Home Physical Sciences Crystal structure of chlorido-(2-ethoxy-6-(((quinolin-8-yl)methyl)-phenolato-κ3N,N′,O)-copper(II), C18H15ClCuN2O2
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Crystal structure of chlorido-(2-ethoxy-6-(((quinolin-8-yl)methyl)-phenolato-κ3N,N′,O)-copper(II), C18H15ClCuN2O2

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Published/Copyright: October 29, 2015
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Zeitschrift für Kristallographie - New Crystal Structures
From the journal Zeitschrift für Kristallographie - New Crystal Structures Volume 230 Issue 4

Abstract

C18H15ClCuN2O2, monoclinic, P21/c (no. 14), a = 8.949(2) Å, b = 22.198(5) Å, c = 8.279(2) Å, β = 106.646(3)°, V = 1575.6 Å3, Z = 4, Rgt(F) = 0.0293, wRref(F2) = 0.0778, T = 293 K.

CCDC no.:: 1267/4191

Source of material

The schiff base ligand (2-ethoxy-6-(((quinolin-8-yl)methyl)-phenolato L was synthesized according to the literature method [1]. The synthesis of the title complex was carried out by reacting CuCl2·2H2O and the schiff base ligand (molar ratio of 1:1) in methanol under the stirring condition at room temperature. The filtrated solution was left to slowly evaporate in air to obtain single crystal suitable for X-ray diffraction with the yield about 60%.

Table 1

Data collection and handling.

Crystal:Blue block, size 0.23×0.26×0.31 mm
Wavelength:Mo Kα radiation (0.71073 Å)
μ:15.69 cm−1
Diffractometer, scan mode:Bruker APEX II CCD, φ and ω
2θmax:50.02°
N(hkl)measured, N(hkl)unique:7742, 2774
Criterion for Iobs, N(hkl)gt:Iobs > 2 σ(Iobs), 2348
N(param)refined:218
Programs:SADABS, SAINT, SHELX [9–11]
Table 2

Atomic coordinates and displacement parameters (in Å2).

AtomSitexyzUiso
H(1)4e0.46160.44310.73870.059
H(2)4e0.38070.36000.56500.070
H(3)4e0.12000.33920.46080.063
H(5)4e−0.16010.36600.45500.057
H(6)4e−0.32410.42810.54370.058
H(7)4e−0.22840.50920.72120.050
H(13)4e0.19910.76831.27430.053
H(14)4e−0.06040.73961.21370.056
H(15)4e−0.14820.65731.05020.050
H(16)4e−0.10930.57490.88980.043
H(17A)4e0.46180.78261.34510.064
H(17B)4e0.40730.80311.15510.064
H(18A)4e0.70030.75481.32010.091
H(18B)4e0.66920.82131.25480.091
H(18C)4e0.64630.76791.12590.091
Table 3

Atomic coordinates and displacement parameters (in Å2).

