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Effect of Y2O3, TiO2, ZrO2 dispersion on oxidation resistance of W–Ni–Nb–Mo alloys

  • Atiqur Rahman Khan , Sambit Swain , Anshuman Patra ORCID logo EMAIL logo , D. Arvindha Babu and Bhaskar Majumdar
Published/Copyright: January 3, 2025
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International Journal of Materials Research
From the journal International Journal of Materials Research Volume 115 Issue 11-12

Abstract

1.0 wt.% Y2O3 (alloy SY), TiO2 (alloy ST), ZrO2 (alloy SZ), dispersed 79W–10Ni–5Nb–5Mo (in weight%) alloys have been produced by mechanical alloying with 5:1 ball to powder weight ratio (BPR) for 20 h at 300 rpm in toluene medium. The powders were consolidated by spark plasma sintering at 1,100 °C for 5 min and at 65 MPa pressure. Oxidation study of the consolidated alloys was carried out at 1,000 °C for 10 h to establish the sustainability at elevated temperature. The study shows that alloys SY, ST exhibit compressive residual stress and alloy SZ evidences tensile residual stress in the oxidized condition. The oxidation rate is significantly lower in alloy SY due to passive layer formation facilitated by Y2O3 and Ni. The oxidation kinetic study also suggests substantial reduction in rate constant in alloy SY. The present study also provides interesting inputs regarding development of oxidation resistant alloys for high temperature applications.

Keywords: W alloys; Oxide dispersion; Mechanical alloying; Oxidation; Residual stress
Corresponding author: Anshuman Patra, Department of Metallurgical and Materials Engineering, National Institute of Technology Rourkela, Rourkela, 769008, Odisha, India E-mail:

Acknowledgments

Support from FIST, DST regarding XRD study at NIT Rourkela is also acknowledged.

  1. Research ethics: Not Applicable.

  2. Informed consent: Informed consent was obtained from all individuals included in this study, or their legal guardians or wards.

  3. Author contributions: The authors have accepted responsibility for the entire content of this manuscript and approved its submission. Mr. Atiqur Rahman Khan has written the manuscript, Mr. Sambit Swain helped in editing and revising the manuscript, Dr. A. Patra supervised the research work and done editing, Dr. D. Arvindha Babu has assisted in analysis and revision, Dr. Bhaskar Majumdar has also assisted in analysis and revision.

  4. Use of Large Language Models, AI and Machine Learning Tools: None declared.

  5. Conflict of interest: The authors state no conflict of interest.

  6. Research funding: The research has been funded by ARMREB (DRDO) (project number: ARMREB/MAA/2017/196).

  7. Data availability: All data generated or analyzed during this study are included in this published article and its supplementary information files.

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Received: 2024-02-15
Accepted: 2024-06-12
Published Online: 2025-01-03
Published in Print: 2024-11-26

© 2024 Walter de Gruyter GmbH, Berlin/Boston

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https://doi.org/10.1515/ijmr-2024-0064
Keywords for this article
W alloys; Oxide dispersion; Mechanical alloying; Oxidation; Residual stress

Articles in the same Issue

  1. Frontmatter
  2. Editorial
  3. 5th International Conference on Processing and Characterization of Materials 2023 (ICPCM 2023)
  4. Original Papers
  5. Experimental studies on coal mine over-burden incorporated concrete as a sustainable substitute for fine aggregate in concrete construction
  6. A complex impedance spectroscopy study on PVDF/PANI/CoFe2O4 composites
  7. Optimizing electrical properties and efficiency of copper-doped CdS and CdTe solar cells through advanced ETL and HTL integration: a comprehensive experimental and numerical study
  8. Synthesis and characterization of hydroxyapatite from Ariidea fish bone as reinforcement material for (chios mastic gum: papyrus vaccine pollen) bio composite bony scaffold
  9. Optimization of the process parameter of lean-grade self-reducing pellets by surface response modelling
  10. From raw materials to functional material: synthesis and piezoelectric characterization of PIN–PT binary relaxor material
  11. Effect of ball milling on bulk MoS2 and the development of Al–MoS2 nanocomposites by powder metallurgy route
  12. Effect of beeswax on the physico-mechanical properties of poly (butylene adipate terephthalate)/poly lactic acid blend films
  13. Effect of Y2O3, TiO2, ZrO2 dispersion on oxidation resistance of W–Ni–Nb–Mo alloys
  14. Multifunctional characterisation of pressureless sintered Al2O3 –CaTiO3 nanocomposite
  15. Silicon–carbon superhydrophobic nano-structure for next generation semiconductor industry
  16. Interrelation between mechanical and electromagnetic radiation emission parameters with variable notch-width ratios under tensile fracture in silicon steel
  17. Effect of tool rotation and welding speed on microstructural and mechanical properties of dissimilar AA6061-T6 and AA5083-H12 joint in friction stir welding
  18. Effect of bentonite and molasses binder content on physical and mechanical properties of green and fired mill scale pellets
  19. FA-GGBFS based geopolymer concrete incorporating CMRW and SS as fine and coarse aggregates
  20. Characteristic study of intra woven green fibers for structural application
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  22. Bažant-Le-Kirane Paradox of fatigue failure in engineering materials
  23. Thermal modeling and analysis of laser transmission welding of polypropylene: process mechanics and parameters
  24. The influence of welding modes on metallic structures processed through WAAM
  25. Ultrasonic metal welding of Al/Cu joints with Ni coating: parametric effects on joint performance and microstructural modifications
  26. News
  27. DGM – Deutsche Gesellschaft für Materialkunde
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