Startseite Performance enhancement of ternary epoxy hybrid composites with rice husk bio-filler
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

Performance enhancement of ternary epoxy hybrid composites with rice husk bio-filler

  • Basithrahman Abbas , Rathinavel Subbiah EMAIL logo , Vijay Kumar Mahakur , Rajagopal Ramkumar , Lakshminarayanan Oblisamy und Jasleen Kour
Veröffentlicht/Copyright: 30. Oktober 2025
Veröffentlichen auch Sie bei De Gruyter Brill

Abstract

The study explores the effect of rice husk biofiller on the hydration, mechanical, and wear properties of ternary fiber-reinforced epoxy hybrid composites composed of jute, kevlar, and basalt fibers. Composites were fabricated via hand layup and compression, with varying stacking sequences and biofiller content (2 % and 4 %). FTIR analysis confirmed that biofiller addition and fiber stacking variations did not alter composite functional groups. Water absorption tests showed that the composite with stacking sequence K-J-B-K-J-J-K-B-J-K and 4 % biofiller (H4) exhibited the lowest water uptake at 3.2 %, indicating enhanced hydration resistance. Mechanical testing revealed that H4 also achieved the highest tensile strength (137.9 N/mm2), flexural strength (225.9 N/mm2), and impact strength (179 kJ/m2), demonstrating superior load-bearing and toughness characteristics. Conversely, the composite with stacking sequence B-J-K-B-J-J-B-K-J-B and 4 % biofiller (H3) displayed the highest hardness (86.2 Shore D) and the lowest coefficient of friction (0.30), signifying excellent wear resistance. These results suggest that the synergistic combination of ternary fiber stacking and rice husk biofiller optimizes composite performance, making H3 and H4 promising candidates for lightweight, durable automotive interior and exterior components, advancing sustainable composite material development.


Corresponding author: Rathinavel Subbiah, Department of Mechanical Engineering, SRM Institute of Science and Technology (Deemed to be University) – Tiruchirappalli Campus, Tiruchirappalli, 621 105, Tamil Nadu, India, E-mail:

  1. Research ethics: Not applicable.

  2. Informed consent: Not applicable.

  3. Author contributions: All authors contributed equally to this manuscript. All authors have accepted responsibility for the entire content of this manuscript and approved its submission.

  4. Use of Large Language Models, AI and Machine Learning Tools: None declared.

  5. Conflict of interest: The authors state no conflict of interest.

  6. Research funding: None declared.

  7. Data availability: Any data related to this manuscript can be made available on request.

References

Al-Maharma, A.Y. and Sendur, P. (2018). Review of the main factors controlling the fracture toughness and impact strength properties of natural composites. Mater. Res. Express 6: 022001, https://doi.org/10.1088/2053-1591/aaec28.Suche in Google Scholar

Alshahrani, H. and Prakash, V.A. (2022). Thermal, mechanical and barrier properties of rice husk ash biosilica toughened epoxy biocomposite coating for structural application. Prog. Org. Coat. 172: 107080, https://doi.org/10.1016/j.porgcoat.2022.107080.Suche in Google Scholar

Amir, S.M.M., Sultan, M., Jawaid, M., Ariffin, A.H., Mohd, S., Salleh, K.A.M., Ishak, M.R., and Shah, A.U.M. (2019). Chapter 16 nondestructive testing method for Kevlar and natural fiber and their hybrid composites. In: Durability and life prediction in biocomposites, fibre-reinforced composites and hybrid composites. Elsevier, Boulevard, United Kingdom, pp. 367–388.10.1016/B978-0-08-102290-0.00016-7Suche in Google Scholar

Anand, P., Rajesh, D., Senthil Kumar, M., and Saran Raj, I. (2018). Investigations on the performances of treated jute/kenaf hybrid natural fiber reinforced epoxy composite. J. Polym. Res. 25: 1–9, https://doi.org/10.1007/s10965-018-1494-6.Suche in Google Scholar