AtomSitexyzU11U22U33U12U13U23
Cu(1)4e0.30203(3)0.54600(1)0.87625(4)0.0297(2)0.0395(2)0.0413(2)−0.0032(1)0.0112(1)−0.0094(1)
Cl(1)4e0.54645(8)0.55753(3)0.84821(9)0.0366(4)0.0593(4)0.0623(5)−0.0083(3)0.0221(3)−0.0158(3)
O(1)4e0.3264(2)0.61603(8)1.0116(2)0.033(1)0.048(1)0.065(1)−0.0033(8)0.0173(9)−0.0222(9)
O(2)4e0.4232(2)0.71409(8)1.1833(3)0.042(1)0.040(1)0.078(1)−0.0042(8)0.017(1)−0.0180(9)
N(1)4e0.2565(2)0.47078(9)0.7405(3)0.033(1)0.034(1)0.039(1)0.0033(9)0.0042(9)0.0011(9)
N(2)4e0.0747(2)0.54364(8)0.8464(2)0.031(1)0.035(1)0.032(1)−0.0012(8)0.0082(9)0.0012(8)
C(1)4e0.3556(3)0.4349(1)0.6979(4)0.038(2)0.045(2)0.058(2)0.007(1)0.003(1)−0.007(1)
C(2)4e0.3074(3)0.3845(1)0.5928(4)0.052(2)0.044(2)0.075(2)0.013(1)0.010(2)−0.016(2)
C(3)4e0.1531(3)0.3719(1)0.5324(4)0.062(2)0.034(1)0.057(2)−0.000(1)0.008(2)−0.011(1)
C(4)4e0.0426(3)0.4085(1)0.5783(3)0.048(2)0.032(1)0.036(1)−0.006(1)0.005(1)0.003(1)
C(5)4e−0.1196(3)0.3982(1)0.5260(3)0.052(2)0.043(2)0.042(2)−0.015(1)0.006(1)−0.000(1)
C(6)4e−0.2173(3)0.4353(1)0.5790(3)0.037(2)0.059(2)0.044(2)−0.015(1)0.005(1)0.004(1)
C(7)4e−0.1597(3)0.4844(1)0.6863(3)0.037(2)0.048(2)0.043(2)−0.006(1)0.013(1)0.002(1)
C(8)4e−0.0027(3)0.4960(1)0.7395(3)0.035(1)0.036(1)0.027(1)−0.004(1)0.007(1)0.005(1)
C(9)4e0.1003(3)0.4578(1)0.6846(3)0.038(1)0.031(1)0.031(1)−0.002(1)0.006(1)0.007(1)
C(10)4e0.0603(3)0.6319(1)1.0147(3)0.035(1)0.035(1)0.034(1)0.005(1)0.011(1)0.006(1)
C(11)4e0.2211(3)0.6470(1)1.0563(3)0.038(1)0.035(1)0.038(1)0.002(1)0.016(1)0.001(1)
C(12)4e0.2694(3)0.7005(1)1.1536(3)0.040(2)0.033(1)0.044(1)−0.000(1)0.013(1)−0.000(1)
C(13)4e0.1649(3)0.7339(1)1.2101(3)0.055(2)0.034(1)0.047(2)0.005(1)0.019(1)−0.002(1)
C(14)4e0.0083(3)0.7170(1)1.1726(3)0.049(2)0.043(2)0.055(2)0.013(1)0.026(1)0.003(1)
C(15)4e−0.0434(3)0.6678(1)1.0764(3)0.035(1)0.044(2)0.048(2)0.009(1)0.016(1)0.011(1)
C(16)4e−0.0027(3)0.5815(1)0.9122(3)0.030(1)0.042(1)0.034(1)0.000(1)0.009(1)0.008(1)
C(17)4e0.4717(3)0.7746(1)1.2334(4)0.054(2)0.040(2)0.065(2)−0.003(1)0.014(2)−0.013(1)
C(18)4e0.6363(3)0.7801(1)1.2336(4)0.056(2)0.053(2)0.071(2)−0.011(2)0.015(2)−0.009(2)

Discussion

Due to their interesting structures and wide potential applicat tions, the schiff base complexes have all along attracted much attention, making them play an important role in the development of coordination chemistry as well as inorganic biochemistry, catalysis, optical materials and so on [2–6]. Here, we report the structure of a new copper complex based on an asymmetric tridentate schiff base ligand 2-ethoxy-6-((quinolin-8-ylimino)-methyl)phenolate. The molecular structure and the cell packing diagram of title compound, which crystallizes in monoclinic cell setting and P21/c space group, are shown in the figure. In the title compound, [Cu(L)Cl] (L=2-ethoxy-6-((quinolin-8-ylimino)methyl)phenol), the coordination sphere of the Cu ion is slightly distorted square planar, in which three positions are occupied by two N atoms and one O atom of the schiffbase ligand, and the other one results from one Cl atom. The mean deviation of the plane formed by CuN2OCl unit is 0.0435 Å, indicative of that these five atoms can form a nearly perfect plane. The Cu–O, Cu–N and Cu–Cl bond lengths are all basically consistant with those found in other Cu complexes containing similar schiff base ligands [7–8]. In the crystal structure, π⋯π interactions link the approximately planar molecules into stacks parallel to a axis.

Corresponding author: Jianzhong Xu, College of Chemistry and Environmental Science, Hebei University, Baoding 071002, Hebei Province, P. R. China, e-mail:

References

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Received: 2014-6-9
Accepted: 2014-10-2
Published Online: 2015-10-29
Published in Print: 2015-12-1

©2015 Shengli Li et al., published by De Gruyter.

