Article
Licensed
Unlicensed
Requires Authentication
Theoretical Estimates of Association Constants for Contact Triple-Ion Formation
-
Willem Η. Mulder
Published/Copyright:
January 1, 2000
Abstract
A formula for the calculation of formation constants for ion-triplets in contact, KIT, is derived on the basis of a thermodynamic argument. This approach also yields an expression for the association constants for ion-pairs, ΚIP, within the same approximation, leading to a modification of the familiar Fuoss equation. The formula for K1T is compared with literature data for transition metal cyano complexes.
Published Online: 2000-1-1
Published in Print: 2000-1-1
© 2014 by Walter de Gruyter Berlin/Boston
You are currently not able to access this content.
You are currently not able to access this content.
Articles in the same Issue
- Hypochlorite Oxidation of a Chromium(III) Schiff Base Complex
- Theoretical Estimates of Association Constants for Contact Triple-Ion Formation
- Inner Sphere Reduction of Tris(pyridine-2- carboxylato)manganese(III) by Hydroxylammonium Ion in Sodium Picolinate-Picolinic Acid Buffer Media
- The Complex Aqueous Chemistry of RUC12(TPPTS)3 and its Reaction with Dihydrogen
- Substitution Reactions of Platinum(II) Dipicolinate Complex with Some Mono- and Bidentate Ligands - Rates and Mechanism
- Kinetics and Mechanism of Oxidation of Azide Ion by 12-Tungstocobaltate(III), [CoW12O40]5-, Ion
- Osmium(VIII) Catalysed Oxidation of Thiocyanate by Periodate in Aqueous Alkaline Medium
- Kinetics and Mechanism of the Reactions of Bis(biguanide)copper(II) Ion with Different Amino Acids in Aqueous Media
- Keywords: Kinetics, copper(II), biguanide, amino acids, associative mechanism
- Aquation and Base Hydrolysis of trans-Tetraammine(methylamine)sulfatocobalt(III) Complex Ion
- Notes for Contributors. Inorganic Reaction Mechanisms
- Instructions for Authors
- Disk Specifications
Articles in the same Issue
- Hypochlorite Oxidation of a Chromium(III) Schiff Base Complex
- Theoretical Estimates of Association Constants for Contact Triple-Ion Formation
- Inner Sphere Reduction of Tris(pyridine-2- carboxylato)manganese(III) by Hydroxylammonium Ion in Sodium Picolinate-Picolinic Acid Buffer Media
- The Complex Aqueous Chemistry of RUC12(TPPTS)3 and its Reaction with Dihydrogen
- Substitution Reactions of Platinum(II) Dipicolinate Complex with Some Mono- and Bidentate Ligands - Rates and Mechanism
- Kinetics and Mechanism of Oxidation of Azide Ion by 12-Tungstocobaltate(III), [CoW12O40]5-, Ion
- Osmium(VIII) Catalysed Oxidation of Thiocyanate by Periodate in Aqueous Alkaline Medium
- Kinetics and Mechanism of the Reactions of Bis(biguanide)copper(II) Ion with Different Amino Acids in Aqueous Media
- Keywords: Kinetics, copper(II), biguanide, amino acids, associative mechanism
- Aquation and Base Hydrolysis of trans-Tetraammine(methylamine)sulfatocobalt(III) Complex Ion
- Notes for Contributors. Inorganic Reaction Mechanisms
- Instructions for Authors
- Disk Specifications