Atiqah, A., Maleque, M., Jawaid, M., and Iqbal, M. (2014). Development of kenaf-glass reinforced unsaturated polyester hybrid composite for structural applications. Compos. B Eng. 56: 68–73, https://doi.org/10.1016/j.compositesb.2013.08.019.Suche in Google Scholar

Atmakuri, A., Palevicius, A., Kolli, L., Vilkauskas, A., and Janusas, G. (2021). Development and analysis of mechanical properties of caryota and sisal natural fibers reinforced epoxy hybrid composites. Polymers 13: 864, https://doi.org/10.3390/polym13060864.Suche in Google Scholar PubMed PubMed Central

Bhanupratap, R. (2020). Study on characterization and sorption behavior of jute reinforced epoxy composite: hybridization effect of Kevlar fabric. Mater. Today Proc. 27: 2017–2021, https://doi.org/10.1016/j.matpr.2019.09.050.Suche in Google Scholar

Davim, J.P. (2011). Tribology for engineers: a practical guide. Wood head Publishing, Cambridge.10.1533/9780857091444Suche in Google Scholar

Davim, J.P. (2013). Wear of advanced materials. John Wiley & Sons, Inc., Hoboken, USA.10.1002/9781118562093Suche in Google Scholar

Dev, B., Rahman, M.A., Khan, A.N., Siddique, A.B., Alam, M.R., and Rahman, M.Z. (2024). Eggshell bio‐filler integration in jute/banana fiber‐reinforced epoxy hybrid composites: fabrication and characterization. J. Appl. Polym. Sc.i. 141: e56155, https://doi.org/10.1002/app.56155.Suche in Google Scholar

Devireddy, S.B.R. and Biswas, S. (2017). Physical and mechanical behavior of unidirectional banana/jute fiber reinforced epoxy based hybrid composites. Polym. Compos. 38: 1396–1403, https://doi.org/10.1002/pc.23706.Suche in Google Scholar

Dong, C. and Davies, I.J. (2012). Flexural properties of glass and carbon fiber reinforced epoxy hybrid composites. Proc. Inst. Mech. Eng. L J. Mater. Des. Appl. 227: 308–317, https://doi.org/10.1177/1464420712459396.Suche in Google Scholar

Govindan, V., Periyagounder, K., Shanmugam, K., and Shanmugam, P. (2025). Development and characterization of glass fiber composites impregnated with limestone powder and bagasse fiber. Int. Polym. Process. 40: 43–51, https://doi.org/10.1515/ipp-2023-4427.Suche in Google Scholar

Gunwant, D. (2024). Moisture resistance treatments of natural fiber-reinforced composites: a review. Compos. Interfaces. 31: 979–1047, https://doi.org/10.1080/09276440.2024.2303543.Suche in Google Scholar

Hangargi, S., Swamy, A., Raj, R.G., Aruna, M., Venkatesh, R., Madhu, S., Obaid, S.A., Alharbi, S.A., and Kalam, M.A. (2023). Enhancement of Kevlar fiber-polypropylene composite by the inclusions of cotton stalk and granite particle: characteristics study. Biomass Conv. Bioref. 14: 30305–30314, https://doi.org/10.1007/s13399-023-04817-2.Suche in Google Scholar

Huang, J.K. and Young, W.B. (2019). The mechanical, hygral, and interfacial strength of continuous bamboo fiber reinforced epoxy composites. Compos. B Eng. 166: 272–283, https://doi.org/10.1016/j.compositesb.2018.12.013.Suche in Google Scholar

Johar, N., Ahmad, I., and Dufresne, A. (2012). Extraction, preparation and characterization of cellulose fibres and nanocrystals from rice husk. Ind. Crops. Prod. 37: 93–99, https://doi.org/10.1016/j.indcrop.2011.12.016.Suche in Google Scholar

Karthi, N., Kumaresan, K., Sathish, S., Prabhu, L., Gokulkumar, S., Balaji, D., Vigneshkumar, N., Rohinth, S., Rafiq, S., Muniyaraj, S., et al.. (2021). Effect of weight fraction on the mechanical properties of flax and jute fibers reinforced epoxy hybrid composites. Mater. Today Proc. 45: 8006–8010, https://doi.org/10.1016/j.matpr.2020.12.1060.Suche in Google Scholar

