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Promotional effects of cerium and titanium on NiMn2O4 for selective catalytic reduction of NO by NH3

  • Sara Karkhaneh , Seyed Mahdi Latifi EMAIL logo , Eslam Kashi and Alireza Salehirad
Published/Copyright: November 4, 2022

Abstract

In this work NiMn2O4, NiMn2O4/TiO2 and NiMn2O4/CeO2 nanocomposites were prepared by co-precipitation method and evaluated for the selective catalytic reduction of NOx with NH3. Various characterization methods such as X-ray diffraction, field emission scanning electron microscope, specific surface area, average pore diameter, temperature programmed desorption (NH3-TPD), temperature-programmed reduction (H2-TPR) and inductively coupled plasma optical emission spectrometer were conducted to probe the physical and chemical properties of these catalysts. The catalytic activity tests showed that in the temperature window of 200–400 °C and the space velocity of 10,000–40,000 h−1, NiMn2O4/CeO2 demonstrated the best performance among the synthesized catalysts.


Corresponding author: Seyed Mahdi Latifi, Department of Chemical Technologies, Iranian Research Organization for Science and Technology (IROST), Tehran, Iran, E-mail:

Acknowledgment

The authors are grateful to the IROST for financial support.

  1. Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: None declared.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

Bagheri, S., N. Muhd Julkapli, and S. Bee Abd Hamid. 2014. “Titanium Dioxide as a Catalyst Support in Heterogeneous Catalysis.” The Scientific World Journal 2014: 727496.10.1155/2014/727496Search in Google Scholar PubMed PubMed Central

Boningari, T., P. R. Ettireddy, and A. Somogyvari. 2015. “Influence of Elevated Surface Texture Hydrated Titania on Ce-Doped Mn/TiO2 Catalysts for the Low-Temperature SCR of NOx under Oxygen-Rich Conditions.” Journal of Catalysis 325: 145–55. https://doi.org/10.1016/j.jcat.2015.03.002.Search in Google Scholar

Casapu, M., O. Kröcher, and M. Elsener. 2009. “Screening of Doped MnOx–CeO2 Catalysts for Low-Temperature NO-SCR.” Applied Catalysis B: Environmental 88 (3): 413–9. https://doi.org/10.1016/j.apcatb.2008.10.014.Search in Google Scholar

Chen, D., J. Feng, J. Sun, C. Cen, S. Tian, J Yang, and Y. Xiong. 2020. “Molybdenum Modified Montmonrillonite Clay as an Efficient Catalyst for Low Temperature NH3-SCR.” Journal of Chemical Technology and Biotechnology 95: 1441–52, https://doi.org/10.1002/jctb.6329.Search in Google Scholar

Deshmane, V. G., S. L. Owen, R. Y. Abrokwah, and D. Kuila. 2015. “Mesoporous Nanocrystalline TiO2 Supported Metal (Cu, Co, Ni, Pd, Zn, and Sn) Catalysts: Effect of Metal-Support Interactions on Steam Reforming of Methanol.” Journal of Molecular Catalysis A: Chemical 408 (336): 202–13, https://doi.org/10.1016/j.molcata.2015.07.023.Search in Google Scholar

Fu, Z., M. Guo, C. Liu, N. Ji, C. Song, and Q. Liu. 2015. “Design and Synthesis Functional Selective Catalytic Reduction Catalyst for NOx Removal.” Procedia Engineering 121: 952–6. https://doi.org/10.1016/j.proeng.2015.09.061.Search in Google Scholar

Fang, D., D. Li, F. He, J. Xie, C. Xiong, and Y. Chen. 2019. “Experimental and DFT Study of the Adsorption and Activation of NH3 and NO on Mn-Based Spinels Supported on TiO2 Catalysts for SCR of NOx.” Computational Materials Science 160: 374–81. https://doi.org/10.1016/j.commatsci.2019.01.025.Search in Google Scholar