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Articles in the same Issue

  1. Frontmatter
  2. Crystal structure of bis(ethyltriphenylphos-phonium) tetrabromidozincate(II), C40H40Br4P2Zn
  3. Crystal structure of chlorido-(2-ethoxy-6-(((quinolin-8-yl)methyl)-phenolato-κ3N,N′,O)-copper(II), C18H15ClCuN2O2
  4. Crystal structure of bis(ethyltriphenylphos-phonium) tetrabromidocobaltate(II), C40H40Br4CoP2
  5. Crystal structure of di(pyrrolidin-1-yl)methane-thione, C9H16N2S
  6. Crystal structure of ammonium phenylglyoxylate, C8H9NO3
  7. Crystal structure of 2-hydroxy-2-methyl-2-phenyl acetic acid hemihydrate, C9H11O3.50
  8. Crystal structure of 2-((E)-2-(1H-benzo[d]imidazol-2-yl)vinyl)-1H-benzo[d]imidazolium dichloride dihydrate, C16H18Cl2N4O2
  9. Crystal structure of 1,2-dimethylimidazolium iodide, C5H9IN2
  10. Crystal structure of catena-poly[(μ2-4,4′-bipyridine-κ2N:N′)-tetraqua-cobalt(II)] – (3-(carboxylatomethyl)benzoic acid) – water (1/2/2), C28H34CoN2O14
  11. Crystal structure of bis(2,2′-bipyridine-κ2N,N′)-bis(thiophene-3,4-dicarboxylato-κ2O,O′)-cadmium(II), C32H22CdN4O8S2
  12. Crystal structure of tetraaqua-(4,4′-diamino-1,1′-biphenyl-2,2′-disulfonato-κN)(4,4′-bipyridyl-κN)zinc(II) trihydrate, C22H32N4O13S2Zn
  13. Crystal structure of poly[[[(1,3-dimethyl-2-imidazolidinone-κ1O11) zinc(II)]-μ-1,4-benzenedi-carboxylato-κ4O1,O2:O3,O4]—1,3-dimethyl-2-imidazolidinone (1:1)], [Zn(C5H10N2O)(C8H4O4)]· C5H10N2O, C18H24N4O6Zn
  14. Crystal structure of poly[[(1,3-dimethyl-2-imidazolidinone-κ1O) zinc(II)]-μ-furan-2,5-dicarboxylato-κ4O,O′:O′′,O′′′], [Zn(C5H10N2O)(C6H2O5)], C22H24N4O12Zn2
  15. Crystal structure of catena-poly[(μ2-4,4′-bipyridine-κ2N:N′)-tetraquamanganese(II)] – (3-(carboxylatomethyl)benzoic acid) – water (1/2/2), C28H34MnN2O14
  16. Crystal structure of chlorido-tricarbonyl-bis(2-pyridylmethanone-N,N′)-rhenium(I), C14H8ClN2O4Re
  17. Crystal structure of (2-(benzoyl)phenolato-κ2O,O′)-trans-dichlorido -cis- bis(methoxido) niobium(V), C15H15Cl2NbO4
  18. Crystal structure of potassium diaqua dihydroxy(methylenediphosphonato-κ2-O,O′)cobaltate(III), CH10CoKO10P2
  19. Crystal structure of hexakis(4-(dimethylamino)pyridin-1-ium) decavanadate-water (1:16), C42H98N12O44V10
  20. Crystal structure of 4-diethylaminobenzaldehyde isonicotinoylhydrazone monohydrate, C17H20N4O·H2O, C17H22N4O2
  21. Crystal structure of bis[μ-1-[(2-ethyl-1H-imidazol-1-yl)methyl]-1H-benzotriazole-κ2N:N′]bis[dibromido]dimercury(II), C24H26Br4Hg2N10
  22. Crystal structure of poly{bis-[(4,4′-biphenyl-dicarboxylate-κ2O:O′)-μ-1,1′-oxy-bis-(ethane-2,1-diyl)-bis-(1H-imidazole)-κ2N:N′] zinc(II)}dihydrate, C48H48N8O12Zn2
  23. Crystal structure of sodium poly[(μ4-2,2′,2′′-nitrilotriacetato-κ4O,O′,O′′,N)magnesium(II)] monohydrate
  24. The crystal structure of 1-(2-(2-chloroethoxy)phenyl)ethanone
  25. The crystal structure of tris(μ2-1,3-bis(4,4,4-Trifluoro-3-oxido-1-(oxo)but-2-en-1-yl)phenyl-/κ4O,O′:O′′,O′′′)-bis(1,2-dimethoxyethane-O,O′)-diterbium(III)
  26. Crystal structure of (S)-2-(2,2′-diethoxy-[1,1′-binaphthalen]-6-yl)-4,4,5,5-tetra-methyl-2-imidazoline-1-oxyle, C31H33N2O3
  27. Crystal structure of cis-tetrachloridobis-(pyridine-κN)platinum(IV), C10H10Cl4N2Pt
  28. Crystal structure of catena-poly[aqua-(μ2-5-norbornene-2,3-dicarboxylato-κ3O,O′:O′′)-(1,10-phenanthroline-κ2N,N′)zinc(II)], [Zn(C9H8O4)(C12H8N2)(H2O)]n
https://doi.org/10.1515/ncrs-2014-0203
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Articles in the same Issue

