Wet route pellets production using primary sludge from kraft pulp mill
-
Bruna Virgínia Cunha Rodrigues
, Angélica de Cássia Oliveira Carneiro
Abstract
The substantial expansion of the Brazilian pulp and paper industry in the last years resulted in a significant increase in the solid waste generation. This paper investigates the production of pellets using primary sludge from the effluent treatment plant of a kraft pulp mill, as a fuel for producing energy, using a novel wet route process. The pellet samples were produced in a laboratory pelletizing press, which has a horizontal circular matrix. The samples were characterized by moisture content, high heating value, ash content, dimensions (diameter and length), mechanical durability and fines content. The net heating value and energetic density were also measured. The pellets manufactured with primary sludge were compared to the European standard for non-woody pellets. Pelletization caused a reduction of the moisture content by 37.8 %, and increased the net heating value by 41 % and bulk density by approximately 39 %, which resulted in a 263 % increase in the material´s energetic density. Pellet production using a wet route process was appropriate for the primary sludge, and produced pellets with a high mechanical durability (99.3 %) and low fines content (0.062 %), indicating the potential of thermal valorization for incineration in the biomass boiler to produce high-quality steam.
Funding source: Conselho Nacional de Desenvolvimento Científico e Tecnológico
Award Identifier / Grant number: 830235/1999-0
Funding source: Coordenação de Aperfeiçoamento de Pessoal de Nível Superior
Award Identifier / Grant number: 1840925
Funding source: Fundação de Amparo à Pesquisa do Estado de Minas Gerais
Award Identifier / Grant number: 503
Funding statement: We also acknowledge the Conselho Nacional de Tecnologia e Desenvolvimento Científico (CNPq – 830235/1999-0), Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES – 1840925) and Fundação de Amparo à Pesquisa do Estado de Minas Gerais (FAPEMIG – 503) for the support provided for this investigation.
Acknowledgments
The authors thank the dedication of all employees and students of the Pulp and Paper Laboratory and the Laboratory of Wood Panels and Energy of the Universidade Federal de Vicosa.
Conflict of interest: The authors declare no conflicts of interest.
References
ASTM ASTM D2015 – Standard Test Method for Gross Calorific Value of Coal and Coke by the Adiabatic Bomb Calorimeter. ASTM International – American Society for Testing and Materials, Philadelphia, PA, U.S.A., 1982.Search in Google Scholar
Bajpai, P. (2015) Generation of waste in pulp and paper mills. In: Manag. Pulp Pap. Mill Waste. Springer, Cham. pp. 9–17.10.1007/978-3-319-11788-1_2Search in Google Scholar
Buratti, C., Barbanera, M., Bartocci, P., Fantozzi, F. (2015) Thermogravimetric analysis of the behavior of sub-bituminous coal and cellulosic ethanol residue during co-combustion. Bioresour. Technol. 186:154–162.10.1016/j.biortech.2015.03.041Search in Google Scholar PubMed
Carroll, J. P., Finnan, J. (2012) Physical and chemical properties of pellets from energy crops and cereal straws. Biosyst. Eng. 112(2):151–159.10.1016/j.biosystemseng.2012.03.012Search in Google Scholar
Castellano, J. M., Gómez, M., Fernández, M., Esteban, L. S., Carrasco, J. E. (2015) Study on the effects of raw materials composition and pelletization conditions on the quality and properties of pellets obtained from different woody and non woody biomasses. Fuel 139:629–636.10.1016/j.fuel.2014.09.033Search in Google Scholar
Castro, J. de S., Assemany, P. P., Carneiro, A. C. de O., Ferreira, J., de Jesus Júnior, M. M., Rodrigues, F. de Á., Calijuri, M. L. (2021) Hydrothermal carbonization of microalgae biomass produced in agro-industrial effluent: Products, characterization and applications. Sci. Total Environ. 768:144480.10.1016/j.scitotenv.2020.144480Search in Google Scholar PubMed