Kennedy, S.M., Arunachalam, V., and Kannan, A. (2024). A novel carbon‐flax bioepoxy hybrid composite bone plate with enhanced bio‐mechanical performance. Materialwiss. Enschaft Werkst. 55: 508–517, https://doi.org/10.1002/mawe.202300230.Suche in Google Scholar

Khanam, P.N., Khalil, H.P.S.A., Jawaid, M., Reddy, G.R., Narayana, C.S., and Naidu, S.V. (2010). Sisal/carbon fibre reinforced hybrid composites: tensile, flexural and chemical resistance properties. J. Polym. Environ. 18: 727–733, https://doi.org/10.1007/s10924-010-0210-3.Suche in Google Scholar

Lin, G.S.S., Cher, C.Y., Cheah, K.K., Noorani, T.Y., Ismail, N.H., and Ghani, N.R.N.A. (2021). Novel dental composite resin derived from rice husk natural biowaste: a systematic review and recommendation for future advancement. J. Esthet. Rest. Dentistry. 34: 503–511, https://doi.org/10.1111/jerd.12831.Suche in Google Scholar PubMed

Ma, G., Yan, L., Shen, W., Zhu, D., Huang, L., and Kasal, B. (2018). Effects of water, alkali solution and temperature ageing on water absorption, morphology and mechanical properties of natural FRP composites: plant-based jute vs. mineral-based basalt. Compos. B: Eng. 153: 398–412, https://doi.org/10.1016/j.compositesb.2018.09.015.Suche in Google Scholar

Mahakur, V.K., Bhowmik, S., and Patowari, P.K. (2023a). Decision making approaches for recognizing the optimal alkalized corchorus olitorius powder based composites for sustainable applications. Phys. Scr. 98: 125308, https://doi.org/10.1088/1402-4896/ad094e.Suche in Google Scholar

Mahakur, V.K., Bhowmik, S., and Patowari, P.K. (2024). Impact of silanization on the characterization of Corchorus olitorius particle‐based composites for sustainable applications. Polym. Int. 73: 270–279, https://doi.org/10.1002/pi.6589.Suche in Google Scholar

Mahakur, V.K., Bhowmik, S., and Patowari, P.K. (2022). Machining parametric study on the natural fiber reinforced composites: a review. Proc. Inst. Mech. Eng. C Mech. Eng. Sci. 236: 6232–6249, https://doi.org/10.1177/09544062211063752.Suche in Google Scholar

Mahakur, V.K., Bhowmik, S., and Patowari, P.K. (2023b). Tribo-informatics evaluation of dry sliding friction of silanized jute filler reinforced epoxy composites using machine learning techniques. Tribol. Int. 183: 108388, https://doi.org/10.1016/j.triboint.2023.108388.Suche in Google Scholar

Mahakur, V.K., Kumar, S., Bhowmik, S., and Patowari, P.K. (2025). Experimental evaluation of physicomechanical, tribological and optimality circumstances for corchorus olitorius particle‐based composites. Polym. Int. 74: 127–139, https://doi.org/10.1002/pi.6695.Suche in Google Scholar

Maharana, S.M., Samal, P., Dehury, J., and Mohanty, P.P. (2020). Effect of fiber content and orientation on mechanical properties of epoxy composites reinforced with jute and Kevlar. Mater. Today. Proc. 26: 273–277, https://doi.org/10.1016/j.matpr.2019.11.239.Suche in Google Scholar

Majeed, K., Ahmed, A., Bakar, M.S.A., Mahlia, T.M.I., Saba, N., Hassan, A., Jawaid, M., Hussain, M., Iqbal, J., and Ali, Z. (2019). Mechanical and thermal properties of montmorillonite-reinforced polypropylene/rice husk hybrid nanocomposites. Polym. 11: 1557, https://doi.org/10.3390/polym11101557.Suche in Google Scholar PubMed PubMed Central

