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Boron segregation and creep in ultra-fine grained tempered martensite ferritic steels

  • G. Eggeler EMAIL logo and A. Dlouhy
Published/Copyright: February 16, 2022

Abstract

The creep strength of ultra-fine grained tempered martensite ferritic steels with 9 to 12 wt.% chromium is significantly increased when small amounts of boron (in the 100 wt-ppm regime) are added. In the present note, experimental evidence from the literature is reviewed and previous explanations for the role of boron are summarized. The explanation for the effect of boron on creep strength must leave space for the simultaneous effect of boron on ductility. A scenario is suggested where boron segregates to micrograin boundaries which often have subgrain-boundary character. Boron can decrease the subgrain-boundary energy, decrease the velocity of subgrain-boundary migration, hinder knitting reactions between free dislocations and subgrain-boundaries and thus contribute to creep strength. This decrease of intensity of interface plasticity contributes to a decrease in ductility. Boron may moreover decrease the strength of the interface and thus promote brittleness. Further work is required to fully account for the role of boron on the mechanical properties of tempered martensite ferritic steels.


Prof. Dr.-Ing. Gunther Eggeler Ruhr-Universität Bochum, Lehrstuhl Werkstoffwissenschaft Universitätsstr. 150, Geb. IA 1/126, D-44801 Bochum, Germany Tel.: +49 234 32 23022 Fax: +49 234 32 14235

Dedicated to Professor Dr.-Ing. habil. Dr. h. c. Heinrich Oettel on the occasion of his 65th birthday


References

[1] T. Fujita, in: Advances in Material Technology for Fossil Power Plants R. Viswanathan, W.T. Bakker, J.D. Parker (Eds.), The Institute of Materials, London (2001) 33.Search in Google Scholar

[2] P.N. Ernst, in: Moderne Stähle, Ergebnisse der Werkstoff-Forschung Band 1, P.J. Uggowitzer (Ed.), Verlag der Schweizerischen Akademie der Werkstoffwissenschaften, Zürich (1987) 67.Search in Google Scholar

[3] P.N. Ernst, P.J. Uggowitzer, M.O. Speidel: J. Mat. Sci. Letters 5 (1986) 835.10.1007/BF01729243Search in Google Scholar

[4] P.N. Ernst, P.J. Uggowitzer, M.O. Speidel, in: High Temperature Alloys for Gas Turbine Applications (Proceedings of the 1986 Liège Conference), W. Betzet al. (Eds.), D. Reidel Publishing Company, Dordrecht (1986) 1357.Search in Google Scholar

[5] K. Spiradek-Hahn, P. Nowakowski, G. Zeiler, in: Advances in Material Technology for Fossil Power Plants, R. Viswanathan, W.T. Bakker, J.D. Parker (Eds.), The Institute of Materials, London (2001) 165.Search in Google Scholar

[6] T. Azuma, K. Miki, Y. Tanaka, in: Advances in Material Technology for Fossil Power Plants, R. Viswanathan, W.T. Bakker, J.D. Parker (Eds.), The Institute of Materials, London (2001) 177.Search in Google Scholar

[7] G. Eggeler, N. Nilsvang, B. Ilschner: Steel Research 58 (1987) 97.10.1002/srin.198701594Search in Google Scholar

[8] A. Drohnhofer, J. Pešička, A. Dlouhý, G. Eggeler: Z. Metallkd. 94 (2003) 505.10.3139/146.030505Search in Google Scholar

[9] J. Pešička, A. Drohnhofer, R. Kužel, G. Eggeler: Acta Mater. 51 (2003) 4847.10.1016/S1359-6454(03)00324-0Search in Google Scholar

[10] J.W. Schinkel, P.L.F. Rademakers, B.R. Drenth, C.P. Scheepens: J. Heat Treating 3 (1984) 237.10.1007/BF02833266Search in Google Scholar

[11] G. Eggeler: Acta Metall. 37 (1986) 3225.10.1016/0001-6160(89)90194-6Search in Google Scholar