Coimbra, R. N., Paniagua, S., Escapa, C., Calvo, L. F., Otero, M. (2016) Thermal Valorization of Pulp Mill Sludge by Co-processing with Coal. Waste Biomass Valorization 7(4):995–1006.10.1007/s12649-016-9524-2Search in Google Scholar
Costa, A., Tamíris, P., Quinteiro, P., Tarelho, L. A. C., Arroja, L., Dias, A. C. (2020) Life cycle assessment of woody biomass ash for soil amelioration. Waste Manag. 101:126–140.10.1016/j.wasman.2019.10.006Search in Google Scholar PubMed
DIN (2009) DIN EN 14774-1 – Solid biofuels – Determination of moisture content – Oven dry method – Part 2: Total moisture – Simplified method, DIN-Deutsches Institut für Normung, Berlin, BE, Germany, 9.Search in Google Scholar
DIN (2010a) DIN EN 14918 – Determination of calorific value, DIN-Deutsches Institut für Normung, Berlin, BE, Germany, 63.Search in Google Scholar
DIN (2010b) DIN EN 14774-2 – Solid biofuels – Determination of moisture content – Oven dry method – Part 1: Total moisture – Reference method, DIN-Deutsches Institut für Normung, Berlin, BE, Germany, 10.Search in Google Scholar
DIN (2010c) DIN EN 15103 – Solid biofuels – Determination of bulk density, DIN-Deutsches Institut für Normung, Berlin, BE, Germany, 14.Search in Google Scholar
DIN (2010d) DIN EN 15210-1 – Solid biofuels – Determination of mechanical durability of pellets and briquettes – Part 1: Pellets, DIN-Deutsches Institut für Normung, Berlin, BE, Germany, 12.Search in Google Scholar
DIN (2012a) DIN EN 16127 – Solid biofuels – Determination of length and diameter of pellets, DIN-Deutsches Institut für Normung, Berlin, BE, Germany, 11.Search in Google Scholar
DIN (2012b) DIN EN 14961-6 – Solid biofuels – Fuel specifications and classes – Part 6: Non-woody pellets for non-industrial use, DIN-Deutsches Institut für Normung, Berlin, BE, Germany, 16.Search in Google Scholar
Elliott, A., Mahmood, T. (2005) Survey benchmarks generation, management of solid residues. Pulp Pap. 79(12):49–55.Search in Google Scholar
Faubert, P., Barnabé, S., Bouchard, S., Côté, R., Villeneuve, C. (2016) Pulp and paper mill sludge management practices: What are the challenges to assess the impacts on greenhouse gas emissions? Resour. Conserv. Recycl. 108:107–133.10.1016/j.resconrec.2016.01.007Search in Google Scholar
Garcia, D. P., Caraschi, J. C., Ventorim, G., Vieira, F. H. A., de Paula Protásio, T. (2019) Assessment of plant biomass for pellet production using multivariate statistics (PCA and HCA). Renew. Energy 139:796–805.10.1016/j.renene.2019.02.103Search in Google Scholar
Garcia, D. P., Caraschi, J. C., Ventorim, G., Vieira, F. H. A., Protásio, T. de P. (2018) Comparative Energy Properties of Torrefied Pellets in Relation to Pine and Elephant Grass Pellets. BioResources 13(2):2898–2906.10.15376/biores.13.2.2898-2906Search in Google Scholar
Garcia-Maraver, A., Rodriguez, M. L., Serrano-Bernardo, F., Diaz, L. F., Zamorano, M. (2015) Factors affecting the quality of pellets made from residual biomass of olive trees. Fuel Process. Technol. 129:1–7.10.1016/j.fuproc.2014.08.018Search in Google Scholar
Gurram, R. N., Al-Shannag, M., Lecher, N. J., Duncan, S. M., Singsaas, E. L., Alkasrawi, M. (2015) Bioconversion of paper mill sludge to bioethanol in the presence of accelerants or hydrogen peroxide pretreatment. Bioresour. Technol. 192:529–539.10.1016/j.biortech.2015.06.010Search in Google Scholar PubMed
Huang, Y., Finell, M., Larsson, S., Wang, X., Zhang, J., Wei, R., Liu, L. (2017) Biofuel pellets made at low moisture content – Influence of water in the binding mechanism of densified biomass. Biomass Bioenergy 98:8–14.10.1016/j.biombioe.2017.01.002Search in Google Scholar
IBÁ (2020) Statistics of Brazilian tree industry/ 4th Quarter 2019, IBÁ, São Paulo/Brasília, 7.Search in Google Scholar
Jaria, G., Silva, C. P., Ferreira, C. I. A., Otero, M., Calisto, V. (2017) Sludge from paper mill effluent treatment as raw material to produce carbon adsorbents: An alternative waste management strategy. J. Environ. Manag. 188:203–211.10.1016/j.jenvman.2016.12.004Search in Google Scholar PubMed
