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Production of nano silver and nano silica coated paper to be used in active packaging

  • Dogan Tutak ORCID logo EMAIL logo
Published/Copyright: April 29, 2025
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Abstract

The use of active packaging is increasing to reduce and prevent the risks of bacterial and viral infections. Recently, studies on this subject have attracted much attention. Especially how Ag nanoparticles enable the easy destruction of many microorganisms. This feature increases the use of silver nanoparticles in active packaging. Moreover, silica nanoparticles can be used in coatings to give different properties to the paper surface. This study aims to use it in active packaging by creating a paper surface coating. In the study, coatings were prepared using silver and silica nanoparticles. The coatings were applied on base paper. The antibacterial activity of coated papers against Staphylococcus aureus (S.aureus) and Escherichia coli (E.coli) was measured by the agar diffusion method. Water absorbency tests (surface contact angle, liquid absorption behavior and surface energy) were measured and analyzed using pendant drop analysis with FTA200 device. Magenta ink was printed on the coated papers with the IGT-C1 test printer, and the CIE L*a*b* color values of the base paper surface, coatings and prints were measured and printability analysis was performed according to ΔE color differences. Simultaneously, the brightness of coated papers (75°) and prints (60°) were measured with BYK Gardner micro glossmeter. As a result, it was determined that especially AgNP’s and AgNP’s + Silica NP’s coated papers showed antibacterial properties and the printing parameters were close to standard values.


Corresponding author: Dogan Tutak, Faculty of Applied Sciences, Department of Printing Technologies, Marmara University, Goztepe, Istanbul, 34722, Türkiye; E-mail:

  1. Research ethics: Not applicable.

  2. Informed consent: Not applicable.

  3. Author contributions: The author have accepted responsibility for the entire content of this manuscript and approved its submission.

  4. Use of Large Language Models, AI and Machine Learning Tools: None declared.

  5. Conflict of interest: The author state no conflict of interest.

  6. Research funding: None declared.

  7. Data availability: The raw data can be obtained on request from the corresponding author.

References

Abushammala, H., Masood, M.A., Ghulam, S.T., and Mao, J. (2023). On the conversion of paper waste and rejects into high-value materials and energy. Sustainability 15: 6915, https://doi.org/10.3390/su15086915.Search in Google Scholar

Adibi, A., Trinh, B.M., and Mekonnen, T.H. (2023). Recent progress in sustainable barrier paper coating for food packaging applications. Prog. Org. Coat. 181: 107566, https://doi.org/10.1016/j.porgcoat.2023.107566.Search in Google Scholar

Altay, B.N., Ma, R., Fleming, P.D., Joyce, M.J., Anand, A., Chen, T., Keskin, B., Maddipatla, D., Turkani, V.S., Kotkar, P.R., et al.. (2020). Surface free energy estimation: a new methodology for solid surfaces. Adv. Mater. Interfaces 7: 1901570, https://doi.org/10.1002/admi.201901570.Search in Google Scholar

An, J., Zhang, M., Wang, S., and Tang, J. (2008). Physical, chemical and microbiological changes in stored green asparagus spears as affected by coating of silver nanoparticles-PVP. LWT-Food Sci. Technol. 41: 1100–1107, https://doi.org/10.1016/j.lwt.2007.06.019.Search in Google Scholar

Aydemir, C., Karademir, A., İmamoglu, S., Altay, B.N., Fleming, P.D., and Tutak, D. (2019). Investigation of the evolution of hydrophobicity and wettability of paper in multi-color printing process. Cellulose Chem. Technol. 53: 787–794, https://doi.org/10.35812/cellulosechemtechnol.2019.53.77.Search in Google Scholar

Ching, K.S., Ching, Y.C., Ng, C.A., Ishenny, N., and Beg, M.T.H. (2014). Effect of polyurethane/nanosilica composite coating on water resistance of paper substrate. Mater. Res. Innov. 18: S6–S368, https://doi.org/10.1179/1432891714z.0000000001009.Search in Google Scholar

Clinical and Laboratory Standards Institute (CLSI). (2006). Standards of practice for antibiotic susceptibility tests; approved standard, M2A9. Vol. XXVI, CLSI, Pittsburgh, USA.Search in Google Scholar

Cornelis, G., Doolette Madeleine Thomas, C., McLaughlin, M.J., Kirby, J.K., Beak, D.G., and Chittleborough, D. (2012). Retention and dissolution of engineered silver nanoparticles in natural soils. Soil Sci. Soc. Am. J. 76: 891–902.10.2136/sssaj2011.0360Search in Google Scholar

