Article
Licensed
Unlicensed Requires Authentication

Corrosion behavior of AISI 1045 carbon steel in simulated marine, acidic, and agricultural environments

  • Dr. Meltem Eryildiz, born in 1987, is an Associate Professor of Mechanical Engineering at Istanbul Beykent University, Turkey, specializing in additive manufacturing and polymer composites.

    ORCID logo EMAIL logo
    and

    Yasemin Bayhan, born in 2002, is an undergraduate Mechanical Engineering student at Istanbul Beykent University, aims to pursue an academic career in the field of materials science.

Published/Copyright: March 19, 2026
Become an author with De Gruyter Brill
Materials Testing
From the journal Materials Testing

Abstract

This study investigates the corrosion behavior of AISI 1045 medium-carbon steel under three simulated corrosive environments: marine (NaCl), acidic (H2SO4), and agricultural (NH4Cl). Tensile specimens were exposed for varying durations (1 and 5 days) and evaluated through corrosion rate measurements, surface hardness testing, tensile testing, and surface/fracture morphology analysis. The highest corrosion rate (7.41 mm·a−1) was recorded after 1 day of exposure to H2SO4 which rapidly deteriorated mechanical properties due to aggressive acid attack and hydrogen-induced embrittlement. In contrast, NaCl exposure caused significant localized corrosion and a pronounced reduction in hardness (∼70 %), while NH4Cl exposure resulted in moderate and more uniform degradation. Tensile strength, elastic modulus, and ductility declined in all corroded specimens, correlating closely with fracture morphology and surface deterioration. These findings highlight the vulnerability of AISI 1045 steel to diverse environmental conditions and emphasize the need for protective strategies in service applications.


Corresponding author: Meltem Eryildiz, Istanbul Beykent University, Department of Mechanical Engineering, Faculty of Engineering and Architecture, Istanbul, Türkiye, E-mail:

About the authors

Meltem Eryildiz

Dr. Meltem Eryildiz, born in 1987, is an Associate Professor of Mechanical Engineering at Istanbul Beykent University, Turkey, specializing in additive manufacturing and polymer composites.

Yasemin Bayhan

Yasemin Bayhan, born in 2002, is an undergraduate Mechanical Engineering student at Istanbul Beykent University, aims to pursue an academic career in the field of materials science.

  1. Research ethics: Not applicable.

  2. Informed consent: Not applicable.

  3. Author contributions: The authors have accepted full responsibility for the entire content of this submitted manuscript and approved its submission to the journal. Yasemin Bayhan identified the research topic, conducted the literature review, performed the experimental studies, and prepared the original draft of the manuscript. Meltem Eryildiz provided academic supervision, contributed to the experimental planning and design, and was responsible for the critical review and editing of the manuscript.

  4. Use of Large Language Models, AI and Machine Learning Tools: None declared.

  5. Conflict of interest: The authors state no conflict of interest.

  6. Research funding: None declared.

  7. Data availability: Not applicable.

References

[1] E. McCafferty, Introduction to Corrosion Science, New York, Springer, 2010.10.1007/978-1-4419-0455-3Search in Google Scholar

[2] F. Dokme, M. K. Kulekci, K. E. Engin, and U. Esme, “Corrosion behavior of a dissimilar Inconel 625 superalloy and AISI 316L stainless steel weld,” Mater. Test., vol. 67, no. 4, pp. 620–632, 2025. https://doi.org/10.1515/mt-2024-0258.Search in Google Scholar

[3] S. Ahmed, I. Lodhi, L. Asghar, and H. Altaf, “From failure to insight: The silver bridge collapse in engineering perspective,” Int. J. Adv. Natural Sci. Eng. Res., vol. 9, no. 2, pp. 141–150, 2025, https://doi.org/10.5281/zenodo.14823787.Search in Google Scholar

[4] X. Kong et al.., “Innovative prevention of stress corrosion crack propagation in nuclear power pipe welds,” Mater. Test., vol. 65, no. 8, pp. 1145–1154, 2023, https://doi.org/10.1515/mt-2023-0153.Search in Google Scholar

[5] S. Bhalla, “A mechanical impedance approach for structural identification, health monitoring and non-destructive evaluation using piezo-impedance transducers,” Ph.D. dissertation, Sch. of Civil and Environ. Eng., Nanyang Technol. Univ., Singapore, 2004.Search in Google Scholar