Kuosa, M., Kopra, R. (2019) Novel methods for monitoring the sludge dewatering operation of a belt filter: a mill study. Nord. Pulp Pap. Res. J. 34(4):550–557.10.1515/npprj-2019-0012Search in Google Scholar
Lee, J.-Y., Kim, C.-H., Kown, S., Park, H.-H. (2017) Effect of composting of paper mill sludge for land spreading. Nord. Pulp Pap. Res. J. 32(4):691–698.10.3183/npprj-2017-32-04_p691-698_kimSearch in Google Scholar
Liu, Z., Liu, X., Fei, B., Jiang, Z., Cai, Z., Yu, Y. (2013) The properties of pellets from mixing bamboo and rice straw. Renew. Energy 55:1–5.10.1016/j.renene.2012.12.014Search in Google Scholar
Lopes, A. do C. P., Silva, C. M., Rosa, A. P., Rodrigues, F. de Á. (2018) Biogas production from thermophilic anaerobic digestion of kraft pulp mill sludge. Renew. Energy, SI: Waste Biomass to Biofuel 124:40–49.10.1016/j.renene.2017.08.044Search in Google Scholar
Lopes, E. J., Okamura, L. A., Yamamoto, C. I., Lopes, E. J., Okamura, L. A., Yamamoto, C. I. (2015) Formation of dioxins and furans during municipal solid waste gasification. Braz. J. Chem. Eng. 32(1):87–97.10.1590/0104-6632.20150321s00003163Search in Google Scholar
de Magalhães, M. A., da Silva, C. M. S., Carneiro, A. de C. O., Vital, B. R., Teixeira, V. L., Fialho, L. de F., Figueiró, C. G. (2018) Estimativas de propriedades energéticas de pellets torrificados por meio de parâmetros colorimétricos. Rev. Ciênc. Madeira Braz. J. Wood Sci. 10:1.10.12953/2177-6830/rcm.v10n1p29-38Search in Google Scholar
Malaiskiene, J., Kizinievic, O., Kizinievic, V., Boris, R. (2018) The impact of primary sludge from paper industry on the properties of hardened cement paste and mortar. Constr. Build. Mater. 172:553–561.10.1016/j.conbuildmat.2018.04.011Search in Google Scholar
Martinez, C. L. M., Alves Rocha, E. P., Oliveira Carneiro, A. de C., Borges Gomes, F. J., Ribas Batalha, L. A., Vakkilainen, E., Cardoso, M. (2019) Characterization of residual biomasses from the coffee production chain and assessment the potential for energy purposes. Biomass Bioenergy 120:68–76.10.1016/j.biombioe.2018.11.003Search in Google Scholar
Monte, M. C., Fuente, E., Blanco, A., Negro, C. (2009) Waste management from pulp and paper production in the European Union. Waste Manag. 29(1):293–308.10.1016/j.wasman.2008.02.002Search in Google Scholar PubMed
Mostafa, M. E., Hu, S., Wang, Y., Su, S., Hu, X., Elsayed, S. A., Xiang, J. (2019) The significance of pelletization operating conditions: An analysis of physical and mechanical characteristics as well as energy consumption of biomass pellets. Renew. Sustain. Energy Rev. 105:332–348.10.1016/j.rser.2019.01.053Search in Google Scholar
Njoku, P. O., Edokpayi, J. N., Odiyo, J. O. (2019) Health and Environmental Risks of Residents Living Close to a Landfill: A Case Study of Thohoyandou Landfill, Limpopo Province, South Africa. Int. J. Environ. Res. Public Health, Multidisciplinary Digital Publishing Institute 16:12. 2125.10.3390/ijerph16122125Search in Google Scholar PubMed PubMed Central
Nosek, R., Holubcik, M., Jandacka, J., Radacovska, L. (2017) Analysis of Paper Sludge Pellets for Energy Utilization. BioResources 12(4):7032–7040.10.15376/biores.12.4.7032-7040Search in Google Scholar
Obernberger, I., Brunner, T., Bärnthaler, G. (2006) Chemical properties of solid biofuels—significance and impact. Biomass Bioenergy 30(11):973–982.10.1016/j.biombioe.2006.06.011Search in Google Scholar
Obernberger, I., Thek, G. (2004) Physical characterisation and chemical composition of densified biomass fuels with regard to their combustion behaviour. Pellets 2002. The first world conference on pellets. Biomass Bioenergy 27(6):653–669.10.1016/j.biombioe.2003.07.006Search in Google Scholar
Orang, N., Tran, H. (2015) Effect of feedstock moisture content on biomass boiler operation. Tappi J. 14:629–637.10.32964/TJ14.10.629Search in Google Scholar
