Startseite Methyl-orange/reduced graphene oxide composite as the electrode material for the solid-state supercapacitor
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Methyl-orange/reduced graphene oxide composite as the electrode material for the solid-state supercapacitor

  • Karsimran Singh und Amarjeet Kaur EMAIL logo
Veröffentlicht/Copyright: 8. Dezember 2023
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Abstract

Herein, we have introduced the electrode material made up of a composite of an electrochemical active organic molecule (i.e. methyl orange (MO)) and reduced graphene oxide (rGO) composite. This composite is found to be a potential material for supercapacitor application due to the sustainability, redox reversibility of organic molecules, and good conductivity of rGO. For fabricating symmetric solid-state cell (MO/rGO//PVA/H2SO4//MO/rGO), polyvinyl alcohol–sulphuric acid (PVA/H2SO4) aqueous gel polymer electrolyte (GPE) has been sandwiched between the two MO/rGO electrodes. It was found that a MO/rGO based symmetric cell interfaced with a PVA/H2SO4 gel electrolyte has a specific capacitance of 166.79 F g−1 and an energy density of 11.58 Wh kg−1 at a power density of 6.25 kW kg−1. Here, good specific capacitance is the result of a combination of both electric double-layer capacitor (EDLC) and pseudo-capacitive behaviour observed in a fabricated cell. The specific capacitance is stable after 2500 cycles of charge and discharge, with an initial fade of 32 %. This synthesized material and fabricated device found its potential to be used for the supercapacitor application.


Corresponding author: Amarjeet Kaur, Department of Physics and Astrophysics, University of Delhi, Delhi 110007, India, E-mail:

Funding source: Institution of Eminence

Award Identifier / Grant number: IoE/2023-24/12/FRP

Acknowledgment

The authors express their sincere gratitude to the Vice-Chancellor of the University of Delhi. We are thankful to the University Science Instrumentation Centre (USIC), University of Delhi for the characterization facilities.

  1. Research ethics: Not applicable.

  2. Author contributions: Karsimran Singh: Methodology, Visualization, Investigation, Writing - original draft. Amarjeet Kaur: Supervision, Conceptualization, Investigation, Writing - review & editing.

  3. Competing interests: The authors declare no conflicts of interest regarding this article.

  4. Research funding: This work is supported by the Institution of Eminence, University of Delhi [Faculty Research Program Grant – /IoE/2023-24/12/FRP]. One of the authors (Karsimran Singh) is grateful to the Council of Scientific and Industrial Research for the NET-SRF fellowship.

  5. Data availability: Data will be made available on request.

References

[1] X. Zhang, R. Han, Y. Liu et al.., “Porous and graphitic structure optimization of biomass-based carbon materials from 0D to 3D for supercapacitors: a review,” Chem. Eng. J., vol. 460, p. 141607, 2023. https://doi.org/10.1016/j.cej.2023.141607.Suche in Google Scholar

[2] F. Béguin, V. Presser, A. Balducci, and E. Frackowiak, “Carbons and electrolytes for advanced supercapacitors,” Adv. Mater., vol. 26, pp. 2219–2251, 2014. https://doi.org/10.1002/adma.201304137.Suche in Google Scholar PubMed

[3] S. Zhang and N. Pan, “Supercapacitors performance evaluation,” Adv. Energy Mater., vol. 5, p. 1401401, 2015. https://doi.org/10.1002/aenm.201401401.Suche in Google Scholar

[4] A. K. Rao, A. Kumar, K. Jain, and A. Kaur, “Design and development of an unprecedented phosphorescent bidentate iridium (III) complex exhibiting green electroluminescence,” Mater. Today Commun., vol. 34, p. 104973, 2023. https://doi.org/10.1016/j.mtcomm.2022.104973.Suche in Google Scholar

[5] A. K. Rao, D. Varshney, R. Srivastava, and A. Kaur, “Realization of room temperature electro-phosphorescence from an iridium metal based efficient novel triplet emitter,” Appl. Phys. A Mater. Sci. Process., vol. 128, pp. 1–11, 2022. https://doi.org/10.1007/s00339-022-05891-5.Suche in Google Scholar

[6] K. Singh, R. Kumar and A. Kaur, “Novel hierarchical porous carbon derived from biomass Citrus limetta pulp for high-performance quasi-solid-state supercapacitor electrodes,” J. Energy Storage, vol. 71, p. 108121, 2023. https://doi.org/10.1016/j.est.2023.108121.Suche in Google Scholar