[12] K. Kuchařová, J. Němec, A. Dlouhy´, in: Creep and Fracture of Engineering Materials and Structures, J.C. Earthman, F.A. Mohamed (Eds.), TMS, Warrendale (1996) 79.Search in Google Scholar

[13] M. Hättestrand, H.-O. Andrén: Mater. Sci. and Eng., A 270 (1999) 33.10.1016/S0921-5093(99)00232-4Search in Google Scholar

[14] M. Hättestrand: Micron 32 (2001) 713.10.1016/S0968-4328(00)00086-XSearch in Google Scholar

[15] G. Eggeler, J.C. Earthman, N. Nilsvang, B. Ilschner: Acta Metall. 37 (1989) 49.10.1016/0001-6160(89)90265-4Search in Google Scholar

[16] W. Blum: High Temperature Deformation and Creep of Crystalline Solids, in: Materials Science and Technology – Volume 6, H. Mughrabi (Ed.), VCH Weinheim (1993) 359.10.1002/9783527603978.mst0055Search in Google Scholar

[17] K. Maruyama, K. Sawada, J. Koike: ISIJ International 41 (2001) 641.10.2355/isijinternational.41.641Search in Google Scholar

[18] G. Eggeler, J. Hald, M. Cans, J. Phillips, in: Creep and Fracture of Engineering Materials and Structures, B. Wilshire, R.W. Evans (Eds.), The Institute of Metals, London(1993) 527.Search in Google Scholar

[19] G. Eggeler, N. Nilsvang, B. Ilschner, in: Strength of Metals and Alloys, ICSMA 9, D.G. Brandon, R. Chaim, A. Rosen (Eds.),Vol. 1, Freund Publishing Company Ltd., London (1991) 351.Search in Google Scholar

[20] O.D. Sherby, R.H. Klundt, A.K. Miller: Metall. Trans. A 8 (1977) 843.10.1007/BF02661565Search in Google Scholar

[21] T.B. Cameron, J.E. Morral, in: boron in Steel, S.K. Banerji, J.E. Morral (Eds.), The Metallurgical Society of AIME, Warrendale (1980) 61.Search in Google Scholar

[22] B. Ilschner: Hochtemperaturplastizität, Springer-Verlag, Berlin, 1973.Search in Google Scholar

[23] J. Cadek: Creep in Metallic Materials, Elsevier, Amsterdam, 1988.Search in Google Scholar

[24] D. McLean: Grain Boundaries in Metals, Clarendon Press, Oxford (1957) 116.Search in Google Scholar

[25] A.P. Sutton, R.W. Balluffi: Interfaces in Crystalline Materials, Clarendon Press, Oxford (1995) 414.Search in Google Scholar

[26] J.M. Howe: Interfaces in Materials, John Wiley and Sons, New York (1997) 470.Search in Google Scholar

[27] W. Losch: Acta Metall. 27 (1979) 1885.10.1016/0001-6160(79)90079-8Search in Google Scholar

[28] G. Duscher, M.F. Chisholm, U. Alber, M. Rühle: Nature materials 3 (2004) 621.10.1038/nmat1191Search in Google Scholar

[29] E.P. George, C.T. Liu, D.P. Pope: phys. stat. sol. (a) 160 (1997) 517.10.1002/1521-396X(199704)160:2<517::AID-PSSA517>3.0.CO;2-SSearch in Google Scholar

[30] J. Buršik, A. Orlova, K. Kuchařová, V. Sklenička, in: Creep Resitant Metallic Materials, M. Filip et al. (Eds.), Vítkovice, Ostrava (1996) 234.Search in Google Scholar

[31] M.K. Miller: Atom Probe Tomography – Analysis at the Atomic Level, Kluwer Academic Publishers, New York, 2000.10.1007/978-1-4615-4281-0Search in Google Scholar

Received: 2004-09-13
Accepted: 2004-11-20
Published Online: 2022-02-16

© 2005 Carl Hanser Verlag, München

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  2. Editorial
  3. Heinrich Oettel – 65 Jahre
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  28. Notifications/Mitteilungen
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