Gao, F., X. Tang, and H. Yi. 2017a. “A Review on Selective Catalytic Reduction of NOx by NH3 over Mn–Based Catalysts at Low Temperatures: Catalysts, Mechanisms, Kinetics and DFT Calculations.” Catalysts 7 (7): 1–32, https://doi.org/10.3390/catal7070199.Search in Google Scholar

Gao, F., X. Tang, and H. Yi. 2017b. “Promotional Mechanisms of Activity and SO2 Tolerance of Co- or Ni-Doped MnOx-CeO2 Catalysts for SCR of NOx with NH3 at Low Temperature.” Chemical Engineering Journal 317: 20–31, https://doi.org/10.1016/j.cej.2017.02.042.10.1016/j.cej.2017.02.042Search in Google Scholar

Gao, F., X. Tang, H. Yi, S. Zhao, J. Wang, and T. Gu. 2019. “Improvement of Activity, Selectivity and H2O&SO2-Tolerance of Micro-mesoporous CrMn2O4 Spinel Catalyst for Low-Temperature NH3-SCR of NOx.” Applied Surface Science 466: 41–424. https://doi.org/10.1016/j.apsusc.2018.09.227.Search in Google Scholar

Gao, F., X. Tang, and H. Yi. 2018. “Novel Co– or Ni–Mn Binary Oxide Catalysts with Hydroxyl Groups for NH3–SCR of NOx at Low Temperature.” Applied Surface Science 443: 103–13. https://doi.org/10.1016/j.apsusc.2018.02.151.10.1016/j.apsusc.2018.02.151Search in Google Scholar

Gao, G., J. W. Shi, Z. Fan, C. Gao, and C. Niu. 2017. “MnM2 O4microspheres (M = Co, Cu, Ni) for Selective Catalytic Reduction of NO with NH3: Comparative Study on Catalytic Activity and Reaction Mechanism via In-Situ Diffuse Reflectance Infrared Fourier Transform Spectroscopy.” Chemical Engineering Journal 325: 91–100. https://doi.org/10.1016/j.cej.2017.05.059.10.1016/j.cej.2017.05.059Search in Google Scholar

Huang, Q., Z.-Y. Zhang, W.-J. Ma, and Y.-W. Chen. 2012. “A Novel Catalyst of Ni–Mn Complex Oxides Supported on Cordierite for Catalytic Oxidation of Toluene at Low Temperature.” Journal of Industrial and Engineering Chemistry 18 (2): 757–62. https://doi.org/10.1016/j.jiec.2011.11.129.Search in Google Scholar

Heo, J. N., N. Son, J. Shin, J. Y. Do, and M. Kang. 2020. “Efficient Hydrogen Production by Low-Temperature Steam Reforming of Propane Using Catalysts with Very Small Amounts of Pt Loaded on NiMn2O4 Particles.” International Journal of Hydrogen Energy 45 (41): 20904–21, https://doi.org/10.1016/j.ijhydene.2020.05.247.Search in Google Scholar

Kang, M., E. D. Park, J. M. Kim, and J. E. Yie. 2007. “Manganese Oxide Catalysts for NOx Reduction with NH3 at Low Temperatures.” Applied Catalysis A: General 327 (2): 261–9. https://doi.org/10.1016/j.apcata.2007.05.024.Search in Google Scholar

Kang, M., E. D. Park, J. M. Kim, and J. E. Yie. 2006. “Cu–Mn Mixed Oxides for Low Temperature NO Reduction with NH3.” Catalysis Today 111 (3): 236–41. https://doi.org/10.1016/j.cattod.2005.10.032.Search in Google Scholar

Kwon, D. W., S. Lee, J. Kim, K.-Y. Lee, and H. P. Ha. 2019. “Influence of Support Composition on Enhancing the Performance of Ce-V on TiO2 Comprised Tungsten-Silica for NH3- SCR.” Catalysis Today 359: 112–23, https://doi.org/10.1016/j.cattod.2019.07.002.Search in Google Scholar

Liu, Z., Y. Yi, S. Zhang, T. Zhu, J. Zhu, and J. Wang. 2013. “Selective Catalytic Reduction of NOx with NH3 over Mn-Ce Mixed Oxide Catalyst at Low Temperatures.” Catalysis Today 216: 76–81. https://doi.org/10.1016/j.cattod.2013.06.009.Search in Google Scholar