[7] R. Kumar, R. M. Kumar, D. Lahiri, and I. Lahiri, “Thermally reduced graphene oxide film on soda lime glass as transparent conducting electrode,” Surf. Coatings Technol., vol. 309, pp. 931–937, 2017. https://doi.org/10.1016/j.surfcoat.2016.10.060.Suche in Google Scholar

[8] S. Gupta, C. Ravikant, and A. Kaur, “Sensors and actuators A: physical one-pot wet chemical synthesis of reduced graphene oxide-zinc oxide nanocomposites for fast and selective ammonia sensing at room temperature,” Sensors Actuators A. Phys., vol. 331, p. 112965, 2021. https://doi.org/10.1016/j.sna.2021.112965.Suche in Google Scholar

[9] D. Jain, S. A. Hashmi, and A. Kaur, “Surfactant assisted polyaniline nanofibres – reduced graphene oxide (SPG) composite as electrode material for supercapacitors with high rate performance,” Electrochim. Acta, vol. 222, pp. 570–579, 2016. https://doi.org/10.1016/j.electacta.2016.11.010.Suche in Google Scholar

[10] S. Sundriyal, V. Shrivastav, S. Mishra, and A. Deep, “Enhanced electrochemical performance of nickel intercalated ZIF-67/rGO composite electrode for solid-state supercapacitors,” Int. J. Hydrogen Energy, vol. 45, pp. 30859–30869, 2020. https://doi.org/10.1016/j.ijhydene.2020.08.075.Suche in Google Scholar

[11] R. Kumar, S. K. Dhawan, H. K. Singh, and A. Kaur, “Charge transport mechanism of thermally reduced graphene oxide and their fabrication for high performance shield against electromagnetic pollution,” Mater. Chem. Phys., vol. 180, pp. 413–421, 2016. https://doi.org/10.1016/j.matchemphys.2016.06.025.Suche in Google Scholar

[12] K. Chaudhary, N. Yadav, P. Venkatesu, and D. T. Masram, “Evaluation of utilizing functionalized graphene oxide nanoribbons as compatible biomaterial for lysozyme,” ACS Appl. Bio Mater., pp. 6112–6124, 2021. https://doi.org/10.1021/acsabm.1c00450.Suche in Google Scholar PubMed

[13] C. Liu, Z. Yu, D. Neff, A. Zhamu, and B. Z. Jang, “Graphene-based supercapacitor with an ultrahigh energy density,” Nano Lett., vol. 10, pp. 4863–4868, 2010. https://doi.org/10.1021/nl102661q.Suche in Google Scholar PubMed

[14] B. G. Choi, J. Hong, W. H. Hong, P. T. Hammond, and H. Park, “Facilitated ion transport in all-solid-state flexible supercapacitors,” ACS Nano., vol. 5, pp. 7205–7213, 2011.10.1021/nn202020wSuche in Google Scholar PubMed

[15] S. Daia, Z. Liuc, B. Zhao et al.., “A high-performance supercapacitor electrode based on N-doped porous graphene,” J. Power Sources, vol. 387, pp. 43–48, 2018. https://doi.org/10.1016/j.jpowsour.2018.03.055.Suche in Google Scholar

[16] C. An, Y. Zhang, and Y. Wang, “Nanoscale advances metal oxide-based supercapacitors: progress and prospectives,” Nanoscale Adv., vol. 1, pp. 4644–4658, 2019. https://doi.org/10.1039/c9na00543a.Suche in Google Scholar PubMed PubMed Central

[17] J. R. Rani, R. Thangavel, M. Kim, Y. S. Lee, and J. H. Jang, “Ultra-high energy density hybrid supercapacitors using MnO2/reduced graphene oxide hybrid nanoscrolls,” Nanomaterials, vol. 10, pp. 1–16, 2020. https://doi.org/10.3390/nano10102049.Suche in Google Scholar PubMed PubMed Central

[18] K. F. Wu, J. H. Fan, X. H. Wang et al.., “Overlapped T-Nb2O5/graphene hybrid for a quasi-solid-state asymmetric supercapacitor with a high rate capacity,” Energy Fuels, vol. 35, pp. 12546–12555, 2021. https://doi.org/10.1021/acs.energyfuels.1c00932.Suche in Google Scholar