  1. Frontmatter
  2. Crystal structure of bis(ethyltriphenylphos-phonium) tetrabromidozincate(II), C40H40Br4P2Zn
  3. Crystal structure of chlorido-(2-ethoxy-6-(((quinolin-8-yl)methyl)-phenolato-κ3N,N′,O)-copper(II), C18H15ClCuN2O2
  4. Crystal structure of bis(ethyltriphenylphos-phonium) tetrabromidocobaltate(II), C40H40Br4CoP2
  5. Crystal structure of di(pyrrolidin-1-yl)methane-thione, C9H16N2S
  6. Crystal structure of ammonium phenylglyoxylate, C8H9NO3
  7. Crystal structure of 2-hydroxy-2-methyl-2-phenyl acetic acid hemihydrate, C9H11O3.50
  8. Crystal structure of 2-((E)-2-(1H-benzo[d]imidazol-2-yl)vinyl)-1H-benzo[d]imidazolium dichloride dihydrate, C16H18Cl2N4O2
  9. Crystal structure of 1,2-dimethylimidazolium iodide, C5H9IN2
  10. Crystal structure of catena-poly[(μ2-4,4′-bipyridine-κ2N:N′)-tetraqua-cobalt(II)] – (3-(carboxylatomethyl)benzoic acid) – water (1/2/2), C28H34CoN2O14
  11. Crystal structure of bis(2,2′-bipyridine-κ2N,N′)-bis(thiophene-3,4-dicarboxylato-κ2O,O′)-cadmium(II), C32H22CdN4O8S2
  12. Crystal structure of tetraaqua-(4,4′-diamino-1,1′-biphenyl-2,2′-disulfonato-κN)(4,4′-bipyridyl-κN)zinc(II) trihydrate, C22H32N4O13S2Zn
  13. Crystal structure of poly[[[(1,3-dimethyl-2-imidazolidinone-κ1O11) zinc(II)]-μ-1,4-benzenedi-carboxylato-κ4O1,O2:O3,O4]—1,3-dimethyl-2-imidazolidinone (1:1)], [Zn(C5H10N2O)(C8H4O4)]· C5H10N2O, C18H24N4O6Zn
  14. Crystal structure of poly[[(1,3-dimethyl-2-imidazolidinone-κ1O) zinc(II)]-μ-furan-2,5-dicarboxylato-κ4O,O′:O′′,O′′′], [Zn(C5H10N2O)(C6H2O5)], C22H24N4O12Zn2
  15. Crystal structure of catena-poly[(μ2-4,4′-bipyridine-κ2N:N′)-tetraquamanganese(II)] – (3-(carboxylatomethyl)benzoic acid) – water (1/2/2), C28H34MnN2O14
  16. Crystal structure of chlorido-tricarbonyl-bis(2-pyridylmethanone-N,N′)-rhenium(I), C14H8ClN2O4Re
  17. Crystal structure of (2-(benzoyl)phenolato-κ2O,O′)-trans-dichlorido -cis- bis(methoxido) niobium(V), C15H15Cl2NbO4
  18. Crystal structure of potassium diaqua dihydroxy(methylenediphosphonato-κ2-O,O′)cobaltate(III), CH10CoKO10P2
  19. Crystal structure of hexakis(4-(dimethylamino)pyridin-1-ium) decavanadate-water (1:16), C42H98N12O44V10
  20. Crystal structure of 4-diethylaminobenzaldehyde isonicotinoylhydrazone monohydrate, C17H20N4O·H2O, C17H22N4O2
  21. Crystal structure of bis[μ-1-[(2-ethyl-1H-imidazol-1-yl)methyl]-1H-benzotriazole-κ2N:N′]bis[dibromido]dimercury(II), C24H26Br4Hg2N10
  22. Crystal structure of poly{bis-[(4,4′-biphenyl-dicarboxylate-κ2O:O′)-μ-1,1′-oxy-bis-(ethane-2,1-diyl)-bis-(1H-imidazole)-κ2N:N′] zinc(II)}dihydrate, C48H48N8O12Zn2
  23. Crystal structure of sodium poly[(μ4-2,2′,2′′-nitrilotriacetato-κ4O,O′,O′′,N)magnesium(II)] monohydrate
  24. The crystal structure of 1-(2-(2-chloroethoxy)phenyl)ethanone
  25. The crystal structure of tris(μ2-1,3-bis(4,4,4-Trifluoro-3-oxido-1-(oxo)but-2-en-1-yl)phenyl-/κ4O,O′:O′′,O′′′)-bis(1,2-dimethoxyethane-O,O′)-diterbium(III)
  26. Crystal structure of (S)-2-(2,2′-diethoxy-[1,1′-binaphthalen]-6-yl)-4,4,5,5-tetra-methyl-2-imidazoline-1-oxyle, C31H33N2O3
  27. Crystal structure of cis-tetrachloridobis-(pyridine-κN)platinum(IV), C10H10Cl4N2Pt
  28. Crystal structure of catena-poly[aqua-(μ2-5-norbornene-2,3-dicarboxylato-κ3O,O′:O′′)-(1,10-phenanthroline-κ2N,N′)zinc(II)], [Zn(C9H8O4)(C12H8N2)(H2O)]n
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