Liu, C., J.-W. Shi, C. Gao, and C. Niu. 2016. “Manganese Oxide-Based Catalysts for Low-Temperature Selective Catalytic Reduction of NOx with NH3: A Review.” Applied Catalysis A: General 522: 54–69. https://doi.org/10.1016/j.apcata.2016.04.023.Search in Google Scholar

Liu, J., X. Li, and R. Li. 2018. “Facile Synthesis of Tube-Shaped Mn-Ni-Ti Solid Solution and Preferable Langmuir-Hinshelwood Mechanism for Selective Catalytic Reduction of NOx by NH3.” Applied Catalysis A: General 549: 289–301. https://doi.org/10.1016/j.apcata.2017.10.010.Search in Google Scholar

Li, J., J. Chen, R. Ke, C. Luo, and J. Hao. 2007. “Effects of Precursors on the Surface Mn Species and the Activities for NO Reduction over MnOx/TiO2 Catalysts.” Catalysis Communications 8 (12): 1896–900. https://doi.org/10.1016/j.catcom.2007.03.007.Search in Google Scholar

Leng, X., Z. Zhang, and Y. Li. 2018. “Excellent Low Temperature NH3-SCR Activity over MnaCe0.3TiOx (a = 0.1–0.3) Oxides: Influence of Mn Addition.” Fuel Processing Technology 181: 33–43. https://doi.org/10.1016/j.fuproc.2018.09.012.Search in Google Scholar

Li, C., X. Tang, and H. Yi. 2018. “Rational Design of Template-Free MnOx-CeO2 Hollow Nanotube as de-NOx Catalyst at Low Temperature.” Applied Surface Science 428: 924–32. https://doi.org/10.1016/j.apsusc.2017.09.131.10.1016/j.apsusc.2017.09.131Search in Google Scholar

Li, X., Y. Du, X. Guo, R. Wang, B. Hou, and X. Wu. 2019. “Synthesis of a Novel NiMnTi Mixed Metal Oxides from LDH Precursor and its Catalytic Application for Selective Catalytic Reduction of NOx with NH3.” Catalysis Letters 149 (2): 456–64. https://doi.org/10.1007/s10562-018-2626-7.10.1007/s10562-018-2626-7Search in Google Scholar

Liu, Z., H. Liu, X. Feng, L. Ma, X. Cao, and B. Wang. 2018. “Ni-Ce-Ti as a Superior Catalyst for the Selective Catalytic Reduction of NOx with NH3.” Molecular Catalysis 445: 179–86. https://doi.org/10.1016/j.mcat.2017.11.028.Search in Google Scholar

Meng, B., Z. Zhao, Y. Chen, X. Wang, Y. Li, and J. Qiu. 2014. “Low-temperature Synthesis of Mn-Based Mixed Metal Oxides with Novel Fluffy Structures as Efficient Catalysts for Selective Reduction of Nitrogen Oxides by Ammonia.” Chemical Communications 50 (82): 12396–9. https://doi.org/10.1039/C4CC03072A.10.1039/C4CC03072ASearch in Google Scholar PubMed

Qi, G., and R. T. Yang. 2003. “Performance and Kinetics Study for Low-Temperature SCR of NO with NH3 over MnOx–CeO2 Catalyst.” Journal of Catalysis 217 (2): 434–41. https://doi.org/10.1016/S0021-9517(03)00081-2.Search in Google Scholar

Qiu, M., S. Zhan, H. Yu, and D. Zhu. 2015. “Low-temperature Selective Catalytic Reduction of NO with NH3 over Ordered Mesoporous MnxCo3−xO4 Catalyst.” Catalysis Communications 62: 107–11. https://doi.org/10.1016/j.catcom.2015.01.022.Search in Google Scholar

Sultana, S. S. P., D. H. V. Kishore, and M. Kuniyil. 2015. “Ceria Doped Mixed Metal Oxide Nanoparticles as Oxidation Catalysts: Synthesis and Their Characterization.” Arabian Journal of Chemistry 8 (6): 766–70. https://doi.org/10.1016/j.arabjc.2015.05.008.Search in Google Scholar