Deshwal, G.K., Panjagari, N.R., and Alam, T. (2019). An overview of paper and paper based food packaging materials: health safety and environmental concerns. J. Food Sci. Technol. 56: 4391–4403, https://doi.org/10.1007/s13197-019-03950-z.Search in Google Scholar PubMed PubMed Central

Ghorbani, H.R. (2014). Biological coating of paper using silver nanoparticles. IET Nanobiotechnol. 8: 263–266, https://doi.org/10.1049/iet-nbt.2013.0039.Search in Google Scholar PubMed

Hospodarova, V., Singovszka, E., and Stevulova, N. (2018). Characterization of cellulosic fibers by FTIR spectroscopy for their further implementation to building materials. Am. J. Anal. Chem. 9: 303–310, https://doi.org/10.4236/ajac.2018.96023.Search in Google Scholar

Ibrahim, I.D., Hamam, Y., Sadiku, E.R., Ndambuki, J.M., Kupolati, W.K., Jamiru, T., Eze, A.A., and Snyman, J. (2022). Need for sustainable packaging: an overview. Polymer 14: 4430, https://doi.org/10.3390/polym14204430.Search in Google Scholar PubMed PubMed Central

Jin, S., Qi, Y., Shen, Y., and Li, H. (2021). A transparent polyurethane based on nanosilica in reinforcing papers. Nord. Pulp Pap. Res. J. 36: 82–90, https://doi.org/10.1515/npprj-2019-0099.Search in Google Scholar

Jung, J., Raghavendra, G.M., Kim, D., and Seo, J. (2018). One-step synthesis of starch-silver nanoparticle solution and its application to antibacterial paper coating. Int. J. Biol. Macromol. 107: 2285–2290, https://doi.org/10.1016/j.ijbiomac.2017.10.108.Search in Google Scholar PubMed

Kandirmaz, E.A. and Ozcan, A. (2019). Antibacterial effect of Ag nanoparticles into the paper coatings. Nord. Pulp Pap. Res. J. 34: 507–515.10.1515/npprj-2019-0034Search in Google Scholar

Krishna, R., Nagar, V., Kaur, A., Rai, A.R., Awasthi, K.K., Awasthi, G., and Sankhla, M.S. (2024). Toxicological effects of metal nanoparticles employed in biomedicine: biocompatibility, clinical trials, and future perspective. Macromol. Symp. 413: 2300057, https://doi.org/10.1002/masy.202300057.Search in Google Scholar

Kwon, G.J., Han, S.Y., Park, C.W., Park, J.S., Lee, E.A., Kim, N.H., Alle, M., Bandi, R., and Lee, S.H. (2020). Adsorption characteristics of Ag nanoparticles on cellulose nanofibrils with different chemical compositions. Polymer 12: 164, https://doi.org/10.3390/polym12010164.Search in Google Scholar PubMed PubMed Central

Li, H. and Xu, H. (2024). Mechanisms of bacterial resistance to environmental silver and antimicrobial strategies for silver: a review. Environ. Res. 248: 118313, https://doi.org/10.1016/j.envres.2024.118313.Search in Google Scholar PubMed

Li, H., Qi, Y., Zhao, Y., Chi, J., and Cheng, S. (2019). Starch and its derivatives for paper coatings: a review. Prog. Org. Coat. 135: 213–227, https://doi.org/10.1016/j.porgcoat.2019.05.015.Search in Google Scholar

Lu, Z., Hu, W., Xie, F., Zhuo, L., and Yang, B. (2017). Sol–gel synthesis of nanosilica-coated para-aramid fibers and their application in the preparation of paper-based friction materials. RSC Adv. 7: 30632–30639, https://doi.org/10.1039/c7ra05142e.Search in Google Scholar

More, P.R., Pandit, S., Filippis, A.D., Franci, G., Mijakovic, I., and Galdiero, M. (2023). Silver nanoparticles: bactericidal and mechanistic approach against drug resistant pathogens. Microorganisms 11: 369, https://doi.org/10.3390/microorganisms11020369.Search in Google Scholar PubMed PubMed Central

Nassar, M.A. and Youssef, A.M. (2012). Mechanical and antibacterial properties of recycled carton paper coated by PS/Ag nanocomposites for packaging. Carbohydr. Polym. 89: 269–274, https://doi.org/10.1016/j.carbpol.2012.03.007.Search in Google Scholar PubMed

Olejnik, K., Stanislawska, A., and Wysocka-Robak, A. (2016) Properties of natural cellulose fibers and methods of their modification for the purpose of paper quality improvement. In: Handbook of sustainable polymers: Structure and chemistry, Vol. 19. Institute of Papermaking and Printing, Lodz University of Technology, Wolczanska, Lodz, Poland, pp. 47–98, https://doi.org/10.1201/b19948-5.Search in Google Scholar

