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Integration of Photocatalysis with Ultrafiltration or Membrane Distillation for Removal of Azo Dye Direct Green 99 from Water

  • Sylwia Mozia EMAIL logo and Antoni W. Morawski
Published/Copyright: November 30, 2016
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Abstract

An application of hybrid processes photocatalysis - ultrafiltration (UF) and photocatalysis - direct contact membrane distillation (DCMD, MD) for removal of azo-dye Direct Green 99 from water is presented. Titanium dioxide Aeroxide® P25 (Degussa, Germany) was used as a photocatalyst. It was found that both membrane processes were effective in separation of TiO2 particles from the reaction solution. However, during UF a significant flux decline (from 5.2 m3/m2d to about 3.7 m3/m2d at 0.5 gTiO2/dm3) due to the membrane fouling caused by TiO2 particles was observed. Moreover, the products and by-products of photodegradation of model azo-dye passed completely through the UF membrane. The results obtained during hybrid photocatalysis - MD processes were much more promising. The permeate flux remained constant (0.35 m3/m2d) during the experiments and was equal to the flux measured for distilled water applied as a feed. After 5 h of the processes performance the model dye was removed completely, whereas TOC concentration in permeate did not exceed the value of 1.5 gC/dm3.

Received: 2008-9-17
Accepted: 2008-12-15
Published Online: 2016-11-30
Published in Print: 2009-1-1

© 2016 by Walter de Gruyter Berlin/Boston

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