[6] M. V. Biezma, M. A. Andrés, D. Agudo, and E. Briz, “Most fatal oil & gas pipeline accidents through history: A lessons learned approach,” Eng. Failure Anal., vol. 110, 2020, Art. no. 104446.10.1016/j.engfailanal.2020.104446Search in Google Scholar

[7] V. Esslinger, R. Kieselbach, R. Koller, and B. Weisse, “The railway accident of Eschede – Technical background,” Eng. Failure Anal., vol. 11, no. 4, pp. 515–535, 2004, https://doi.org/10.1016/j.engfailanal.2003.11.001.Search in Google Scholar

[8] M. G. Fontana, Corrosion Engineering, 3rd ed. Singapore, McGraw-Hill, 1987.Search in Google Scholar

[9] B. Xing, Z. Cao, G. Yang, K. Zeng, and X. He, “Corrosion of self-piercing riveting joint in a Cl− and HSO3− environment,” Mater. Test., vol. 67, no. 7, pp. 1140–1148, 2025. https://doi.org/10.1515/mt-2025-0066.Search in Google Scholar

[10] Z. Ahmad, Principles of Corrosion Engineering and Corrosion Control, 1st ed. Oxford, Butterworth-Heinemann, 2006.10.1016/B978-075065924-6/50002-7Search in Google Scholar

[11] I. Y. Afif, J. Jamari, E. Saputra, S. Saefudin, M. Subri, and M. Amin, “Exploring wear characteristics of AISI 1045 steel under variable disc rotation speeds: A tribological investigation,” Teknik, vol. 45, no. 1, pp. 111–116, 2024, https://doi.org/10.14710/teknik.v45i1.59720.Search in Google Scholar

[12] M. M. Padzi, S. Abdullah, and M. Z. Nuawi, “Fatigue behaviour monitoring of an AISI 1045 carbon steel using the statistical-based z-notched approach,” Mater. Test., vol. 55, no. 5, pp. 361–368, 2013, https://doi.org/10.3139/120.110446.Search in Google Scholar

[13] R. Karimbaev, S. Choi, Y. Pyun, and A. Amanov, “Mechanical and tribological characteristics of cladded AISI 1045 carbon steel,” Materials, vol. 13, no. 4, p. 859, 2020, https://doi.org/10.3390/ma13040859.Search in Google Scholar PubMed PubMed Central

[14] J. M. R. S. Appuhamy, M. Ohga, T. Kaita, K. Fujii, and P. B. R. Dissanayake, “Development of analytical method for predicting residual mechanical properties of corroded steel plates,” Int. J. Corr., vol. 2011, pp. 1–10, 2011, Art. no. 385083. https://doi.org/10.1155/2011/385083.Search in Google Scholar

[15] S. Aldousari, “The effect of nanocomposite coating with different concentrations on fatigue life of carbon steel AISI 1045,” Mater. Test., vol. 55, nos. 11–12, pp. 878–884, 2013, https://doi.org/10.3139/120.110508.Search in Google Scholar

[16] Z. Panossian, N. L. de Almeida, R. M. F. de Sousa, G. S. de Pimenta, and L. B. S. Marques, “Corrosion of carbon steel pipes and tanks by concentrated sulfuric acid: A review,” Corrosion Sci., vol. 58, pp. 1–11, 2012, https://doi.org/10.1016/j.corsci.2012.01.025.Search in Google Scholar

[17] E. Osarolube, I. O. Owate, and N. C. Oforka, “Corrosion behaviour of mild and high carbon steels in various acidic media,” Sci. Res. Essays, vol. 3, no. 6, pp. 224–228, 2008.Search in Google Scholar

[18] Y. Teng et al.., “Investigation of corrosion behavior of Q235 steel in simulated industrial wastewater,” Int. J. Electrochem. Sci., vol. 14, no. 11, pp. 10670–10680, 2019, https://doi.org/10.20964/2019.11.33.Search in Google Scholar

[19] A. A. Rosidah, V. A. Setyowati, S. Suheni, and R. Rijayanto, “The effect of time variation on the steels corrosion rate in 0.5 M H2SO4 solution,” J. Mech. Eng., Sci. Innov., vol. 1, no. 2, pp. 49–55, 2021, https://doi.org/10.31284/j.jmesi.2021.v1i2.2183.Search in Google Scholar

[20] M. Kadowaki, I. Muto, Y. Sugawara, T. Doi, K. Kawano, and N. Hara, “Pitting corrosion resistance of martensite of AISI 1045 steel and the beneficial role of interstitial carbon,” J. Electrochem. Soc., vol. 164, no. 14, pp. C962–C972, 2017, https://doi.org/10.1149/2.0541714jes.Search in Google Scholar

