Startseite Determining and modeling of density and viscosity of biodiesel-diesel and biodiesel-diesel-butanol blends
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Determining and modeling of density and viscosity of biodiesel-diesel and biodiesel-diesel-butanol blends

  • Milind H. Joshipura ORCID logo EMAIL logo , Parag Saxena , Nimish Shah , Ankur Dwivedi , Shibu Pillai und Madhu Aggrawal
Veröffentlicht/Copyright: 20. Juli 2023

Abstract

In the present work jatropha, palm, and karanja-based biodiesel and diesel blends, as well as biodiesel diesel and butanol blends, were studied. 112 density data for biodiesel-diesel blends in the temperature range of 30–65 °C were generated. 651 data for viscosity for these blends were generated in the temperature range of 25–65 °C. Blends with butanol were studied only at room temperature. The addition of butanol has not made much of a difference in the density or viscosity of the blends. Empirical models available in the literature were fitted to the data. The linear model in volume fraction and temperature was accurate for density. A generalized model was proposed representing the density for the biodiesel/diesel blend comprising all three biodiesels. A new empirical model for viscosity was also proposed in the study. The proposed model performed well compared to other models, with % an OARD of 3.74 %. A generalized model for viscosity was also proposed. The generalized models could estimate the density and viscosity with % OARD of 0.673  and 5.25 %, respectively.


Corresponding author: Milind H. Joshipura, Chemical Engineering Department, Institute of Technology, Nirma University, SG Highway, Ahmedabad, Gujarat, 382481, India, E-mail:

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: None declared.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

Anand, K., R. P. Sharma, and P. S. Mehta. 2011. “A Comprehensive Approach for Estimating Thermo-Physical Properties of Biodiesel Fuels.” Applied Thermal Engineering 31 (2–3): 235–42. https://doi.org/10.1016/j.applthermaleng.2010.09.003.Suche in Google Scholar

An, H., W. M. Yang, A. Maghbouli, S. K. Chou, and K. J. Chua. 2013. “Detailed Physical Properties Prediction of Pure Methyl Esters for Biodiesel Combustion Modeling.” Applied Energy 102: 647–56. https://doi.org/10.1016/j.apenergy.2012.08.009.Suche in Google Scholar

Alptekin, E., and M. Canakci. 2008. “Determination of the Density and the Viscosities of Biodiesel–Diesel Fuel Blends.” Renewable Energy 33 (12): 2623–30. https://doi.org/10.1016/j.renene.2008.02.020.Suche in Google Scholar

Atmanli, A., E. Ileri, B. Yuksel, and N. Yilmaz. 2015. “Extensive Analyses of Diesel–Vegetable Oil–N-Butanol Ternary Blends in a Diesel Engine.” Applied Energy 145 (1): 155–62. https://doi.org/10.1016/j.apenergy.2015.01.071.Suche in Google Scholar

Atmanli, A. 2016a. “Effects of a Cetane Improver on Fuel Properties and Engine Characteristics of a Diesel Engine Fueled with the Blends of Diesel, Hazelnut Oil and Higher Carbon Alcohol.” Fuel 172: 209–17. https://doi.org/10.1016/j.fuel.2016.01.013.Suche in Google Scholar

Atmanli, A. 2016b. “Comparative Analyses of Diesel–Waste Oil Biodiesel and Propanol, N-Butanol or 1-pentanol Blends in a Diesel Engine.” Fuel 176: 209–15. https://doi.org/10.1016/j.fuel.2016.02.076.Suche in Google Scholar

Baroutian, S., M. K. Aroua, A. A. Raman, and N. M. Sulaiman. 2010. “Viscosities and Densities of Binary and Ternary Blends of Palm Oil+ Palm Biodiesel+ Diesel Fuel at Different Temperatures.” Journal of Chemical & Engineering Data 55 (1): 504–7. https://doi.org/10.1021/je900299x.Suche in Google Scholar

Benjumea, P., J. Agudelo, and A. Agudelo. 2008. “Basic Properties of Palm Oil Biodiesel–Diesel Blends.” Fuel 87 (10–11): 2069–75. https://doi.org/10.1016/j.fuel.2007.11.004.Suche in Google Scholar

Bilgin, A., and M. Gulum. 2018. “Effects of Various Transesterification Parameters on the Some Fuel Properties of Hazelnut Oil Methyl Ester.” Energy Procedia 147: 54–62. https://doi.org/10.1016/j.egypro.2018.07.033.Suche in Google Scholar

Freitas, S. V., M. J. Pratas, R. Ceriani, A. S. Lima, and J. A. Coutinho. 2011. “Evaluation of Predictive Models for the Viscosity of Biodiesel.” Energy & Fuels 25 (1): 352–8. https://doi.org/10.1021/ef101299d.Suche in Google Scholar

Fahd, M. E. A., P. S. Lee, S. K. Chou, Y. Wenming, and C. Yap. 2014. “Experimental Study and Empirical Correlation Development of Fuel Properties of Waste Cooking Palm Biodiesel and its Diesel Blends at Elevated Temperatures.” Renewable Energy 68: 282–8. https://doi.org/10.1016/j.renene.2014.02.007.Suche in Google Scholar

Gülüm, M., and A. Bilgin. 2017. “Measurements and Empirical Correlations in Predicting Biodiesel-Diesel Blends’ Viscosity and Density.” Fuel 199: 567–77. https://doi.org/10.1016/j.fuel.2017.03.001.Suche in Google Scholar

Gülüm, M., and A. Bilgin. 2015. “Density, Flash Point and Heating Value Variations of Corn Oil Biodiesel–Diesel Fuel Blends.” Fuel Processing Technology 134: 456–64. https://doi.org/10.1016/j.fuproc.2015.02.026.Suche in Google Scholar