Pereira, B. L. C., Carneiro, A. de C. O., Carvalho, A. M. M. L., Colodette, J. L., Oliveira, A. C., Fontes, M. P. F. (2013) Influence of Chemical Composition of Eucalyptus Wood on Gravimetric Yield and Charcoal Properties. BioResources 8(3):4574–4592.10.15376/biores.8.3.4574-4592Search in Google Scholar
Pöykiö, R., Watkins, G., Dahl, O. (2018) Characterization of primary and secondary wastewater treatment sludge from a pulp and board mill complex to evaluate the feasibility of utilization as a soil amendment agent and a fertilizer product. J. Bioresour. Bioprod.. 3(3):88–95.10.21967/jbb.v3i3.174Search in Google Scholar
Prins, M. J., Ptasinski, K. J., Janssen, F. J. J. G. (2006) Torrefaction of wood: Part 1. Weight loss kinetics. J. Anal. Appl. Pyrolysis 77(1):28–34.10.1016/j.jaap.2006.01.002Search in Google Scholar
Santana, D. A. R., Scatolino, M. V., Lima, M. D. R., de Oliveira Barros Junior, U., Garcia, D. P., Andrade, C. R., de Cássia Oliveira Carneiro, A., Trugilho, P. F., de Paula Protásio, T. (2020) Pelletizing of lignocellulosic wastes as an environmentally friendly solution for the energy supply: insights on the properties of pellets from Brazilian biomasses. Environ. Sci. Pollut. Res.10.1007/s11356-020-11401-ySearch in Google Scholar PubMed
SCAN (1989) Scan – W.9: 89. Organically bound chlorine by the AOX method, Testing committee, box 5604, S – 11486, Scanbdina – VIAN Pouep, Paper and Board, Stockholm, Sweden.Search in Google Scholar
Scatolino, M. V., Neto, L. F. C., Protásio, T. de P., Carneiro, A. de C. O., Andrade, C. R., Guimarães Júnior, J. B., Mendes, L. M. (2018) Options for Generation of Sustainable Energy: Production of Pellets Based on Combinations Between Lignocellulosic Biomasses. Waste Biomass Valorization 9(3):479–489.10.1007/s12649-017-0010-2Search in Google Scholar
da Silva, C. M. S., Vital, B. R., Rodrigues, F. de Á., de Almeida, Ê.W., Carneiro, A. de C. O., Cândido, W. L. (2019) Hydrothermal and organic-chemical treatments of eucalyptus biomass for industrial purposes. Bioresour. Technol. 289:121731.10.1016/j.biortech.2019.121731Search in Google Scholar PubMed
Simão, L., Hotza, D., Raupp-Pereira, F., Labrincha, J. A., Montedo, O. R. K. (2019) Characterization of pulp and paper mill waste for the production of waste-based cement. Rev. Int. Contam. Ambient. 35(1):237–246.10.20937/RICA.2019.35.01.17Search in Google Scholar
de Souza, H. J. P. L., Arantes, M. D. C., Vidaurre, G. B., Andrade, C. R., Carneiro, A. de C. O., de Souza, D. P. L., Protásio, T. de P. (2020) Pelletization of eucalyptus wood and coffee growing wastes: Strategies for biomass valorization and sustainable bioenergy production. Renew. Energy 149:128–140.10.1016/j.renene.2019.12.015Search in Google Scholar
TAPPI (1985) TAPPI T 257 om-85 – Sampling and preparing wood for analysis, TAPPI – Techinical association of the pulp and paper industry, Atlanta, GA, U.S.A.Search in Google Scholar
TAPPI (2006) TAPPI T 266 om-18 – Determination of Sodium, Calcium, Copper, Iron, and Manganese in Pulp and Paper by Atomic Absorption Spectroscopy, TAPPI – Techinical association of the pulp and paper industry, Atlanta, GA, U.S.A.Search in Google Scholar
Tsuchiya, Y., Yoshida, T. (2017) Pelletization of brown coal and rice bran in Indonesia: Characteristics of the mixture pellets including safety during transportation. Fuel Process. Technol. 156:68–71.10.1016/j.fuproc.2016.10.009Search in Google Scholar
Tumuluru, J. S. (2018) Effect of pellet die diameter on density and durability of pellets made from high moisture woody and herbaceous biomass. Carbon Resour. Convers 1(1):44–54.10.1016/j.crcon.2018.06.002Search in Google Scholar
Valdés, C. F., Marrugo, G. P., Chejne, F., Marin-Jaramillo, A., Franco-Ocampo, J., Norena-Marin, L. (2020) Co-gasification and co-combustion of industrial solid waste mixtures and their implications on environmental emissions, as an alternative management. Waste Manag. 101:54–65.10.1016/j.wasman.2019.09.037Search in Google Scholar PubMed