Makul, N. (2019). Combined use of untreated-waste rice husk ash and foundry sand waste in high-performance self-consolidating concrete. Results Mater. 1: 100014, https://doi.org/10.1016/j.rinma.2019.100014.Suche in Google Scholar

Mani, M., Mani, S.K., Arockiasamy, F.S., Sivanantham, G., and Iyyadurai, J. (2025 In press). A review on the effect of fiber treatment and fillers on mechanical properties of kenaf fiber–reinforced composites. Int. Polym. Process., https://doi.org/10.1515/ipp-2025-0006.Suche in Google Scholar

Monjon, A., Santos, P., Valvez, S., and Reis, P.N. (2022). Hybridization effects on bending and interlaminar shear strength of composite laminates. Materials 15: 1302, https://doi.org/10.3390/ma15041302.Suche in Google Scholar PubMed PubMed Central

Nachippan, N.M., Alphonse, M., Raja, V.B., Shasidhar, S., Teja, G.V., and Reddy, R.H. (2021). Experimental investigation of hemp fiber hybrid composite material for automotive application. Mater. Today Proc. 44: 3666–3672, https://doi.org/10.1016/j.matpr.2020.10.798.Suche in Google Scholar

Nalini, S.R., Sridevi, B., and Giri, R. (2024). Experimental investigation of mechanical properties of Moringa oleifera gum filler reinforced bio polymer composite. ES Food Agrofor. 18: 1246, https://doi.org/10.30919/esfaf1246.Suche in Google Scholar

Poli, A.L., Batista, T., Schmitt, C.C., Gessner, F., and Neumann, M.G. (2008). Effect of sonication on the particle size of montmorillonite clays. J. Colloid Inter. Sci. 325: 386–390, https://doi.org/10.1016/j.jcis.2008.06.016.Suche in Google Scholar PubMed

Prabhu, P., Karthikeyan, B., Vannan, R.R.R.M., and Balaji, A. (2024). Mechanical, thermal and morphological analysis of hybrid natural and glass fiber-reinforced hybrid resin nanocomposites. Biomass Convers. Biorefin. 14: 4941–4955, https://doi.org/10.1007/s13399-022-02632-9.Suche in Google Scholar

Premnath, A.A. (2019). Impact of surface treatment on the mechanical properties of sisal and jute reinforced with epoxy resin natural fiber hybrid composites. J. Nat. Fibers 16: 718–728, https://doi.org/10.1080/15440478.2018.1432002.Suche in Google Scholar

Priyanka, P., Mali, H.S., and Dixit, A. (2020). Dynamic mechanical behaviour of kevlar and carbon-kevlar hybrid fibre reinforced polymer composites. Proc. Inst. Mech. Eng. C J. Mech. Eng. Sci. 235: 4181–4193, https://doi.org/10.1177/0954406220970600.Suche in Google Scholar

Raghu, N., Kale, A., Chauhan, S., and Aggarwal, P.K. (2018). Rice husk reinforced polypropylene composites: mechanical, morphological and thermal properties. J. Indian Acad. Wood Sci. 15: 96–104, https://doi.org/10.1007/s13196-018-0212-7.Suche in Google Scholar

Raj, H., Tripathi, S., Bauri, S., Choudhury, A. M., Mandal, S.S., and Maiti, P. (2023). Green composites using naturally occurring fibers: a comprehensive review. Sustain. Polym. Energy 1: 10010, https://doi.org/10.35534/spe.2023.10010.Suche in Google Scholar

Ramesh, V., Karthik, K., Arunkumar, K., Unnam, N.K., Ganesh, R., and Rajkumar, C. (2023). Effect of sawdust filler with Kevlar/basalt fiber on the mechanical properties epoxy-based polymer composite materials. Mater. Today Proc. 72: 2225–2230, https://doi.org/10.1016/j.matpr.2022.09.208.Suche in Google Scholar

Rathinavel, S., Basithrahman, A., Karthikeyan, J., Banu, T., Senthilkumar, S., and Senthilkumar, T.S. (2024a). Chemical treatment effect on hydration and mechanical properties of basalt and Kevlar fiber-epoxy-based hybrid composites. Biomass Conv. Bioref. 15: 10719–10731, https://doi.org/10.1007/s13399-024-05933-3.Suche in Google Scholar