Gulum, M., and A. Bilgin. 2021. “Two-dimensional Surface Models to Predict the Density of Biodiesel-Diesel-Alcohol Ternary Blends.” Energy Sources Part A Recovery, Utilization and Environmental Effects 43 (5): 517–87. https://doi.org/10.1080/15567036.2019.1630034.Suche in Google Scholar

Hoekman, S. K., A. Broch, C. Robbins, E. Ceniceros, and M. Natarajan. 2012. “Review of Biodiesel Composition, Properties, and Specifications.” Renewable & Sustainable Energy Reviews 16 (1): 143–69. https://doi.org/10.1016/j.rser.2011.07.143.Suche in Google Scholar

Joshi, R. M., and M. J. Pegg. 2007. “Flow Properties of Biodiesel Fuel Blends at Low Temperatures.” Fuel 86 (1–2): 143–51. https://doi.org/10.1016/j.fuel.2006.06.005.Suche in Google Scholar

Krisnangkura, K., C. Sansa-Ard, K. Aryusuk, S. Lilitchan, and K. Kittiratanapiboon. 2010. “An Empirical Approach for Predicting Kinematic Viscosities of Biodiesel Blends.” Fuel 89 (10): 2775–80. https://doi.org/10.1016/j.fuel.2010.04.033.Suche in Google Scholar

Noureddini, H., B. C. Teoh, and L. Davis Clements. 1992. “Viscosities of Vegetable Oils and Fatty Acids.” Journal of the American Oil Chemists’ Society 69 (12): 1189–91. https://doi.org/10.1007/BF02637678.Suche in Google Scholar

Pratas, M. J., S. V. Freitas, M. B. Oliveira, S. C. Monteiro, Á. S. Lima, and J. A. Coutinho. 2011. “Biodiesel Density: Experimental Measurements and Prediction Models.” Energy & Fuels 25 (5): 2333–40. https://doi.org/10.1021/ef2002124.Suche in Google Scholar

Pham, M. T., A. T. Hoang, A. T. Le, A. R. M. S. Al-Tawaha, V. H. Dong, and V. V. Le. 2018. “Measurement and Prediction of the Density and Viscosity of Biodiesel Blends.” Int. J. Technol 9 (5): 1015–26. https://doi.org/10.14716/ijtech.v9i5.1950.Suche in Google Scholar

Ramírez-Verduzco, L. F., B. E. García-Flores, J. E. Rodríguez-Rodríguez, and A. del Rayo Jaramillo-Jacob. 2011. “Prediction of the Density and Viscosity in Biodiesel Blends at Various Temperatures.” Fuel 90 (5): 1751–61. https://doi.org/10.1016/j.fuel.2010.12.032.Suche in Google Scholar

Seffati, K., B. Honarvar, H. Esmaeili, and N. Esfandiari. 2019. “Enhanced Biodiesel Production from Chicken Fat Using CaO/CuFe2O4 Nanocatalyst and its Combination with Diesel to Improve Fuel Properties.” Fuel 235: 1238–44. https://doi.org/10.1016/j.fuel.2018.08.118.Suche in Google Scholar

Thapa, S., N. Indrawan, and P. R. Bhoi. 2018. “An Overview on Fuel Properties and Prospects of Jatropha Biodiesel as Fuel for Engines.” Environmental Technology & Innovation 9: 210–9. https://doi.org/10.1016/j.eti.2017.12.003.Suche in Google Scholar

Tate, R. E., K. C. Watts, C. A. W. Allen, and K. I. Wilkie. 2006. “The Densities of Three Biodiesel Fuels at Temperatures up to 300 C.” Fuel 85 (7–8): 1004–9. https://doi.org/10.1016/j.fuel.2005.10.024.Suche in Google Scholar

Tesfa, B., R. Mishra, F. Gu, and N. Powles. 2010. “Prediction Models for Density and Viscosity of Biodiesel and Their Effects on Fuel Supply System in CI Engines.” Renewable Energy 35 (12): 2752–60. https://doi.org/10.1016/j.renene.2010.04.026.Suche in Google Scholar

Verma, P., M. P. Sharma, and G. Dwivedi. 2016. “Impact of Alcohol on Biodiesel Production and Properties.” Renewable and Sustainable Energy Reviews 56: 319–33. https://doi.org/10.1016/j.rser.2015.11.048.Suche in Google Scholar

Wakil, M. A., M. A. Kalam, H. H. Masjuki, A. E. Atabani, and I. R. Fattah. 2015. “Influence of Biodiesel Blending on Physicochemical Properties and Importance of Mathematical Model for Predicting the Properties of Biodiesel Blend.” Energy Conversion and Management 94: 51–67. https://doi.org/10.1016/j.enconman.2015.01.043.Suche in Google Scholar

Yusuf, N. N. A. N., S. K. Kamarudin, and Z. Yaakub. 2011. “Overview on the Current Trends in Biodiesel Production.” Energy Conversion and Management 52 (7): 2741–51. https://doi.org/10.1016/j.enconman.2010.12.004.Suche in Google Scholar

Yilmaz, N., F. M. Vigil, K. Benalil, S. M. Davis, and A. Calva. 2014. “Effect of Biodiesel–Butanol Fuel Blends on Emissions and Performance Characteristics of a Diesel Engine.” Fuel 135: 46–50. https://doi.org/10.1016/j.fuel.2014.06.022.Suche in Google Scholar


Supplementary Material

This article contains supplementary material (https://doi.org/10.1515/ijcre-2023-0004).


Received: 2023-01-06
Accepted: 2023-07-05
Published Online: 2023-07-20

© 2023 Walter de Gruyter GmbH, Berlin/Boston

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