Mechanochemical synthesis of a red luminescent coordination polymer from a polydentate quinoline ligand with large conjugation
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Xueli Jia
Abstract
A red luminescent coordination polymer has been prepared from a polydentate 8-hydroxyquinoline ligand via mechanochemical synthesis. The obtained coordination polymer is micro/nano spherical and can suspend stably in organic solvents after ultrasonic treatment. Due to the large conjugation of the ligand with a strong polar s-triazine core, the coordination polymer shows a largely red-shifted emission relative to the ligand. The photoluminescence peak of the coordination polymer in organic solvent is at 613 nm, while a largely red-shifted photoluminescence peak at 675 nm and a shoulder peak at 770 nm are found in the photoluminescence spectrum of the coordination polymer in solid due to the strong interchain interaction.
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Research ethics: Not applicable.
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Author contributions: The authors have accepted responsibility for the entire content of this manuscript and approved its submission.
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Competing interests: The authors state no conflict of interest.
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Research funding: None declared.
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Data availability: The raw data can be obtained on request from the corresponding author.
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Articles in the same Issue
- Frontmatter
- Original Papers
- Preparation of cellulose/activated carbon cells: application to the adsorption of cobalt from stagnant waters
- CNT/TiO2 nanocomposite for environmental remediation
- Examining the dual effect of copper nanoparticles and nitrogen doping on Cu@N-TiO2
- Mechanochemical synthesis of a red luminescent coordination polymer from a polydentate quinoline ligand with large conjugation
- Hybrid effect of neem seed and groundnut shell bio-fillers on the mechanical, water absorption and thermal properties of jute fiber reinforced epoxy composites
- Erosion behaviour of B4C/TiB2/Mo ceramic nozzles
- Facile fabrication of a flower-like superhydrophobic copper surface with superior corrosion resistance
- Characterisation of Fe, Cr and Al behaviour at the interface during diffusion bonding of ODS/Al couple
- Effect of shielding gas composition and pulsed current frequency on geometry and nitrogen content of 304L austenitic stainless-steel welds
- News
- DGM – Deutsche Gesellschaft für Materialkunde