Wang, Y., Wu, H., Sárossy, Z., Dong, C., Glarborg, P. (2017) Release and transformation of chlorine and potassium during pyrolysis of KCl doped biomass. Fuel 197:422–432.10.1016/j.fuel.2017.02.046Search in Google Scholar
Xing, J., Luo, K., Wang, H., Gao, Z., Fan, J. (2019) A comprehensive study on estimating higher heating value of biomass from proximate and ultimate analysis with machine learning approaches. Energy 188:116077.10.1016/j.energy.2019.116077Search in Google Scholar
Zambare, V. P., Christopher, L. P. (2020) Integrated biorefinery approach to utilization of pulp and paper mill sludge for value-added products. J. Clean. Prod. 274:122791.10.1016/j.jclepro.2020.122791Search in Google Scholar
© 2021 Walter de Gruyter GmbH, Berlin/Boston
Articles in the same Issue
- Frontmatter
- Review
- Aspects on bond strength in sheet structures from TMP and CTMP – a review
- Chemical pulping
- The impact of using different wood qualities and wood species on chips produced using a novel type of pilot drum chipper
- Temperature and effective alkali effect on brown pulp kraft cooking
- Mechanical pulping
- On the modeling of pulp properties in CTMP processes
- Paper technology
- Pulp pumping efficiency I – A critical review on loss and its estimation
- Pulp pumping efficiency II – Designing of a pulp pump
- Three-dimensional scanning electron microscopy used as a profilometer for the surface characterization of polyethylene-coated paperboard
- Paper chemistry
- Ageing mechanisms of the papers with zeolite and PCC fillers
- Synthesis of macro-RAFT agent containing M13-10 and its application in surface sizing agent
- Coating
- The role of MFC and hydrophobically modified ethyl(hydroxyethyl)cellulose in film formation and the barrier properties of methyl nanocellulose film
- Printing
- Fabrication of rosemary essential oil microcapsules and using in active packaging
- Packaging
- Development of a nonwetting coating for packaging substrate surfaces using a novel and easy to implement method
- Recycling
- Wet route pellets production using primary sludge from kraft pulp mill
- Chemical technology/modifications
- Modification of cellulosic filler with diisocyanates – volatile organic compounds emission assessment and stability of chemical structure over time
- Characterization and application of wood-ZrO2 sorbent for simultaneous removal of chromium (III) and chromium (VI) from binary mixture
Articles in the same Issue
- Frontmatter
- Review
- Aspects on bond strength in sheet structures from TMP and CTMP – a review
- Chemical pulping
- The impact of using different wood qualities and wood species on chips produced using a novel type of pilot drum chipper
- Temperature and effective alkali effect on brown pulp kraft cooking
- Mechanical pulping
- On the modeling of pulp properties in CTMP processes
- Paper technology
- Pulp pumping efficiency I – A critical review on loss and its estimation
- Pulp pumping efficiency II – Designing of a pulp pump
- Three-dimensional scanning electron microscopy used as a profilometer for the surface characterization of polyethylene-coated paperboard
- Paper chemistry
- Ageing mechanisms of the papers with zeolite and PCC fillers
- Synthesis of macro-RAFT agent containing M13-10 and its application in surface sizing agent
- Coating
- The role of MFC and hydrophobically modified ethyl(hydroxyethyl)cellulose in film formation and the barrier properties of methyl nanocellulose film
- Printing
- Fabrication of rosemary essential oil microcapsules and using in active packaging
- Packaging
- Development of a nonwetting coating for packaging substrate surfaces using a novel and easy to implement method
- Recycling
- Wet route pellets production using primary sludge from kraft pulp mill
- Chemical technology/modifications
- Modification of cellulosic filler with diisocyanates – volatile organic compounds emission assessment and stability of chemical structure over time
- Characterization and application of wood-ZrO2 sorbent for simultaneous removal of chromium (III) and chromium (VI) from binary mixture