[21] B. Zhang, J. Wang, H. Liu, Y. Yan, P. Jiang, and F. Yan, “Tribocorrosion properties of AISI 1045 and AISI 2205 steels in seawater: Synergistic interactions of wear and corrosion,” Friction, vol. 9, no. 5, pp. 929–940, 2021, https://doi.org/10.1007/s40544-020-0376-1.Search in Google Scholar

[22] O. Awheme, G. U. Unueroh, and I. M. Ibrahim, “The effect of tempering temperature on corrosion of AISI 1045 steel in 1M sodium chloride environment,” Nigerian J. Tech., vol. 37, no. 3, pp. 640–646, 2018, https://doi.org/10.4314/njt.v37i3.12.Search in Google Scholar

[23] J. Wu, W. Zhang, K. Chai, and A. Yu, “Corrosion behavior of AISI 1045 steel in seawater in the presence of flavobacterium sp,” Front. Microbiol., vol. 11, p. 303, 2020, Art. no. 303. https://doi.org/10.3389/fmicb.2020.00303.Search in Google Scholar PubMed PubMed Central

[24] A. Suprihanto, S. Widyanto, G. Haryadi, and M. Sholikhin, “Effect of heat treatment on the corrosion rate of AISI 1045 medium carbon steel in the seawater,” Int. Res. J. Innov. Eng. Tech., vol. 6, no. 10, pp. 13–18, 2022, https://doi.org/10.47001/IRJIET/2022.610003.Search in Google Scholar

[25] J. R. Davis, Metals Handbook Desk Edition, 2nd ed. Materials Park, OH, USA, ASM International, 1998.10.31399/asm.hb.mhde2.9781627081993Search in Google Scholar

[26] Z. Fei, Z. Pan, D. Cuiuri, H. Jun Li, S. van Duin, and Z. Yu, “Microstructural characterization and mechanical properties of K-TIG welded SAF2205/AISI316L dissimilar joint,” J. Manuf. Process., vol. 45, pp. 340–355, 2019, https://doi.org/10.1016/j.jmapro.2019.07.017.Search in Google Scholar

[27] D. L. Buruiană, A. C. Mureşan, N. Bogatu, V. Ghisman, E. E. Herbei, and V. Başliu, “Corrosion tendency of S235 steel in 3.5% NaCl solution and drinking water during six months of exposure,” Materials, vol. 17, no. 23, pp. 5979, 2024, https://doi.org/10.3390/ma17235979.Search in Google Scholar PubMed PubMed Central

[28] B. Eker and E. Yüksel, “Solutions to corrosion caused by agricultural chemicals,” Trakia J. Sci., vol. 3, no. 7, pp. 1–6, 2005.Search in Google Scholar

[29] M. Oki and P. A. L. Anawe, “A review of corrosion in agricultural industries,” Phys. Sci. Int. J., vol. 5, no. 4, pp. 216–222, 2015, https://doi.org/10.9734/psij/2015/14847.Search in Google Scholar

[30] Standard Guide for Laboratory Immersion Corrosion Testing of Metals, NACE/ASTM Standard G31-12a, 2012.Search in Google Scholar

[31] W. D. Callister and D. G. Rethwisch, Materials Science and Engineering: An Introduction, 10th ed. Hoboken, NJ, Wiley, 2020.Search in Google Scholar

[32] M. May, “Corrosion behavior of mild steel immersed in different concentrations of NaCl solutions,” J. Sebha Univ. (Pure and Appl. Sci.), vol. 15, no. 1, pp. 1–12, 2016.Search in Google Scholar

[33] R. Winston Revie and H. H. Uhlig, Uhlig’s Corrosion Handbook, 3rd ed, Hoboken, NJ, Wiley, 2011.10.1002/9780470872864Search in Google Scholar

[34] W. Sun, S. Nešić, and S. Papavinasam, “Kinetics of corrosion layer formation. Part 2 - iron sulfide and mixed iron sulfide/carbonate layers in carbon dioxide/hydrogen sulfide corrosion,” Corrosion, vol. 64, no. 7, pp. 586–599, 2008, https://doi.org/10.5006/1.3278494.Search in Google Scholar

[35] M. G. Acharya and A. N. Shetty, “The corrosion behavior of AZ31 alloy in chloride and sulfate media – A comparative study through electrochemical investigations,” J. Magnesium Alloys, vol. 7, no. 1, pp. 98–112, 2019, https://doi.org/10.1016/j.jma.2018.09.003.Search in Google Scholar