[19] A. Morenghi, S. Scaravonati, G. Magnani, et al.., “Asymmetric supercapacitors based on nickel decorated graphene and porous graphene electrodes,” Electrochim. Acta, vol. 424, supp. 140626, pp. 1–8, 2022.10.1016/j.electacta.2022.140626Suche in Google Scholar

[20] C. Fang and D. Zhang, “High multifunctional performance structural supercapacitor with polyethylene oxide cement electrolyte and reduced graphene oxide @ CuCo2O4 nanowires,” Electrochim. Acta, vol. 401, p. 139491, 2022. https://doi.org/10.1016/j.electacta.2021.139491.Suche in Google Scholar

[21] R. Shi, C. Han, H. Duan et al.., “Redox-active organic sodium anthraquinone-2-sulfonate (AQS) anchored on reduced graphene oxide for high-performance supercapacitors,” 2018, pp. 1–9. Art. no. 1802088. https://doi.org/10.1002/aenm.201802088.Suche in Google Scholar

[22] W. Zhang, Y. Li, H. Kang, B. Yang, Z. Li, and H. Liu, “2, 6-diaminopyridine decorated reduced graphene oxide as integrated electrode with excellent electrochemical properties for aqueous supercapacitors,” Electrochim. Acta, vol. 404, p. 139725, 2022. https://doi.org/10.1016/j.electacta.2021.139725.Suche in Google Scholar

[23] W. Li, W. Yang, M. Wu, M. Zhao, and X. Lu, “Polydopamine-coated graphene for supercapacitors with improved electrochemical performances and reduced self-discharge,” Electrochim. Acta, vol. 426, p. 140776, 2022. https://doi.org/10.1016/j.electacta.2022.140776.Suche in Google Scholar

[24] S. Bag, A. Samanta, P. Bhunia, and C. R. Raj, “Rational functionalization of reduced graphene oxide with imidazolium-based ionic liquid for supercapacitor application,” Int. J. Hydrogen Energy, vol. 41, pp. 22134–22143, 2016. https://doi.org/10.1016/j.ijhydene.2016.08.041.Suche in Google Scholar

[25] M. Khandelwal, S. H. Hur, and J. S. Chung, “Tailoring the structural properties of simultaneously reduced and functionalized graphene oxide via alkanolamine(s)/alkyl alkanolamine for energy storage applications,” Chem. Eng. J., vol. 363, pp. 120–132, 2019. https://doi.org/10.1016/j.cej.2019.01.110.Suche in Google Scholar

[26] S. Ghosh, X. An, R. Shah et al.., “Effect of 1-pyrene carboxylic-acid functionalization of graphene on its capacitive energy storage,” J. Phys. Chem. C, vol. 116, pp. 20688–20693, 2012. https://doi.org/10.1021/jp303339f.Suche in Google Scholar

[27] C. Dong, Y. Yu, X. Zhang et al.., “An ionic liquid-modified reduced graphene oxide electrochemical properties,” New J. Chem., vol. 44, pp. 6428–6434, 2020. https://doi.org/10.1039/D0NJ00914H.Suche in Google Scholar

[28] L. Deng, C. Zhou, Z. Ma, and G. Fan, “Methylene blue functionalized graphene as binder-free electrode for high-performance solid-state supercapacitors,” J. Colloid Interface Sci., vol. 561, pp. 416–425, 2020. https://doi.org/10.1016/j.jcis.2019.11.007.Suche in Google Scholar PubMed

[29] S. Alipoori, S. Mazinani, S. H. Aboutalebi, and F. Sharif, “Review of PVA-based gel polymer electrolytes in flexible solid-state supercapacitors: opportunities and challenges,” J. Energy Storage, vol. 27, p. 101072, 2020. https://doi.org/10.1016/j.est.2019.101072.Suche in Google Scholar

[30] R. Kumar, K. Singh, P. Kumar, and A. Kaur, “Highly porous activated carbon prepared from the bio-waste of yellow mustard seed for high-capacity supercapacitor applications,” Mater. Chem. Phys., vol. 304, p. 127869, 2023. https://doi.org/10.1016/j.matchemphys.2023.127869.Suche in Google Scholar