Sheng, Z., D. Ma, and D. Yu. 2018. “Synthesis of Novel MnOx@TiO2 Core-Shell Nanorod Catalyst for Low-Temperature NH3 Selective Catalytic Reduction of NOx with Enhanced SO2 Tolerance.” Cuihua Xuebao/Chinese Journal of Catalysis 39 (4): 821–30. https://doi.org/10.1016/s1872-2067(18)63059-1.10.1016/S1872-2067(18)63059-1Search in Google Scholar

Tang, X., J. Hao, W. Xu, and J. Li. 2007. “Low Temperature Selective Catalytic Reduction of NOx with NH3 over Amorphous MnOx Catalysts Prepared by Three Methods.” Catalysis Communications 8 (3): 329–34. https://doi.org/10.1016/j.catcom.2006.06.025.Search in Google Scholar

Thirupathi, B., and P. G. Smirniotis. 2011. “Co-doping a Metal (Cr, Fe, Co, Ni, Cu, Zn, Ce, and Zr) on Mn/TiO2 Catalyst and its Effect on the Selective Reduction of NO with NH3 at Low-Temperatures.” Applied Catalysis B: Environmental 110: 195–206. https://doi.org/10.1016/j.apcatb.2011.09.001.Search in Google Scholar

Thirupathi, B., and P. G. Smirniotis. 2012. “Nickel-doped Mn/TiO2 as an Efficient Catalyst for the Low-Temperature SCR of NO with NH3: Catalytic Evaluation and Characterizations.” Journal of Catalysis 288: 74–83. https://doi.org/10.1016/j.jcat.2012.01.003.Search in Google Scholar

Wei, L., S. Cui, H. Guo, and X. Ma. 2018. “Study on the Role of Mn Species in Low Temperature SCR on MnOx/TiO2 through Experiment and DFT Calculation.” Molecular Catalysis 445: 102–10. https://doi.org/10.1016/j.mcat.2017.11.022.Search in Google Scholar

Wu, X., Z. Si, G. Li, D. Weng, and Z. Ma. 2011. “Effects of Cerium and Vanadium on the Activity and Selectivity of MnOx-TiO2 Catalyst for Low-Temperature NH3-SCR.” Journal of Rare Earths 29 (1): 64–8. https://doi.org/10.1016/S1002-0721(10)60403-6.Search in Google Scholar

Wei, L., S. Cui, H. Guo, X. Ma, and L. Zhang. 2016. “DRIFT and DFT Study of Cerium Addition on SO2 of Manganese-Based Catalysts for Low Temperature SCR.” Journal of Molecular Catalysis A: Chemical 421: 102–8. https://doi.org/10.1016/j.molcata.2016.05.013.Search in Google Scholar

Xiao, X., Z. Sheng, L. Yang, and F. Dong. 2016. “Low-Temperature Selective Catalytic Reduction of NOx with NH3 over a Manganese and Cerium Oxide/Graphene Composite Prepared by a Hydrothermal Method.” Catalysis Science & Technology 6 (5): 1507–14. https://doi.org/10.1039/c5cy01228g.10.1039/C5CY01228GSearch in Google Scholar

Xu, C., W. Sun, L. Cao, and J. Yang. 2016. “Highly Efficient Pd-Doped Ferrite Spinel Catalysts for the Selective Catalytic Reduction of NO with H2 at Low Temperature.” Chemical Engineering Journal 289: 231–8. https://doi.org/10.1016/j.cej.2015.12.085.10.1016/j.cej.2015.12.085Search in Google Scholar

Xu, L., X.-S. Li, M. Crocker, Z.-S. Zhang, A.-M. Zhu, and C. Shi. 2013. “A Study of the Mechanism of Low-Temperature SCR of NO with NH3 on MnOx/CeO2.” Journal of Molecular Catalysis A: Chemical 378: 82–90. https://doi.org/10.1016/j.molcata.2013.05.021.Search in Google Scholar