[36] A. B. Wicaksono, H. Sutanto, and W. Ruslan, “Effects of immersion in the NaCl and H2SO4 solutions on the corrosion rate, microstructure, and hardness of stainless steel 316L,” Res. Eng. Struct. Mater., vol. 9, no. 4, pp. 1153–1168, 2023. https://doi.org/10.17515/resm2023.695ma0220.Search in Google Scholar

[37] S. Simard, H. Menard, and L. Brossard, “Localized corrosion of 1024 mild steel in slightly alkaline bicarbonate solution with Cl− ions,” J. Appl. Electrochem., vol. 28, no. 2, pp. 151–160, 1998. https://doi.org/10.1023/a:1003274507668.10.1023/A:1003274507668Search in Google Scholar

[38] S. Salleh, N. M. S. Mortadha, and A. Alzakri, “Three-dimensional model of ionic species concentration and flux during localised corrosion of steel in marine environment,” J. Adv. Res. Micro. Nano. Eng., vol. 25, no. 1, pp. 27–38, 2024, https://doi.org/10.37934/armne.25.1.2738.Search in Google Scholar

[39] M. A. Pletnev, S. G. Morozov, and V. P. Alekseev, “Peculiar effect of chloride ions on the anodic dissolution of iron in solutions of various acidity,” Protect. Met., vol. 36, no. 3, pp. 202–208, 2000. https://doi.org/10.1007/bf02758391.Search in Google Scholar

[40] J. W. Walton, J. H. Dwyer, L. Rice, Z. Rueger, and G. M. Swain, “The effect of sulfuric acid anodization on the electrochemical properties of aluminum alloy AlSi10Mg prepared by selective laser melting,” J. Electrochem. Soc., vol. 171, no. 5, 2024, Art. no. 051503, https://doi.org/10.1149/1945-7111/ad45c5.Search in Google Scholar

[41] Z. Panossian, N. L. de Almeida, R. M. F. de Sousa, G. S. Pimenta, and L. B. S. Marques, “Corrosion by concentrated sulfuric acid in carbon steel pipes and tanks – State of the art,” in Presented at the Rio Pipeline Conf. and Expo., Rio de Janeiro, Brazil, Sep. 22–24, 2009.Search in Google Scholar

[42] Y. G. Avdeev and Y. I. Kuznetsov, “Iron oxide and oxyhydroxide phases formed on steel surfaces and their dissolution in acidic media. Review,” Int. J. Corros. Scale Inhib., vol. 12, no. 2, pp. 366–409, 2023, https://doi.org/10.17675/2305-6894-2023-12-2-1.Search in Google Scholar

[43] M. S. Hadi, S. N. Saud, E. Hamzah, and M. Fauzi Mamat, “Hydrogen embrittlement of 316L stainless steels exposed in 1.0 M hydrochloric acid solution,” Annales de Chimie Science des Matériaux, vol. 43, no. 6, pp. 369–375, 2019, https://doi.org/10.18280/acsm.430602.Search in Google Scholar

[44] F. Yang, M. M. Yuan, W. J. Qiao, N. N. Li, and B. Du, “Mechanical investigation of carbon steel under strong corrosion effected by corrosion pits,” Math. Problems Eng., vol. 2022, pp. 1–18, 2022, Art. no. 1719196. https://doi.org/10.1155/2022/1719196.Search in Google Scholar

[45] A. Abboub, A. Aboura, K. Benmahdi, M. Sadoun, M. Belkacem, and D. Semsoum, “Mechanical behaviour of austenitic stainless steel loaded in the aqueous solution of H2SO4 during tensile testing,” Vojnotehnicki glasnik, vol. 72, no. 4, pp. 1992–2011, 2024, https://doi.org/10.5937/vojtehg72-49964.Search in Google Scholar

[46] T. Y. Eken, K. Kardelen, N. Celebi, and M. F. Oktem, “Pitting corrosion behaviour of ST 37 structural steel in several corrosive environments,” Int. J. Energy Eng. Sci., vol. 1, no. 3, pp. 33–48, 2016.Search in Google Scholar

Published Online: 2026-03-19

© 2026 Walter de Gruyter GmbH, Berlin/Boston

Downloaded on 12.4.2026 from https://www.degruyterbrill.com/document/doi/10.1515/mt-2025-0321/html
Scroll to top button