[31] C. Wang, J. Wang, N. Wu et al.., “Donor–acceptor single cocrystal of coronene and perylene diimide: molecular self-assembly and charge-transfer photoluminescence,” RSC Adv., vol. 7, pp. 2382–2387, 2017, https://doi.org/10.1039/c6ra25447k.Suche in Google Scholar

[32] M. Jana, S. Saha, P. Khanra et al.., Non-covalent functionalization of reduced graphene oxide using sulfanilic acid azocromotrop and its application as a supercapacitor electrode material, J. Mater. Chem. A, vol. 3, pp. 7323–7331, 2015. https://doi.org/10.1039/c4ta07009g.Suche in Google Scholar

[33] J. Kim, L. J. Cote, F. Kim, W. Yuan, K. R. Shull, and J. Huang, “Graphene oxide sheets at interfaces,” J. Am. Chem. Soc., vol. 132, pp. 8180–8186, 2010, https://doi.org/10.1021/ja102777p.Suche in Google Scholar PubMed

[34] D. C. Marcano, D. V Kosynkin, J. M. Berlin et al.., “Improved synthesis of graphene oxide,” ACS Nano, vol. 4, pp. 4806–4814, 2010. https://doi.org/10.1021/nn1006368.Suche in Google Scholar PubMed

[35] A. K. Ishpal, “Spectroscopic investigations of ammonia gas sensing mechanism in polypyrrole nanotubes/nanorods,” J. Appl. Phys., vol. 113, p. 094504, 2013. https://doi.org/10.1063/1.4793994.Suche in Google Scholar

[36] B. Karaman and A. Bozkurt, “Enhanced performance of supercapacitor based on boric acid doped PVA-H2SO4 gel polymer electrolyte system,” Int. J. Hydrogen Energy, vol. 43, pp. 6229–6237, 2018. https://doi.org/10.1016/j.ijhydene.2018.02.032.Suche in Google Scholar

[37] K. Krishnamoorthy, M. Veerapandian, K. Yun, and S.-J. Kim, “The chemical and structural analysis of graphene oxide with different degrees of oxidation,” Carbon, vol. 53, pp. 38–49, 2013. https://doi.org/10.1016/j.carbon.2012.10.013.Suche in Google Scholar

[38] R. Kumar, D. K. Avasthi, and A. Kaur, “Fabrication of chemiresistive gas sensors based on multistep reduced graphene oxide for low parts per million monitoring of sulfur dioxideat room temperature,” Sens. Actuators B Chem., vol. 242, pp. 461–468, 2017. https://doi.org/10.1016/j.snb.2016.11.018.Suche in Google Scholar

[39] S. Stankovich, D. A. Dikin, R. D. Piner et al.., “Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide,” Carbon, vol. 45, pp. 1558–1565, 2007, https://doi.org/10.1016/j.carbon.2007.02.034.Suche in Google Scholar

[40] J. R. Miller, “Pulse Power performance of electrochemical capacitors: technical status of present commercial devices,” in Proc. 8th International Seminar on Double Layer Capacitors and Similar Energy Storage Devices, Deerfield Beach, Fla, Florida Educational Seminars, S. P. Wolsky, Ed., 1998.Suche in Google Scholar

[41] C. G. Liu, M. Liu, F. Li, and H. M. Cheng, “Frequency response characteristic of single-walled carbon nanotubes as supercapacitor electrode material,” Appl. Phys. Lett., vol. 92, pp. 1–4, 2008. https://doi.org/10.1063/1.2907501.Suche in Google Scholar

[42] N. Yadav, P. Ritu, and S. A. Hashmi, “Hierarchical porous carbon derived from eucalyptus-bark as a sustainable electrode for high-performance solid-state supercapacitors,” Sustain. Energy Fuels, vol. 4, pp. 1730–1746, 2020. https://doi.org/10.1039/c9se00812h.Suche in Google Scholar

[43] M. Sevilla and A. B. Fuertes, “Direct synthesis of highly porous interconnected carbon nanosheets and their application as high-performance supercapacitors,” ACS Nano, vol. 8, pp. 5069–5078, 2014. https://doi.org/10.1021/nn501124h.Suche in Google Scholar PubMed

[44] T. Kim, G. Jung, S. Yoo, K. S. Suh, and R. S. Ruoff, “Activated graphene-based carbons as supercapacitor electrodes with macro- and mesopores,” ACS Nano, vol. 7, pp. 6899–6905, 2013. https://doi.org/10.1021/nn402077v.Suche in Google Scholar PubMed