Xie, C., S. Yang, J. W. Shi, and C. Niu. 2019. “Constructing Hollow Silkworm Structure in MnOx–TiO2 Catalysts for Improving the Performance in Selective Catalytic Reduction of NO by NH3.” Reaction Kinetics, Mechanisms and Catalysis 128 (2): 681–93. https://doi.org/10.1007/s11144-019-01669-8.10.1007/s11144-019-01669-8Search in Google Scholar

Yang, C., J. Yang, and Q. Jiao. 2019. “Promotion Effect and Mechanism of MnOx Doped CeO2 Nano-Catalyst for NH3-SCR.” Ceramics International. https://doi.org/10.1016/j.ceramint.2019.10.163.Search in Google Scholar

Yang, B., D.-H. Zheng, and Y.-S. Shen. 2015. “Influencing Factors on Low-Temperature deNOx Performance of Mn–La–Ce–Ni–Ox/PPS Catalytic Filters Applied for Cement Kiln.” Journal of Industrial and Engineering Chemistry 24: 148–52. https://doi.org/10.1016/j.jiec.2014.09.022.Search in Google Scholar

You, X., Z. Sheng, D. Yu, L. Yang, X. Xiao, and S. Wang. 2017. “Influence of Mn/Ce Ratio on the Physicochemical Properties and Catalytic Performance of Graphene Supported MnOx-CeO2 Oxides for NH3-SCR at Low Temperature.” Applied Surface Science 423: 845–54. https://doi.org/10.1016/j.apsusc.2017.06.226.Search in Google Scholar

Yao, X., J. Cao, and L. Chen. 2019. “Doping Effect of Cations (Zr4+, Al3+, and Si4+) on MnOx/CeO2 Nano-Rod Catalyst for NH3-SCR Reaction at Low Temperature.” Chinese Journal of Catalysis 40 (5): 733–43. https://doi.org/10.1016/S1872-2067(18)63204-8.Search in Google Scholar

Zhang, P., Y. Sun, W. Su, Y. Wei, and J. Liu. 2016. “Low-temperature Selective Catalytic Reduction of NO with NH3 over Ni–Mn–Ox Catalysts.” RSC Advances 6 (109): 107270–7. https://doi.org/10.1039/C6RA21267K.10.1039/C6RA21267KSearch in Google Scholar

Zhang, S., B. Zhang, B. Liu, and S. Sun. 2017. “A Review of Mn-Containing Oxide Catalysts for Low Temperature Selective Catalytic Reduction of NOx with NH3: Reaction Mechanism and Catalyst Deactivation.” RSC Advances 7 (42): 26226–42. https://doi.org/10.1039/C7RA03387G.10.1039/C7RA03387GSearch in Google Scholar

Zhang, L., L. Li, and C. Ge. 2019. “Promoting N2 Selectivity of CeMnOx Catalyst by Supporting TiO2 in NH3-SCR Reaction.” Industrial & Engineering Chemistry Research 58 (16): 6325–32. https://doi.org/10.1021/acs.iecr.9b00650.10.1021/acs.iecr.9b00650Search in Google Scholar

Zhang, N., Z. Yang, Z. Chen, Y. Li, Y. Liao, Y. Li, M. Gong, and Y. Chen. 2018. “Synthesis of Sulfur-Resistant TiO2-CeO2 Composite and its Catalytic Performance in the Oxidation of a Soluble Organic Fraction from Diesel Exhaust.” Catalysts 8 (6): 9–11, https://doi.org/10.3390/catal8060246.Search in Google Scholar

Zhang, Z., R. Li, and M. Wang. 2021. “Two Steps Synthesis of CeTiOx Oxides Nanotube Catalyst: Enhanced Activity, Resistance of SO2 and H2O for Low Temperature NH3-SCR of NOx.” Applied Catalysis B: Environmental 282: 119542. https://doi.org/10.1016/j.apcatb.2020.119542.Search in Google Scholar

Received: 2022-04-09
Accepted: 2022-10-21
Published Online: 2022-11-04

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