophenyl) aminotolyl phosphine (TAP), with various diimide-diacids (DIDAS). All polymers were fully characterized by FTIR, 1H-NMR, 13C-NMR, 31P-NMR spectroscopy and elemental analysis. These polymers showed no significant weight loss below 419°C and glass transition temperatures (Tg) in the region of 231°C–290°C. The resulting polymeric films exhibited high optical transparency. The inherent viscosity of the synthesized polymers was in the range 0.55–0.85 dl/g and wide angle X-ray diffraction measurements revealed that these polymers were predominantly amorphous.

Keywords: film transparency; glass transition temperature; pendent phosphorus; polyamide-imides; thermal stability
Corresponding author: Anudeep Kumar Narula, GGS Indraprastha University, Sector-16C Dwarka, Delhi 110078, India

The author (S. Agrawal) wishes to express gratitude to Guru Gobind Singh Indraprastha University, New Delhi, for providing financial support in the form of IPRF.

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Received: 2013-4-18
Accepted: 2013-6-29
Published Online: 2013-08-03
Published in Print: 2013-09-01

©2013 by Walter de Gruyter Berlin Boston

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https://doi.org/10.1515/polyeng-2013-0100
Keywords for this article
film transparency; glass transition temperature; pendent phosphorus; polyamide-imides; thermal stability

Articles in the same Issue

  1. Masthead
  2. Masthead
  3. Original articles
  4. Heat distortion temperature of PPS/PC blend, PPS/PC nanocomposite and PPS/PC/GF hybrid nanocomposite
  5. Mechanical and thermal properties of impact modified PBT blends and impact modified PBT nanocomposites
  6. Twin screw extrusion with Expancel foaming agent
  7. Facile synthesis of new thermally stable and organo-soluble polyamide-imides from phosphorus-containing aromatic amines and various dianhydrides
  8. Graft copolymerization of poly(vinyl acetate) onto starch using KMnO4-H2SO4 redox system
  9. Synthesis and properties of polysiloxane graft waterborne polyurethane modified with α-N,N-dihydroxyethylaminopropyl-ω-butylpolydimethylsiloxane
  10. Thermal, mechanical and tribological properties of polycarbonate/acrylonitrile-butadiene-styrene blends
  11. Thermal conductivity and electrical conductivity of silicone rubber filled with aluminum nitride and aluminum powder
  12. Individual and combined effects of modified starch, bentonite and their composite powder with HPMC on the performance of cement mortars
  13. Optical characteristics of injection-molded fluorene polymers
  14. Novel epoxy resin composites containing polyaniline coated short kenaf bast fibers and polyaniline nanowires: mechanical and electrical properties
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