[45] B. Xu, S. Yue, Z. Sui et al.., “What is the choice for supercapacitors: graphene or graphene oxide?” Energy Environ. Sci., vol. 4, pp. 2826–2830, 2011. https://doi.org/10.1039/c1ee01198g.Suche in Google Scholar

[46] A. Yu, V. Chabot, and J. Zhang, Electrochemical Supercapacitors for Energy Storage and Delivery, Boca Raton, CRC Press, 2017.10.1201/b14671Suche in Google Scholar

[47] A. K. Tripathi, S. Murugavel, and R. K. Singh, “Dead Ashoka (Saraca asoca) leaves-derived porous activated carbons and flexible iongel polymer electrolyte for high-energy-density electric double-layer capacitors,” Mater. Today Sustain., vol. 11–12, p. 100062, 2021.10.1016/j.mtsust.2021.100062Suche in Google Scholar

[48] M. Suleman, Y. Kumar, and S. A. Hashmi, “High-rate supercapacitive performance of GO/r-GO electrodes interfaced with plastic-crystal-based flexible gel polymer electrolyte,” Electrochim. Acta, vol. 182, pp. 995–1007, 2015. https://doi.org/10.1016/j.electacta.2015.09.125.Suche in Google Scholar

[49] Z. S. Wu, A. Winter, L. Chen et al.., “Three-dimensional nitrogen and boron co-doped graphene for high-performance all-solid-state supercapacitors,” Adv. Mater., vol. 24, pp. 5130–5135, 2012. https://doi.org/10.1002/adma.201201948.Suche in Google Scholar PubMed

[50] M. Yao, X. Zhao, Q. Zhang, Y. Zhang, and Y. Wang, “Polyaniline nanowires aligned on MOFs-derived nanoporous carbon as high-performance electrodes for supercapacitor,” Electrochim. Acta, vol. 390, p. 138804, 2021. https://doi.org/10.1016/j.electacta.2021.138804.Suche in Google Scholar

[51] Q. Wang, H. Gao, C. Zhao et al.., “Covalent modified reduced graphene oxide: facile fabrication and high rate supercapacitor performances,” Electrochim. Acta, vol. 369, p. 137700, 2021. https://doi.org/10.1016/j.electacta.2020.137700.Suche in Google Scholar

[52] M. Suleman, M. A. R. Othman, S. A. Hashmi et al.., “Activated graphene oxide/reduced graphene oxide electrodes and low viscous sulfonium cation based ionic liquid incorporated flexible gel polymer electrolyte for high rate supercapacitors,” J. Alloys Compd., vol. 695, pp. 3376–3392, 2017. https://doi.org/10.1016/j.jallcom.2016.12.023.Suche in Google Scholar

[53] M. K. Singh, M. Suleman, Y. Kumar, and S. A. Hashmi, “A novel configuration of electrical double layer capacitor with plastic crystal based gel polymer electrolyte and graphene nano-platelets as electrodes: a high rate performance,” Energy, vol. 80, pp. 465–473, 2015. https://doi.org/10.1016/j.energy.2014.11.087.Suche in Google Scholar

[54] Z. Pan and X. Ji, “Facile synthesis of nitrogen and oxygen co-doped C@Ti3C2 MXene for high performance symmetric supercapacitors,” J. Power Sources, vol. 439, p. 227068, 2019. https://doi.org/10.1016/j.jpowsour.2019.227068.Suche in Google Scholar

[55] W. Xiao, W. Zhou, H. Yu, Y. Pu, Y. Zhang, and C. Hu, “Template synthesis of hierarchical mesoporous δ-MnO2 hollow microspheres as electrode material for high-performance symmetric supercapacitor,” Electrochim. Acta, vol. 264, pp. 1–11, 2018. https://doi.org/10.1016/j.electacta.2018.01.070.Suche in Google Scholar

[56] P. Pal and A. Ghosh, “Highly efficient gel polymer electrolytes for all solid-state electrochemical charge storage devices,” Electrochim. Acta, vol. 278, pp. 137–148, 2018. https://doi.org/10.1016/j.electacta.2018.05.025.Suche in Google Scholar

Received: 2023-04-01
Accepted: 2023-11-04
Published Online: 2023-12-08

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