Ozcan, A., Kandirmaz, E.A., and Buyukpehlivan, G.A. (2023). Chitosan-titanium nanoparticle coated papers for active packaging. J. Food Eng. 356: 111584.10.1016/j.jfoodeng.2023.111584Search in Google Scholar

Qi, H. (2017). Novel functional materials based on cellulose. Springer International Publishing, Cham, Switzerland.10.1007/978-3-319-49592-7Search in Google Scholar

Rastogi, V.K. and Samyn, P. (2015). Bio-based coatings for paper applications. Coatings 5: 887–930, https://doi.org/10.3390/coatings5040887.Search in Google Scholar

Sahin, H.T. and Arslan, M.B. (2008). A study on physical and chemical properties of cellulose paper immersed in various solvent mixtures. Int. J. Mol. Sci. 9: 78–88, https://doi.org/10.3390/ijms9010078.Search in Google Scholar PubMed PubMed Central

Srikhao, N., Ounkaew, A., Srichiangsa, N., Phanthanawiboon, S., Boonmars, T., Artchayasawat, A., Theerakulpisut, A., Okhavilai, M., and Kasemsiri, P. (2023). Green-synthesized silver nanoparticle coating on paper for antibacterial and antiviral applications. Polym. Bull. 80: 9651–9668, https://doi.org/10.1007/s00289-022-04530-6.Search in Google Scholar PubMed PubMed Central

Tang, H., Xiong, H., Tang, S., and Zou, P. (2009). A starch-based biodegradable film modified by nano silicon dioxide. J. Appl. Polym. Sci. 113: 34–40, https://doi.org/10.1002/app.29855.Search in Google Scholar

Tessema, B., Gonfa, G., Hailegiorgis, S.M., Workneh, G.A., and Tadesse, T.G. (2024). Synthesis and evaluation of the anti-bacterial effect of modified silica gel supported silver nanoparticles on E. coli and S. aureus. Results Chem. 7: 101471.10.1016/j.rechem.2024.101471Search in Google Scholar

Wyrwa, J. and Barska, A. (2017). Innovations in the food packaging market: active packaging. Eur. Food Res. Technol. 243: 1681–1692, https://doi.org/10.1007/s00217-017-2878-2.Search in Google Scholar

Xia, Y., Wang, S., Meng, F., Xu, Z., Fang, Q., Gu, Z., Zhang, C., Li, P., and Kong, F. (2024). Eco-friendly food packaging based on paper coated with a bio-based antibacterial coating composed of carbamate starch, calcium lignosulfonate, cellulose nanofibrils, and silver nanoparticles. Int. J. Biol. Macromol. 254: 127659, https://doi.org/10.1016/j.ijbiomac.2023.127659.Search in Google Scholar PubMed

Yang, D., Liu, Q., Gao, Y., Wan, S., Meng, F., Weng, W., and Zhang, Y. (2023). Characterization of silver nanoparticles loaded chitosan/polyvinyl alcohol antibacterial films for food packaging. Food Hydrocoll. 136: 108305, https://doi.org/10.1016/j.foodhyd.2022.108305.Search in Google Scholar

Yildirim, S. and Röcker, B. (2018). Active packaging. In: Nanomaterials for food packaging. Elsevier: Amsterdam, Netherlands, pp. 173–202.10.1016/B978-0-323-51271-8.00007-3Search in Google Scholar

Yildirim, S., Röcker, B., Pettersen, M.K., Nilsen-Nygaard, J., Ayhan, Z., Rutkaite, R., Radusin, T., Suminska, P., Marcos, B., and Coma, V. (2018). Active packaging applications for food. Compr. Rev. Food Sci. F 17: 165–199, https://doi.org/10.1111/1541-4337.12322.Search in Google Scholar PubMed

Zhou, S.X., Wu, L.M., Sun, J., and Shen, W.D. (2003). Effect of nanosilica on the properties of polyester-based polyurethane. J. Appl. Polym. Sci. 88: 189–193, https://doi.org/10.1002/app.11624.Search in Google Scholar

Zhou, X., Wu, M., Fu, L., Liao, M., Deng, L., Wang, L., Wang, H., Xiang, Y., and Chen, S. (2023). A facile preparation process of polyhexamethylene biguanide/cellulose/polylactic acid fiber composite antibacterial paper. Ind. Crop. Prod. 191: 115980, https://doi.org/10.1016/j.indcrop.2022.115980.Search in Google Scholar

Received: 2024-04-18
Accepted: 2025-04-17
Published Online: 2025-04-29
Published in Print: 2025-09-25

© 2025 Walter de Gruyter GmbH, Berlin/Boston

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