Rathinavel, S., Saravankumar, S.S., Senthilkumar, T.S., Barile, C., Kumar, S.S., and Prithviraj, M. (2024b). Utilization of bio-waste material pomegranate peel powder along with silver nitrate and polyvinyl alcohol to form a hybrid biofilm. Biomass Conv. Bioref. 14: 24305–24316, https://doi.org/10.1007/s13399-023-04435-y.Suche in Google Scholar

Sahayaraj, A.F., Muthukrishnan, M., Ramesh, M., and Rajeshkumar, L. (2021). Effect of hybridization on properties of tamarind (Tamarindus indica L.) seed nano‐powder incorporated jute‐hemp fibers reinforced epoxy composites. Polym. Compos. 42: 6611–6620, https://doi.org/10.1002/pc.26326.Suche in Google Scholar

Saravanan, P., Josephraj, J., Thillainayagam, B.P., and Ravindiran, G. (2021). Evaluation of the adsorptive removal of cationic dyes by greening biochar derived from agricultural bio-waste of rice husk. Biomass Conver. Biorefin. 13: 4047–4060, https://doi.org/10.1007/s13399-021-01415-y.Suche in Google Scholar

Sathish, S., Ganapathy, T., and Bhoopathy, T. (2014). Experimental testing on hybrid composite materials. Appl. Mech. Mater. 592: 339–343, https://doi.org/10.4028/www.scientific.net/amm.592-594.339.Suche in Google Scholar

Senthil Muthu Kumar, T., Senthilkumar, K., Chandrasekar, M., Subramaniam, S., Mavinkere Rangappa, S., Siengchin, S., and Rajini, N. (2020). Chapter 5 influence of fillers on the thermal and mechanical properties of biocomposites: an overview. In: Biofibers and biopolymers for biocomposite. Springer, Charm, pp. 111–133.10.1007/978-3-030-40301-0_5Suche in Google Scholar

Singh, T.J. and Samanta, S. (2015). Characterization of kevlar fiber and its composites: a review. Mater. Today Proc. 2: 1381–1387, https://doi.org/10.1016/j.matpr.2015.07.057.Suche in Google Scholar

Singh, H. and Singh, T. (2019). Effect of fillers of various sizes on mechanical characterization of natural fiber polymer hybrid composites: a review. Compos. B Eng. 18: 5345–5350, https://doi.org/10.1016/j.matpr.2019.07.560.Suche in Google Scholar

Soundararajan, R., Sathishkumar, A., Sivasankaran, S., Shanthosh, G., and Karthik, S. (2022). Evaluation of microstructures, mechanical and dry-sliding wear performance of A356-(fly ash/SiCp) hybrid composites. Int. J. Metalcast. 16: 2079–2096, https://doi.org/10.1007/s40962-021-00731-3.Suche in Google Scholar

Subramanian, M., Arunkumar, N., Rethnam, G.S.N., and Balasubramanian, T. (2021). Exploration of the damping characteristics of basalt hybrid composites reinforced with natural fibers and epoxy resin. Fibers Polym. 22: 1684–1692, https://doi.org/10.1007/s12221-021-0761-z.Suche in Google Scholar

Venkatesh, R., Ballal, S., Krishnan, A.M., Prabagaran, S., Mohankumar, S., and Ramaraj, E. (2023). Effect of fiber layer formation on mechanical and wear properties of natural fiber filled epoxy hybrid composites. Heliyon 9: e15934, https://doi.org/10.1016/j.heliyon.2023.me15934.Suche in Google Scholar

Received: 2025-05-13
Accepted: 2025-09-12
Published Online: 2025-10-30

© 2025 Walter de Gruyter GmbH, Berlin/Boston

Heruntergeladen am 30.10.2025 von https://www.degruyterbrill.com/document/doi/10.1515/ipp-2025-0046/html?lang=de
Button zum nach oben scrollen